Characteristics of ionic components in precipitation in Kitakyushu City,Japan

Precipitation samples were collected by filtrating bulk sampler in Kitakyushu City, Japan, from January 1988 to December 1990. Volume weighted annual mean of pH was 4.93, but the pH distribution indicated that most probable value lay in the range pH 6.0–6.4. Volume weighted annual mean concentrations of major ionic components were as follows; SO ₄ ^2– : 84.2, NO ₃ ^– : 28.1, Cl^–: 86.3, NH ₄ ⁺ : 45.5, Ca²⁺: 63.3, Mg²⁺: 27.0, K⁺: 3.4, Na⁺: 69.0 µ eq l^–1. The highest concentrations of these ionic components were observed in winter and the lowest occurred in the rainy season. The ratio of ex-SO ₄ ^2– /NO ₃ ^– exhibited the lowest ratio in summer, and the highest ratio in winter. Good correlations were obtained between Cl^– and Na⁺, ex-SO ₄ ²⁺ and ex-Ca²⁺, NO ₃ ^– and ex-Ca²⁺, and NH ₄ ⁺ and ex-SO ₄ ^2– , respectively. However, no correlation between Cl^– and Na⁺ with Ca²⁺ was observed. The relationship of H⁺ with (ex-SO ₄ ^2– + NO ₃ ^– ) - (ex-Ca²⁺ + NH ₄ ⁺ ) indicated positive correlation.     

Characteristics of rainfall systems accompanied with Changma front at Chujado in Korea

The rainy season from June to July in the East Asia is called the Changma in Korea, the Meiyu in China, or the Baiu in Japan. The mesoscale convective systems which occur near a front frequently lead to severe weather phenomenon such as localized gust and heavy rainfall. An intensive field experiment was conducted at Chujado (33.95°N, 126.28°E) to find out the characteristics of the precipitating system using information such as the raindrop size distribution, kinematic features during a Changma period between June 21 2007 and July 11 2007. Different characteristics of three identified rainfall cases in a Changma frontal precipitation system occurred from 5 to 6 July in 2007 at Chujado area have been identified. Based on the radar reflectivity and raingage at Chujado, each rainfall system maintained for 7 hours, 4 hours, and 9 hours, respectively. According to the analysis of a total vertical wind shear (TVWS) and a directional vertical wind shear (DVWS), the temperature gradient was the strongest near the surface and both warm and cold advections were occurred in all cases but at different levels. The deep warm advection was related to the longer rainfall lifetime and stronger rainrate, but smaller raindrop size. The unstable atmospheric condition, which has cold advection at the surface and warm advection in higher level, caused the larger size diameter of raindrop. The echo top height of 30 dBZ was around 6 km in the two rainfall systems and around 4 km in the other one. The number concentrations of raindrop has turning point at the drop size of 2 mm in diameter. The stronger (weaker) updraft and downdraft were also related to the decreased number concentration of smaller (larger) size drops and increased that of the larger (smaller) drops.     

Dynamical rupture process on a three-dimensional fault with non-uniform frictions and near-field seismic waves

Summary. Dynamical rupture process on the fault is investigated in a quasi-three-dimensional faulting model with non-uniform distributions of static frictions or the fracture strength under a finite shearing pre-stress. The displacement and stress time functions on the fault are obtained by solving numerically the equations of motion with a finite stress—fracture criterion, using the finite difference method.
If static frictions are homogeneous or weakly non-uniform, the rupture propagates nearly elliptically with a velocity close to that of P waves along the direction of pre-stress and with a nearly S wave velocity in the direction perpendicular to it. The rise time of the source function and the final displacements are larger around the centre of the fault. In the case when the static frictions are heavily non-uniform and depend on the location, the rupture propagation becomes quite irregular with appreciably decreased velocities, indicating remarkable stick-slip phenomena. In some cases, there remain unruptured regions where fault slip does not take place, and high stresses remain concentrated up to the final stage. These regions could be the source of aftershocks at a next stage.
The stick—slip faulting and irregular rupture propagation radiate high-frequency seismic waves, and the near-field spectral amplitudes tend to show an inversely linear frequency dependence over high frequencies for heavily non-uniform frictional faults.     

