Temporal and Spatial Dynamics of Diel-Cycling Hypoxia in Estuarine Tributaries

The distribution and intensity of hypoxia (low dissolved oxygen) in estuaries is increasing worldwide due to cultural eutrophication. This study quantifies the strength of associations between the duration of diel-cycling severe hypoxia (≤2 mg O₂ l⁻¹) in bottom water (∼15 cm above bottom) of a shallow (<2 m) coastal lagoon estuary (Delaware, USA) and abiotic environmental variables (water temperature, insolation, tide, streamflow, and wind) and predicts the duration of severe hypoxia given different combinations of these variables. The intensity and spatial extent and dynamics of diel-cycling severe hypoxia events were defined. Vertical variability in dissolved oxygen (DO) concentration during the daytime was also determined. During the summers of 2001–2005, bottom DO data were collected for periods of weeks to months at multiple sites using automated sondes. Multiple linear regression (MLR) and regression tree analysis (RTA) were used to determine the relative importance of the environmental variables in predicting the number of hours of severe hypoxia per day. Key findings of the study were that severe hypoxia events of minutes to hours in duration occurred frequently in all four tributaries sampled, primarily between 0200 and 1000 hours. Severe hypoxia duration and diel-cycling amplitudes of DO concentration increased in the up-tributary direction. Hierarchically, the duration of severe hypoxia was influenced mostly by the mean daily water temperature, then by preceding days’ total insolation, percentage of morning hours (02:00 to 10:00 a.m.) ebb tide, and daily streamflow. Collectively, the variables examined by the MLR and the RTA approaches accounted for 62% and 65% of the variability in the duration of severe hypoxia, respectively. RTA demonstrated that daily mean water temperature above 26.3°C and previous day’s total insolation below 13.6 kW m⁻² were associated with the longest lasting severe hypoxic events (9.56 h). The environmental variables and combinations of conditions that modulate or augment diel-cycling hypoxia presented in this paper enhance understanding of this widespread and growing phenomenon and provide additional insight regarding the extent to which it can impact food webs in very shallow estuarine waters that often serve as nursery habitat.     

Relation between temperature changes of the mid-upper troposphere over Eurasian mid-high latitudes and solar irradiance in the twentieth century

The δ¹⁸O data obtained from an 18.7 m ice core drilled in Chongce Ice Cap at an elevation of 6,530 m a.s.l. in the West Kunlun Mountains on the northern Tibetan Plateau show a strong correlation with the summer temperature of the middle to upper troposphere over the mid-high latitudes of Eurasia. Based on this, the δ¹⁸O record can be used as a proxy of the June–September mean temperature of the mid-upper troposphere (MUT) from 1903 to 1992. The time span of the ice core record is much longer than the meteorological data available only after 1948. Using the empirical mode decomposition method (EMD), the δ¹⁸O record is decomposed into various frequency components and compared with the solar irradiance variations of the same period. The results show that (1) The June–September mean temperature of the MUT over Eurasian mid-high latitudes is completely decomposed into four IMF (intrinsic mode function) components and an increasing trend. (2) Solar irradiance is decomposed into the Schwabe cycle, the Hale cycle, the Gleissberg cycle, and an increasing trend. (3) The correlation coefficients between the June and September mean temperatures of the MUT over Eurasian mid-high latitudes and solar irradiance on the longer timescales (at least more than 11-year) show the significant correlations; their phase changes are basically identical in general, and (4) the 11-year Schwabe cycle exists in the June–September mean temperature of the MUT over Eurasian mid-high latitudes during most of the time from 1903 to 1992, and only in the two high-temperature phases (1929–1944 and from 1975 to the present) may global warming disturb this relation. A full understanding of this phenomenon would shed insight into the potential consequence of global warming on the MUT.     

