Concentration and subcellular distribution of trace elements in liver of small cetaceans incidentally caught along the Brazilian coast

Concentrations of trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, T-Hg, Org-Hg, Tl and Pb) were determined in liver samples of estuarine dolphin (Sotalia guianensis; n = 20), Franciscana dolphin (Pontoporia blainvillei; n = 23), Atlantic spotted dolphin (Stenella frontalis; n = 2), common dolphin (Delphinus capensis; n = 1) and striped dolphin (Stenella coeruleoalba; n = 1) incidentally caught along the coast of Sao Paulo State and Parana State, Brazil, from 1997 to 1999. The hepatic concentrations of trace elements in the Brazilian cetaceans were comparable to the data available in literature on marine mammals from Northern Hemisphere. Concentrations of V, Se, Mo, Cd, T-Hg and Org-Hg increased with increasing age in liver of both estuarine and Franciscana dolphins. Very high concentrations of Cu (range, 262-1970 microg/g dry wt.) and Zn (range, 242-369 microg/g dry wt.) were observed in liver of sucklings of estuarine dolphin. Hepatic concentrations of V, Se, T-Hg, Org-Hg and Pb were significantly higher in estuarine dolphin, whereas Franciscana dolphin showed higher concentrations of Mn, Co, As and Rb. Ratio of Org-Hg to T-Hg in liver was significantly higher in Franciscana dolphin than estuarine dolphin, suggesting that demethylation ability of methyl Hg might be lower in liver of Franciscana than estuarine dolphins. High hepatic concentrations of Ag were found in some specimens of Franciscana dolphin (maximum, 20 microg/g dry wt.), and 17% of Franciscana showed higher concentrations of Ag than Hg. These samples with high Ag concentration also exhibited elevated hepatic Se concentration, implying that Ag might be detoxified by Se in the liver. Higher correlation coefficient between (Hg+0.5 Ag) and Se than between Hg and Se and the large distribution of Ag in non-soluble fraction in nuclear and mitochondrial fraction of the liver also suggests that Ag might be detoxified by Se via formation of Ag2Se in the liver of Franciscana dolphin.     

A novel index to evaluate discretization methods:A case study of flood susceptibility assessment based on random forest

The selection of a suitable discretization method(DM)to discretize spatially continuous variables(SCVs)is critical in ML-based natural hazard susceptibility assessment.However,few studies start to consider the influence due to the selected DMs and how to efficiently select a suitable DM for each SCV.These issues were well addressed in this study.The information loss rate(ILR),an index based on the informa-tion entropy,seems can be used to select optimal DM for each SCV.However,the ILR fails to show the actual influence of discretization because such index only considers the total amount of information of the discretized variables departing from the original SCV.Facing this issue,we propose an index,infor-mation change rate(ICR),that focuses on the changed amount of information due to the discretization based on each cell,enabling the identification of the optimal DM.We develop a case study with Random Forest(training/testing ratio of 7:3)to assess flood susceptibility in Wanan County,China.The area under the curve-based and susceptibility maps-based approaches were presented to compare the ILR and ICR.The results show the ICR-based optimal DMs are more rational than the ILR-based ones in both cases.Moreover,we observed the ILR values are unnaturally small(＜1％),whereas the ICR values are obviously more in line with general recognition(usually 10％-30％).The above results all demonstrate the superiority of the ICR.We consider this study fills up the existing research gaps,improving the ML-based natural hazard susceptibility assessments.     

Deep structure of the Nojima Fault, southwest Japan, estimated from borehole observations of fault-zone trapped waves