Performance of dry-separation processes in the recovery of cenospheres from fly ash and their implementation in a recovery unit

Cenospheres recovery is one of the coal fly ash beneficiations, providing economic as well as environmental benefits. Current techniques, such as lagoon or other wet-separation processes, consume large amounts of water and add to water pollution due to leaching of toxic materials from fly ash. The other possible disadvantage is the need for a wide operational area, which is unsuitable for densely populated countries. As wet-separation processes have some disadvantages, an improved and/or sustainable alternative recovery technique is required. An air classifier is one of the alternative techniques. In this study, two types of air classifiers, namely a closed-type pneumatic separator and a micron separator, have been investigated. In terms of separation efficiency, it was found that the micron separator has the potential to be applied in cenospheres recovery from coal fly ash, giving a Newton's efficiency of 0.44, as compared to a value of about 0.26 for the closed-type pneumatic separator. The cenospheres recoveries of both pieces of equipment at their optimum Newton's efficiencies were similar at over 60 wt.%. The separation performance was further assessed from the particle distributions of the overflow and underflow products obtained from both pieces of equipment, as well as from SEM images. It was found that the lower Newton's efficiency of the closed-type pneumatic separator was due to the re-concentration of fine particles in the underflow product at air-flow rates higher than 2.2 m/s (the underflow product yield was about 55 wt.%).In order to further confirm the applicability of this technique, the micron separator, which had provided higher separation efficiency and cenospheres recovery, was deployed in a cenospheres recovery unit prior to the use of a wet-separation process (float and sink tank). About 80% of the cenospheres was recovered, with an 87.8% reduction in the total mass of fly ash to be separated in the float and sink tank. Consequently, much less water was needed for the process of cenospheres recovery. Moreover, it was also confirmed that the micron separator could yield higher quality fly ashes, that is, fly ash types I and II, from lower feed quality of fly ash type IV, which is the lowest category in commercial classification of fly ash according to JIS A6201.     

Integrated magnetobiochronology of the Pliocene–Pleistocene Miyazaki succession,southern Kyushu,southwest Japan: Implications for an Early Pleistocene hiatus and defining the base of the Gelasian (P/P boundary type section) in Japan

An integrated magnetobiochronology of the Miyazaki Pliocene–Pleistocene succession in the Miyazaki area, southwest Japan, was established using planktic foraminiferal and calcareous nannofossil biostratigraphy together with paleomagnetic data. The upper Miyazaki succession in the northern Miyazaki region can be divided into the Takanabe, Hisamine (redefined), and Higoyashiki (new) Formations, in ascending order. A depositional hiatus between the Hisamine Formation and the Takanabe and/or older formations was also identified based on integrated magnetobiostratigraphy from five sections including the Nagatani River (NGT) section through the uppermost Miyazaki succession. The hiatus, herein called the Hisamine unconformity, is equivalent to the Kurotaki unconformity between the Miura and Kazusa groups of the Boso Peninsula in central Japan. The depositional hiatus recognised in the lower Pleistocene of Pacific coastal areas in southwestern and central Japan may have resulted from tectonic activity associated with a change in the subduction direction of the Philippine Sea plate, which commenced prior to ca. 2.2 Ma. The youngest unit just below the hiatus is the upper part of the Takanabe Formation in the NGT section. The NGT section represents the continuous Late Pliocene to earliest Pleistocene sequence including the Gauss/Matuyama boundary and is here proposed as the type section for the Pliocene/Pleistocene boundary in Japan, which the IUGS ratified as the base of the Gelasian in 2009.     

Power spectra of temperature and salinity fluctuations in the slope water off Cape Hatteras

Summary Eleven STD stations by lowering and raising the sensor were occupied about 170 n. miles northeast of Cape Hatteras in June, 1968. The stations were located in the slope water region covered by the upper warm water from the Gulf Stream. Power spectra of temperature and salinity fluctuations at 1-meter depth intervals were computed versus vertical wave numbers for the upper layer (5–320 m) and lower layer (320–1000 m) at each station. The power law coefficients of the spectra about the vertical wave number are between –5/3 and –3. These coefficients indicate that the temperature and salinity fluctuations are influenced by stratification as well as by turbulence.     