PLL Tracking Performance in the Presence of Oscillator Phase Noise

The tracking performance of a Phase Lock Loop (PLL) is affected by the influence of several error sources. In addition to thermal noise and dynamic stress error, oscillator phase noise can cause significant phase jitter which degrades the tracking performance. Oscillator phase noise is usually caused by two different effects: Allan deviation phase noise is caused by frequency instabilities of the receiver's reference oscillator and the satellite's frequency standard. It can be termed as system-inherent phase noise and is relevant for both static and dynamic applications. “External” phase noise, however, is caused by vibration and is a major problem for dynamic applications. In the context of this paper, both types of phase noise will be modeled and the resulting integrals will be evaluated for PLLs up to the third order. Besides, phase jitter induced by thermal noise and signal dynamics will also be discussed, thus providing all necessary formulas for analyzing the performance of a phase lock loop in case of different forms of stress. Since the main focus is centered on the effects of oscillator phase noise, the overall PLL performance is graphically illustrated with and without consideration of oscillator phase noise. © 2002 Wiley Periodicals, Inc.     

Evaluation of the effect of river style framework on water quality: application of geomorphological factors

The Tarwal River basin with an area of 6560.20 km² is located in the eastern part of Iranian Kurdistan Province. This river crosses the Qorveh and Dehgolan plains and joins the Ghezel Ozan River in Zanjan Province. The importance of this river as a source for drinking water and agricultural and industrial uses in the region necessitates the need for research in this field. The main purpose of this study is to identify the natural features of the riverbed from the perspective of river geomorphology and to investigate their impact on water quality and river self-purification capacity. To achieve this, the river style framework was employed. To investigate the effects of each style framework on the river, a total of 20 samples from the entrance and outlet of styles were obtained using Impact Assessment method and sampling standards which were later analyzed for their quality parameters including T, pH, EC, TDS, TSS, Na, Ca, Mg, K, Cl, F, NO₂, NO₃, SO₄, PO₄, DO, COD and BOD. The results indicated that the changes in the styles lead to changes in water quality and the impact of each style is greater on the physical parameters than the chemical parameters. The river self-purification capacity varied depending on the style. The maximum and the minimum self-purifications occurred in fine-grained Anabranching and low-sinuosity fine-grained styles, respectively.     

Output-only identification of the modal and physical properties of structures using free vibration response

The viability of a complete structural characterization of civil structures is explored and discussed. In particular, the identification of modal (i.e. natural frequencies, damping ratios and modal shapes) and physical properties (i.e. mass and stiffness) using only the structure’s free decay response is studied. To accomplish this, modal analysis from free vibration response only (MAFVRO) and mass modification (MM) methodologies are engaged along with Wavelet based techniques for optimal signal processing and modal reconstruction. The methodologies are evaluated using simulated and experimental data. The simulated data are extracted from a simple elastic model of a 5 story shear building and from a more realistic nonlinear model of a RC frame structure. The experimental data are gathered from shake table test of a 2-story scaled shear building. Guidelines for the reconstruction procedure from the data are proposed as the quality of the identified properties is shown to be governed by adequate selection of the frequency bands and optimal modal shape reconstruction. Moreover, in cases where the structure has undergone damage, the proposed identification scheme can also be applied for preliminary assessment of structural health.     

Simplification and Validation of a Spectral-Tensor Model for Turbulence Including Atmospheric Stability

A spectral-tensor model of non-neutral, atmospheric-boundary-layer turbulence is evaluated using Eulerian statistics from single-point measurements of the wind speed and temperature at heights up to 100 m, assuming constant vertical gradients of mean wind speed and temperature. The model has been previously described in terms of the dissipation rate \(\epsilon \), the length scale of energy-containing eddies \(\mathcal {L}\), a turbulence anisotropy parameter \(\varGamma \), the Richardson number Ri, and the normalized rate of destruction of temperature variance \(\eta _\theta \equiv \epsilon _\theta /\epsilon \). Here, the latter two parameters are collapsed into a single atmospheric stability parameter z / L using Monin–Obukhov similarity theory, where z is the height above the Earth’s surface, and L is the Obukhov length corresponding to \(\{Ri,\eta _\theta \}\). Model outputs of the one-dimensional velocity spectra, as well as cospectra of the streamwise and/or vertical velocity components, and/or temperature, and cross-spectra for the spatial separation of all three velocity components and temperature, are compared with measurements. As a function of the four model parameters, spectra and cospectra are reproduced quite well, but horizontal temperature fluxes are slightly underestimated in stable conditions. In moderately unstable stratification, our model reproduces spectra only up to a scale \(\sim \) 1 km. The model also overestimates coherences for vertical separations, but is less severe in unstable than in stable cases.     