To estimate the deep structure of the southern part of the Nojima Fault, southwest Japan without the influence of near-surface structures, we analyzed the Love-wave-type fault-zone trapped waves (LTWs) recorded by a borehole seismometer at 1800 m depth. We examined the polarization, dispersion, and dominant frequency of the wavetrain following the direct S-wave in each seismogram to identify the LTW. We selected eight candidates for typical LTWs from 462 records. Because the duration of the LTW increases with hypocentral distance, we infer that the low velocity fault-zone of the Nojima Fault continues towards the seismogenic depth. In addition, since the duration of the LTW increases nonlinearly with hypocentral distance, we infer that the S-wave velocity of the fault-zone increases with depth. The location of events showing the LTW indicates that the fault-zone dips to the southeast at 75° and continues to a depth of approximately 10 km. We assumed a uniform low-velocity waveguide to estimate the average structure of the fault-zone. We estimated the average width, S-wave velocity, and Q_s of the fault-zone by comparing an analytical solution of the LTW with measured data. The average width, S-wave velocity, and Q_s of the fault-zone are 150 to 290 m, 2.5 to 3.2 km/s, and 40 to 90, respectively. Hence the fault-zone structure with a larger width and smaller velocity reduction than the fault-zone model estimated by previous surface observation is more suitable to represent the average fault-zone structure of the Nojima fault. The present study also indicated that the shallow layers and/or a shallow fault-zone structure drastically changes the characteristics of the LTW recorded at the surface, and therefore cause a discrepancy in the fault-zone model between the borehole observation and surface observation.     

Experiment study on RC frame retrofitted by the external structure

A new retrofitting method is proposed herein for reinforced concrete (RC) structures through attachment of an external structure. The external structure consists of a fiber concrete encased steel frame, connection slab and transverse beams. The external structure is connected to the existing structure through a connection slab and transverse beams. Pseudostatic experiments were carried out on one unretrofitted specimen and three retrofitted frame specimens. The characteristics, including failure mode, crack pattern, hysteresis loops behavior, relationship of strain and displacement of the concrete slab, are demonstrated. The results show that the load carrying capacity is obviously increased, and the extension length of the slab and the number of columns within the external frame are important influence factors on the working performance of the existing structure. In addition, the displacement difference between the existing structure and the outer structure was caused mainly by three factors: shear deformation of the slab, extraction of transverse beams, and drift of the conjunction part between the slab and the existing frame. Furthermore, the total deformation determined by the first two factors accounted for approximately 80% of the damage, therefore these factors should be carefully considered in engineering practice to enhance the effects of this new retrofitting method.     

Duluth Complex apatites: Age reference material for LA–ICP–MS‐based fission‐track dating

Anorthositic series apatites of the Duluth Complex, Minnesota, USA, have high spontaneous fission‐track densities of up to ~10⁷ cm^–2 and a homogeneous age of ~900 Ma, allowing high‐precision fission‐track dating based on LA–ICP–MS U analysis. Absolute fission‐track dating, track‐length measurement and chemical composition analysis were performed to evaluate a cooling history, which is essential for age reference materials. Preliminary inverse modelling for a sample with a shortened track‐length distribution yielded a monotonic cooling history from ~100°C at 925 Ma. The apatites incur an over‐etching problem when employing the commonly used etching protocol involving 5.5 M HNO₃.     

Spectroscopic Studies of Solar Corona VII. Formation of a Coronal Loop by Evaporation

We obtained time-sequence spectroscopic observations in (Fe x) 6374 Å and (Fe xiv) 5303 Å lines successively with the 25-cm coronagraph, and narrow-band and Doppler images in 5303 Å line by the 2-D 10-cm Doppler coronagraph NOGIS at the Norikura Solar Observatory, of a coronal region for about 7 h on 9 19–20, 2001. The raster scans were obtained with a quasi-periodicity of about 14 min and NOGIS obtained the images with an interval of about 1 min. The coronal region observed showed the formation of a coronal loop by a high-speed surge in the 6374 Å line rising from one of the footpoints of the loop. Off the limb spectroscopic observations in the 6374 Å line showed large velocities along the line of sight and vertical to the solar limb at the time of formation of the loop. The 5303 Å line observations showed negligible line-of-sight velocities and low vertical velocities when compared to those in the 6374 Å line. A hump in the intensity plots in 5303 Å with height appears to move up with respect to the solar limb with an average velocity of 4km s^–1. The FWHM of the 6374 Å showed a much smaller value of about 0.7 Å near the foot point as compared to a value of 1.2 Å at larger heights at the beginning of observations. Later as the loop developed, the FWHM of 6374 Å line showed a gradual decrease along the loop up to 70 from the limb, reached a minimum value of about 0.5 Å and then increased with height during the formation of the loop; this trend lasted for about 2 h. About 3 h after the beginning of the formation of the loop, the FWHM of 6374 Å emission line showed normal values and normal rate of increase with height with some fluctuations. The FWHM of the 5303 Å line did not show such variations along the loop and showed normal decrease in FWHM with height found earlier (Singh et al., 2003a). These observations suggest that a relatively cooler plasma at a temperature of about 0.7 MK or less (corresponding to minimum value of FWHM of 0.5 Å) was ejected from the transition region with a large velocity of about 48km s^–1, heated up in the corona by some process and formed a coronal loop with a height of about 200 above the limb that had lifetime greater than 4 h. It appears that the plasma moved from one of the footpoints and the loop was formed by evaporation of chromospheric plasma. No large-scale brightening and H flare were observed in this region during the observational period of 7 h.On leave from Indian Institute of Astrophysics, Bangalore 560034, India.     