Jointing of two tunnel shields using artificial underground freezing

Freezing was used in the jointing section of two shields (diameter 3.14 m) which ran across at right angles and at 25-m depth under the crossing of main roads for the construction of a 2.4-m diameter sewer tunnel. The object of freezing was to create a frozen barrier to prevent the inflow of water and fine sand into the area to be excavated.

Thirty-five freeze pipes (length about 7 m) were placed from one shield conically in the direction of the flank of another shield with freeze pipes attached to its inside wall. The cooling unit was placed on unoccupied land at about 60 m distant from the jointing section and the freeze pipes were connected with the cooling unit by supply and return pipelines.

The cooling unit had a cooling capacity of 79,000 kcal/h at an evaporation temperature of −27°C and a condensation temperature of +40°C. Freezing was continued for 180 days and the CaCl₂ brine temperature was −25 to −30°C. These works were accomplished without the sinking of shaft and the use of injection, in complete safety with no traffic restriction on the road surface.     

Water saturated phase relations of some andesites with application to the estimation of the initial temperature and water pressure at the time of eruption

Near-liquidus phase relations in one-atmosphere dry and water-saturated high pressure conditions were experimentally determined on products of three historic andesitic eruptions. Run conditions ranged from 900 to 1100°C, at pressures up to 1500 bars with fO₂ controlled close to the nickel-nickel oxide (NNO) buffer. In order to represent the compositions of the true liquid parts of the erupting magmas, groundmass portions were mechanically separated from the porphyritic andesites. Such groundmass materials should lie exactly on the liquidus field boundary between the phases precipitating from the magma just prior to eruption under the prevailing P-T condition.All the samples showed a crossing of the plagioclase and orthopyroxene liquidi in the pressure-temperature range from 1 to 800 bar and 950–1090°C. The crossing condition approximates the magmatic condition immediately prior to eruption. In the case of the 1970 eruption of Akita-komagatake, the crossing point is at 150 bar and 1090°C, matching closely the observed explosive gas pressure and the temperature. In both cases of the 1783 eruption of Asama and the 1914–1915 eruption of Sakurajima volcanoes, the crossing point shift from higher water pressure and lower temperature for the earlier erupting magmas to lower pressure and higher temperature for the later magmas. This regularity may be explained by a vertical gradient of the temperature and water content within the magma column prior to eruption.     

New K–Ar ages for calculating end-of-shield extrusion rates at West Maui volcano,Hawaiian island chain

Thirty-seven new K–Ar ages from West Maui volcano, Hawai‘i, are used to define the waning stages of shield growth and a brief episode of postshield volcanism. All but two samples from shield-stage strata have reversed polarity magnetization, so conceivably the exposed shield is not much older than the Olduvai Normal-Polarity subchron, or about 1.8 Ma. The oldest ages obtained are in the range 1.9–2.1 Ma but have large analytical error. Shield volcanism ended about 1.35 Ma, and postshield volcanism followed soon thereafter, persisting until about 1.2 Ma. Exposed shield-stage strata were emplaced at a rate of about 0.001 km³ per year, a rate smaller than historic Hawaiian magmatic rates by a factor of 100. Stratigraphic accumulation rates are similar to those measured previously at Wai‘anae volcano (O‘ahu) or the upper part of the Mauna Kea shield sequence (Hilo drill core, Hawai‘i). These rates diminish sharply during the final 0.3–0.5 m.y. of the shield stage. Hawaiian shield volcanoes begin waning well before their last 0.5 m.y. of life, then end quickly, geologically speaking, if West Maui is representative.     

Influence of the asymmetrical cratering rate on the lunar cratering chronology

The lunar cratering rate studied over the past 1.1 Gyr, which is a foundation of the lunar cratering chronology, is a decreasing function of the angular distance from the apex of the orbital motion due to the synchronous rotation of the Moon. We here evaluate an influence of the asymmetrical rate upon the age determination.