The Natural Hazards Theme of the International Year of Planet Earth

The United Nations has declared 2008 to be the International Year of Planet Earth. It is being organised under the auspices of the International Union of Geological Sciences and UNESCO. Planning for the International Year of Planet Earth has consisted of establishing 10 major science themes including Hazards. The Hazards Theme is centred around the following key questions: (1) How have humans altered the geosphere, the biosphere and the landscape, thereby creating long-term changes detrimental to life and the environment and triggering certain hazards, while increasing societal vulnerability to geophysical (geological and hydrometeorological) hazards? (2) What technologies and methodologies are required to assess the vulnerability of people and places to hazards and how might these be used at a variety of spatial scales? (3) How do geophysical hazards compare relative to each other regarding current capabilities for monitoring, prediction and mitigation and what can be done in the short-term to improve these capabilities (4) What barriers exist to the utilisation of risk and vulnerability information by governments (and other entities) for risk and vulnerability reduction policies and planning (including mitigation) from each of the geophysical hazards? Following the 26 December 2004 Indian Ocean Tsunami and the UN World Conference on Disaster Reduction held in Kobe, Japan in January 2005, the International Council for Science (ICSU) decided to establish a major research programme and initiative on Natural and Human Induced Environmental Hazards and Disasters that will co-operate with the Hazards theme of the International Year and continue through to 2011.     

Analysis of radial movement of an unconfined leaky aquifer due to well pumping and injection

Radial movement of an unconfined leaky aquifer was studied with respect to hydraulic forces that are induced by well recharge and discharge. New analytic solutions in the velocity and displacement fields were found and applied to describe transient movement in an unconfined leaky aquifer. Linear momentum and mass balance of saturated porous sediments, the Darcy-Gersevanov law, and the analytic solution of hydraulic drawdown for unsteady flow within the unconfined leaky aquifer were introduced to find the new solutions. Analytic results indicate that the nonlinear relation between the initial hydraulic head (h₀) and the well function has an insignificant effect on the aquifer transient movement when the drawdown s<0.02h ₀. When the well function is simplified with different assumptions and pumping conditions, the new solutions correspondingly reduce to cases that are similar to the Hantush-Jacob, Muskat, and Theis transient movement of a confined leaky aquifer. It was found that large leakance is important in slowing radial movement and reducing aquifer deformation. Flow velocity in the aquifer is more responsive to leakance than to cumulative displacement within the aquifer. The zones and boundary with tensile stress can be located using the same approach applied to a confined aquifer for risk assessment of earth fissuring.