Power spectra of temperature and salinity fluctuations in the slope water off Cape Hatteras

Summary Eleven STD stations by lowering and raising the sensor were occupied about 170 n. miles northeast of Cape Hatteras in June, 1968. The stations were located in the slope water region covered by the upper warm water from the Gulf Stream. Power spectra of temperature and salinity fluctuations at 1-meter depth intervals were computed versus vertical wave numbers for the upper layer (5–320 m) and lower layer (320–1000 m) at each station. The power law coefficients of the spectra about the vertical wave number are between –5/3 and –3. These coefficients indicate that the temperature and salinity fluctuations are influenced by stratification as well as by turbulence.     

Instabilities in the consumption and production for cobalt

Cobalt is obtained mainly as a byproduct of the mining and metallurgical processing of copper and nickel. The amount of minable cobalt has a characteristic supply limit, which is dependent upon demand for copper and nickel. It is considered that cobalt consumption will be affected by the amount mined in the near future, because world demand has been gradually increasing, while the production from copper sulfide ores in Zaire and Zambia, major producing countries, has decreased for political, economical and technological reasons. The world demand for cobalt has surpassed the world mine production, and cobalt sales from the National Defense Stockpile of the United States and exports from Russia and cobalt recovered from stockpiled intermediates contributed to the supply in 1994. It is concluded, from a statistical point of view, that this trend of shortage and high prices for cobalt will continue in the near future.     

Effects of high-order nonlinear interactions on unidirectional wave trains

Numerical simulations of gravity waves with high-order nonlinearities in two-dimensional domain are performed by using the pseudo spectral method. High-order nonlinearities more than third order excite apparently chaotic evolutions of the Fourier energy in deep water random waves. The high-order nonlinearities increase kurtosis, wave height distribution and H_max/H_1/3 in deep water and decrease these wave statistics in shallow water. Moreover, they can generate a single extreme high wave with an outstanding crest height in deep water. High-order nonlinearities (more than third order) can be regarded as one cause of freak waves in deep water.     

Different thermal preferences for brooding and larval dispersal of two neighboring shrimps in deep‐sea hydrothermal vent fields

Temperature is an important factor affecting the distributions and life‐history traits of marine animals. Deep‐sea hydrothermal vents are suitable environments to examine ecologic differences related to temperature, due to the steep temperature gradients around the vents. Rearing experiments under various temperature conditions (5–30 °C) at atmospheric pressure demonstrated a difference in thermal effects on egg hatching and larva in two co‐occurring, vent‐associated alvinocaridid shrimps – the peripherally distributed Alvinocaris longirostris and the centrally distributed Shinkaicaris leurokolos. The duration before hatching became shorter as temperature increased, while the maximum hatching rate occurred at higher temperatures in S. leurokolos (10–20 °C) than in A. longirostris (10 °C). Hatched larvae of both species were negatively buoyant, and larva with normal abdominal length could actively swim and stay suspended in the mid‐ or surface water layers of the culture plates under our experimental conditions. However, no larvae settled or metamorphosed into juveniles under the rearing conditions used in this study. Larvae with shortened abdomens occurred under most of the experimental conditions, although they were less frequent at 10 °C in A. longirostris and 20 °C in S. leurokolos. The maximum survival periods at these temperatures were 88 days in A. longirostris and 30 days in S. leurokolos. These characteristics may cause differences in the distributional ranges of the two species. The present results indicate that temperature is an important factor controlling life‐history traits of vent shrimps.