Historical record of heavy metal pollution deduced by lead isotope ratios in core sediments from the Osaka Bay,Japan

Three marine sediment cores from Osaka Bay were analyzed for ²¹⁰Pb geochronology, heavy metal concentrations (Zn, Cu, and Pb) and stable lead isotope ratios (²⁰⁶Pb/²⁰⁷Pb) in order to reconstruct high-resolution heavy metal pollution history from 1900–2006. Anthropogenic metal accumulation in sediments peaked in 1970 in agreement with the high economic growth period in Japan. The comparison of temporal patterns of ²⁰⁶Pb/²⁰⁷Pb ratio with other areas of Japan suggested that the heavy metals, imported from several different countries during the periods of economic growth (1955 to 1973), are the main pollution source for the country. For the period 1970–2006, the sediment data reflect the result of stricter environmental regulations applied after the late 1960s. However, heavy metal concentrations in the surface sediments are still elevated to levels several times higher than the levels at the bottoms of the cores. Additionally, the lead isotope ratio does not show significant change after the 1980s. Secondary heavy metal pollution through the mixing of deeper polluted sediment appears to be the likely reason for the deterioration of present time submarine sediment environments. In conclusion, this study has demonstrated that it is difficult to recover over a period of several years the benthic quality of a bay, once it is heavily polluted.     

Mineralogical and spectroscopic characterization,and potential environmental use of limestone from the Abiod formation,Tunisia

Limestone beds of the Late Cretaceous Abiod formation (Campanian-Maastrichtian system) are fundamentally important for the economic growth of the raw material sector in Tunisia. However, little attention has been paid to the detailed physical and chemical properties of the Abiod limestone. Nine limestone samples collected from the Abiod formation outcropping in the areas of Bizerte, Gafsa and Gabes, Tunisia, as well as their separated clay fractions, were characterized using different techniques, such as XRF, XRD, FTIR and TG/DTA. XRF showed the chemical composition of the limestone in which calcium carbonate was the main constituent, and silica, iron and magnesium were the impurities. XRD also confirmed the presence of small amounts of clay minerals and quartz along with sharp peaks of calcite. FTIR spectra indicated that the limestone was mainly composed of CaCO₃ in the form of calcite, as identified by its main characteristic absorption bands. These data were in agreement with XRD and XRF analysis data. The TG/DTA curves of the limestone samples, showing a close similarity to that of pure calcium carbonate, exhibited an endothermic peak between 600 and 760°C, with the maximum near 750°C. Moreover, FTIR spectra of clay fraction samples indicated high silica content in some samples. Especially the samples SD1 and SD2 collected in the northern area showed higher amounts of silica compared with those of AS1, AS2, CHB, ZNC, SND, MKM and GBS collected from southern districts. However, among the latter seven samples, one could recognize two groups based on the clay mineral investigations: (1) limestone with minor amounts of smectite and mixed layer minerals of smectite/illite (AS1 and 2, CHB, ZNC, SND and GBS) and (2) limestone with smectite, kaolinite and apatite (SND and MKM). Differences in these mineralogical and chemical characteristics should be considered when limestone from the Abiod formation is utilized as a medium for heavy metal removal from wastewater.     

Global mantle heterogeneity and its influence on teleseismic regional tomography

A new global P-wave tomography model is determined using a flexible-grid parameterization. This new model better reveals the mantle structure under the polar regions than the previous tomographic models. The subducting slabs are generally imaged clearly as high-velocity (high-V) zones. The young slabs are still subducting in the upper mantle and the mantle transition zone (MTZ), whereas the old and ancient slabs are either stagnant in the MTZ or have subducted down to the lower mantle, even reaching the core-mantle boundary. Low-velocity (low-V) anomalies are generally revealed in the mantle under the hotspot regions. It seems that a variety of mantle upwelling (plumes) exist. Some strong plumes are visible in the whole mantle under the long-living hotspots, such as those in south-central Pacific, Africa, Hawaii and Iceland, whereas weak plumes are visible in only some depth range under the minor hotspots. Under the intraplate volcanoes in East Eurasia, Bering Sea and West Alaska, significant low-V anomalies are revealed in the upper mantle, which may reflect hot and wet upwelling associated with corner flows in the big mantle wedge (BMW) above the stagnant Pacific slab in the MTZ and perhaps deep slab dehydration as well. The subduction-triggered magmatism in the BMW may be a new class of mantle plumes. We also used the new global model to investigate the influence of whole-mantle heterogeneity on the determination of upper-mantle tomography under Japan with a teleseismic inversion method. The results show that the mantle heterogeneities outside the target volume of regional tomography can cause significant changes (~ 0.2-0.4 s) to the observed relative travel-time residuals of a distant earthquake. The pattern of regional tomography remains the same even after correcting for the whole-mantle heterogeneity, but there are some changes in the amplitude of velocity anomalies in the regional tomography. Hence it is necessary to correct for the mantle heterogeneities outside the target volume so as to obtain a better regional tomography.     