---

Résumé Le mouvement radial dans un aquifère semi-perméable libre a été étudié en considérant les forces hydrauliques induites par la recharge et le prélèvement au niveau d’un puits. De nouvelles solutions analytiques des champs de vitesse et de déplacement ont été trouvées et appliquées pour décrire le mouvement transitoire dans un aquifère semi-perméable libre. Pour trouver les nouvelles solutions, le moment linéaire et le bilan de masse dans les sédiments poreux saturés, la loi de Darcy-Gersevanov, et la solution analytique du rabattement hydraulique pour un écoulement transitoire dans un aquifère semi-perméable libre sont pris en compte. Les résultats analytiques montrent que la relation non-linéaire entre le potentiel hydraulique initial (h₀) et la fonction de puits a un effet insignifiant sur le mouvement transitoire de l’aquifère quand le rabattements s <0.02h₀. Si la fonction de puits est simplifiée en tenant compte de différentes hypothèses et conditions de pompage, les nouvelles solutions se réduisent en conséquence à des cas similaires au mouvement transitoire dans un aquifère semi-perméable captif selon Hantush-Jacob, Muskat, et Theis. Il s’est avéré qu’une drainance élevée est importante pour le ralentissement du mouvement radial et la réduction de la déformation de l’aquifère. La vitesse d’écoulement dans l’aquifère est plus sensible à la drainance qu’au déplacement cumulé dans l’aquifère. Les zones et la frontière présentant des contraintes de traction peuvent être localisées en utilisant la même approche appliquée à un aquifère captif pour l’évaluation des risques de fissuration du sol.

---

Resumen Se ha estudiado el movimiento radial en un acuífero no confinado con fuga en relación a las fuerzas hidráulicas que son inducidas por la descarga y recarga del pozo. Se encontraron nuevas soluciones analíticas en los campos de desplazamiento y velocidad, las cuales se aplicaron para describir el movimiento transitorio en un acuífero no confinado con fuga. Se han introducido cálculos de balance de masa y momentum lineal de los sedimentos porosos saturados, la Ley Darcy-Gersevanov, y la solución analítica de descenso hidráulico para flujo sin régimen permanente dentro del acuífero no confinado con goteo para encontrar las nuevas soluciones. Los resultados analíticos indican que la relación no lineal entre la presión hidráulica inicial (h₀) y la función del pozo tiene efecto insignificante en el movimiento transitorio del acuífero cuando el descenso s < 0.02h₀. Cuando se simplifica la función del pozo en base a diferentes supuestos y condiciones de bombeo se reducen las nuevas soluciones a casos que son similares a el movimiento transitorio Hantush-Jacob, Muskat, y Theis de un acuífero confinado con goteo. Se encontró que las fugas grandes son importantes en la disminución del movimiento radial y en la reducción de la deformación del acuífero. La velocidad de flujo en el acuífero responde más a las fugas que al desplazamiento acumulativo dentro del acuífero. Pueden localizarse zonas y límites con esfuerzos tensionales usando el mismo enfoque aplicado a acuíferos confinados para evaluación de riesgo de generación de fracturas en el terreno.

---

     

Photochemical characteristics of high and low ozone episodes observed in the Taehwa Forest observatory (TFO) in June 2011 near Seoul South Korea

We present a comprehensive discussion on what cause high ozone episodes at a suburban photochemical observation site of the Seoul Metropolitan Area (population ～23 million). The observational site, Taehwa Research Forest (TRF), is situated ～30 km from the center of Seoul. In June 2011, we observed two very distinctive ozone periods-high ozone (peak up to 120 ppbv) and low ozone (peak up to 60 ppbv) in the mid and early month, respectively. The trace gas measurement dataset, especially CO and NO _X clearly indicate that less anthropogenic influences during the high ozone period. Volatile organic compound (VOC) measurement results show that at the observational site, biogenic VOCs (mostly isoprene) contribute most of chemical reactivity towards OH, although toluene from anthropogenic activities was observed in higher concentrations. Back-trajectory analysis indicates that air-masses from the forest part of Korea Peninsula were dominant influences during the high ozone episode event. On the other hand, Aged air masses from China were the dominant influence during the low ozone episode event. Model calculations conducted using the University of Washington Chemical Mechanism (UWCM) box model, also consistently show that BVOC, especially isoprene photochemistry, can be the significantly contribution to local ozone formation in the given photochemical environments of TRF. These research results strongly suggest that ozone control strategy in the Eastern Asian megacities, mostly situated in surrounding forest areas should be based on the comprehensive scientific understanding in BVOC photochemistry and interplays between anthropogenic and biogenic interactions.