理学ZSX系列X荧光光谱仪中文软件开发

介绍了日本理学ZSX系列X荧光光谱仪的特点和新开发的中文版软件的功能。     

The effect of microorganisms on Fe precipitation rates at neutral pH

The effect of microorganisms on Fe precipitation rates at neutral pH in the field was examined. The studied area was a cave having Fe-stalactites composed mainly of ferrihydrite and associated microorganisms. The microorganisms were covered with ferrihydrite. Water associated with stalactites was slightly supersaturated with respect to ferrihydrite, and had a dissolved oxygen concentration of 2 ppm, a pH of 6, and an Fe concentration of approximately 14 ppm. Fe precipitation rates were estimated from decreases in Fe concentrations in water during flowing through the Fe-stalactites. The estimated Fe precipitation rate in the field ranges from 6.8×10⁻⁸ to 4.0×10⁻⁷ mol/l/s. These values are in good agreement with bulk estimates of Fe-stalactite growth rates derived from the length increase (1.3 cm) of one formation over 30 days. The estimated Fe precipitation rates are faster by about four orders of magnitude than expected inorganic precipitation rates. On-site Fe precipitation experiments with sterilized and unsterilized Fe-stalactites and without Fe-stalactites indicate that microorganisms are the controlling factor accelerating Fe precipitation rates at neutral pH. These results suggest that microbially accelerated Fe precipitation rates are more likely related to exopolysaccharides and microbial surface properties than metabolic precipitation mechanisms.     

Determination of Total Sulfur in Thirty One Geochemical Reference Materials Using an Inductively Coupled Plasma-Atomic Emission Spectrometer Fitted with a Semiconductor Photodiode Detector

The total sulfur contents of thirty one geochemical reference materials were determined using an inductively coupled plasma-atomic emission spectrometer fitted with a semiconductor photodiode detector. Most samples were decomposed using an HF-aqua regia digestion. However, a few were incompletely decomposed by simple acid digestion, and these were decomposed by a fusion method. The agreement between the analytical results from this work and published data is generally good.     

Application of Image Analysis to Observe Microstructure in Sandstone and Granite

Abstract: Advanced techniques are examined to observe microstructure of rocks using image analysis combined with methods such as the fluorescent approach and the application of optical characteristics of minerals. Analyzed are discrimination of grains in rocks, distribution patterns of grain orientation in sandstone, changes of grain shape as weathering advances and distribution patterns of microcracks in granite. In Shirahama sandstone, relatively large and flat grains are orientated parallel to the bedding on the plane perpendicular to the bedding, while grains on the plane parallel to the bedding show random patterns. In weathered granite, it is clarified that the grain surface becomes complex as weathering advances and differences among three major mineral species are identified. In Inada granite, intracrystalline cracks predominate over intercrystalline cracks and grain boundary cracks both in total length and number. Furthermore, three types of microcracks show different orientations; the intercrystalline cracks show a dominant orientation which coincides with the orientation of the rift plane, the easiest plane to split, while the intracrystalline cracks and grain boundary cracks show no preferred orientation.     

京都市中心人口变化与居住可能性分析

本文以日本京都市为研究对象，分析京都市1990年至1997年人口变化持域差异。一般地，城市中心地带人口呈减少趋势，城市外围地带人口呈增长趋势，但是，与城市中心区的一般发展规律相异，位于京都市中心地带、老城区的光德学区，人口社会变化、自然变化都呈现上升的趋势，优越的区位条件，良好的居住环境、适当的住宅类型、相应的居住人群使光德学区具有居住可能性。     

The subsurface transport of heat and moisture and its effect on the environment: A numerical model

A numerical model was developed to study the transport of heat and vapor under the surface of bare soil and soil covered by some materials such as asphalt and concrete under no rainfall conditions. The computational results provide a good match with the experimental data. The results show that the transport of water vapor inside the soil has an important effect on the subsurface distribution of temperature, especially for bare soil. Because of evaporation, the temperature of bare soil is much lower than that under covered surfaces throughout the day and the temperature of the surface covered by asphalt is extremely high-higher than the atmospheric temperature even at night. An increase of thickness of the covering material further increases the temperature and heat stored under surfaces. The stored heat is released to the atmosphere at night, contributing to environmental effects such as the urban heat island.     

Discovery of an ancient tsunami deposit in coastal sequences of southwest Japan: Verification of a large historic tsunami

Abstract A tsunamigenic sand layer is present in coastal sequences of the Masuda Plain, southwest Japan. The radiometric age of the layer has been estimated at 930 ± 80 years BP. It is proposed that the deposit is the product of a large historic tsunami believed to have occurred in the Japan Sea on 16 June 1026 AD.     

Spectroscopic Studies of the Solar Corona – V. Physical Properties of Coronal Structures

Spectra around the 6374 Å [Fex] and 7892 Å [Fexi] emission lines were obtained simultaneously with the 25-cm coronagraph at Norikura Observatory covering an area of 200 ×500 of the solar corona. The line width, peak intensity and line-of-sight velocity for both the lines were computed using Gaussian fits to the observed line profiles at each location (4 ×4 ) of the observed coronal region. The line-width measurements show that in steady coronal structures the FWHM of the 6374 Å emission line increases with height above the limb with an average value of 1.02 mÅ arc sec^–1. The FWHM of the 7892 Å line also increases with height but at a smaller average value of 0.55 mÅ arc sec^–1. These observations agree well with our earlier results obtained from observations of the red, green, and infrared emission lines that variation of the FWHM of the coronal emission lines with height in steady coronal structures depends on plasma temperatures they represent. The FWHM gradient is negative for high-temperature emission lines, positive for relatively low-temperature lines and smaller for emission lines in the intermediate temperature range. Such a behaviour in the variation of the FWHM of coronal emission lines with height above the limb suggests that it may not always be possible to interpret an increase in the FWHM of emission line with height as an increase in the nonthermal velocity, and hence rules out the existence of waves in steady coronal structures.     

Concentrations of Trace Elements in Carbonate Reference Materials Coral JCp-1 and Giant Clam JCt-1 by Inductively Coupled Plasma-Mass Spectrometry

Trace elements in the Geological Survey of Japan carbonate reference materials Coral JCp-1 and Giant Clam JCt-1 were determined by inductively coupled plasma-mass spectrometry after digestion with 2% v/v HNO₃. A standard addition method was adopted in this determination in order to neutralise the Ca matrix effect. In addition, Sc, Y, In and Bi were used as internal standards to control the matrix effect and correct instrumental drift. Of the eighteen elements measured in JCp-1, precisions for fourteen elements, including Cu, Cd and Ba, were better than 10% RSD and concentrations ranged from 0.002 μg g^-1 (Cs) to 8.02 μg g^-1 (Ba). The concentrations of measured trace elements in JCt-1, except for Cu, were lower than those in JCp-1. Precisions for all elements with concentrations higher than 0.04 μg g^-1 in JCt-1 were also better than 10% RSD and concentrations were found to be between 0.001 μg g^-1 (Cs) and 4.84 μg g^-1 (Ba). The concentrations of more than fifteen trace elements in the aragonite reference materials are reported here for the first time. Both reference materials are suitable for use in geochemical studies of environmental reconstruction based upon biogenic carbonate materials.