Rainfall–runoff–inundation analysis of the 2010 Pakistan flood in the Kabul River basin

Abstract

Pakistan has suffered a devastating flood disaster in 2010. In the Kabul River basin (92 605 km²), large-scale riverine and flash floods caused destructive damage with more than 1100 casualties. This study analysed rainfall–runoff and inundation in the Kabul River basin with a newly developed model that simulates the processes of rainfall–runoff and inundation simultaneously based on two-dimensional diffusion wave equations. The simulation results showed a good agreement with an inundation map produced based on MODIS for large-scale riverine flooding. In addition, the simulation identified flash flood-affected areas, which were confirmed to be severely damaged based on a housing damage distribution map. Since the model is designed to be used even immediately after a disaster, it can be a useful tool for analysing large-scale flooding and to provide supplemental information to agencies for relief operations.

Editor Z.W. Kundzewicz

Citation Sayama, T., Ozawa, G., Kawakami, T., Nabesaka, S. and Fukami, K., 2012. Rainfall–runoff–inundation analysis of the 2010 Pakistan flood in the Kabul River basin. Hydrological Sciences Journal, 57 (2), 298–312.     

Olivine-rich exposures in the South Pole-Aitken Basin

The distribution and the geological context of the olivine-rich exposures in the South Pole-Aitken (SPA) Basin on the Moon were investigated based on the spectral data obtained from the Spectral Profiler (SP) and Multiband Imager (MI) onboard the Japanese lunar explorer Kaguya/SELENE. The olivine-rich exposures are found only in the peak rings or central peaks of the Schrödinger basin and Zeeman crater, which are located in the outer region of the SPA Basin and not in the center region. On a localized scale, the olivine-rich materials are exposed on landslide features on the crater walls or sloped wall of the central peaks or the peak rings. Another observational finding is the co-existence of olivine-rich and plagioclase-rich materials on a kilometer scale spanning most of the olivine-rich sites in the Schrödinger basin. Pyroxene-rich materials are found in fresh craters outside the peak rings or the central peaks with olivine-rich materials. Based on these results, the following scenario are proposed: (1) the impact to form the SPA Basin melted a large amount of the lunar upper mantle and crust, and distributed the melted materials to the outer region; (2) local differentiation of melted materials hid the olivine-rich materials in the center region of the SPA Basin; (3) later impacts that formed the Schrödinger and Zeeman craters excavated and exposed the olivine-rich materials to the surface again; and (4) space weathering and regolith gardening obscured the olivine-rich spectra at the exposure sites, but recent, small scale impacts or landslides on the sloped wall exposed fresh olivine-rich materials, allowing the identification of the olivine-rich exposures by spectral remote-sensing. This suggests that several, different scale events play an important role in forming the surface distributions of originally deep-seated materials on the Moon, as well as on other planetary bodies.     

Projection of extreme flood inundation in the Mekong River basin under 4K increasing scenario using large ensemble climate data

Projecting changes in the frequency and intensity of future precipitation and flooding is critical for the development of social infrastructure under climate change. The Mekong River is among the world's large-scale rivers severely affected by climate change. This study aims to define the duration of precipitation contributing to peak floods based on its correlation with peak discharge and inundation volume in the Lower Mekong Basin (LMB). We assessed the changes in precipitation and flood frequency using a large ensemble Database for Policy Decision-Making for Future Climate Change (d4PDF). River discharge in the Mekong River Basin (MRB) and flood inundation in the LMB were simulated by a coupled rainfall-runoff and inundation (RRI) model. Results indicated that 90-day precipitation counting backward from the day of peak flooding had the highest correlation with peak discharge (R² = .81) and inundation volume (R² = .81). The ensemble mean of present simulation of d4PDF (1951–2010) showed good agreement with observed extreme flood events in the LMB. The probability density of 90-day precipitation shifted from the present to future climate experiments with a large variation of mean (from 777 to 900 mm) and SD (from 57 to 96 mm). Different patterns of sea surface temperature significantly influence the variation of precipitation and flood inundation in the LMB in the future (2051–2110). Extreme flood events (50-year, 100-year, and 1,000-year return periods) showed increases in discharge, inundation area, and inundation volume by 25%–40%, 19%–36%, and 23%–37%, respectively.     

Field measurements of absolute gravity in East Antarctica

Abstract This paper reports the results of field-based absolute gravity measurements aimed at detecting gravity change and crustal displacement caused by glacial isostatic adjustment. The project was initiated within the framework of the 53rd Japanese Antarctic Research Expedition （JARE53）. Absolute gravity measurements, together with GPS measurements, were planned at several outcrops along the Prince Olav Coast and S6ya Coast of East Antarctica, including at Syowa Station. Since the icebreaker Shirase （AGB 5003） was unable to moor alongside Syowa Station, operations were somewhat restricted during JARE53. However, despite this setback, we were able to complete measurements at two sites： Syowa Station and Langhovde. The absolute gravity value at the Syowa Station IAGBN （A） site, observed using an FG-5 absolute gravimeter （serial number 210; FG-5 #210）, was 982 524 322.7＋0.1 ktGal, and the gravity change rate at the beginning of 2012 was -0.26 gGal.a-1. An absolute gravity value of 982 535 584.2~0.7 ktGal was obtained using a portable A-10 absolute gravimeter （serial number 017; A-10 #017） at the newly located site AGS01 in Langhovde.