Groundwater arsenic contamination in Manipur,one of the seven North-Eastern Hill states of India: a future danger

Manipur State, with a population of 2.29 million, is one of the seven North-Eastern Hill states in India, and is severely affected by groundwater arsenic contamination. Manipur has nine districts out of which four are in Manipur Valley where 59% of the people live on 10% of the land. These four districts are all arsenic contaminated. We analysed water samples from 628 tubewells for arsenic out of an expected total 2,014 tubewells in the Manipur Valley. Analyzed samples, 63.3%, contained >10 μg/l of arsenic, 23.2% between 10 and 50 μg/l, and 40% >50 μg/l. The percentages of contaminated wells above 10 and 50 μg/l are higher than in other arsenic affected states and countries of the Ganga–Meghna–Brahmaputra (GMB) Plain. Unlike on the GMB plains, in Manipur there is no systematic relation between arsenic concentration and the depth of tubewells. The source of arsenic in GMB Plain is sediments derived from the Himalaya and surrounding mountains. North-Eastern Hill states were formed at late phase of Himalaya orogeny, and so it will be found in the future that groundwater arsenic contamination in the valleys of other North-Eastern Hill states. Arsenic contaminated aquifers in Manipur Valley are mainly located within the Newer Alluvium. In Manipur, the high rainfall and abundant surface water resources can be exploited to avoid repeating the mass arsenic poisoning that has occurred on the GMB plains.     

Large are variability in climate-based soil moisture estimates and implications for remote sensing

Although the basic physical relationships between various remotely sensed signatures and soil are sound, the representativeness of pixel-averaged wetness used to interpret the remotely sensed data is often suspect and at times even doubtful. To study the affect of local variation in soil moisture on the large-area average, mean areal precipitation, temperature and modelled soil moisture in 1/4° grid cells were analyzed for a 700 km by 400 km region in the US Southern Great Plains. Variability in five years of mean daily grid cell data was investigated for 150 km² study sites, approximately corresponding in size to a satellite microwave pixel. The number of wetted grid cells and the magnitude of precipitation in grid cells within a site were highly variable. The variability of each of these factors is critical, and will not only influence mean site wetness, but also how the area will be seen from space. Analysis indicated that similar mean site precipitation values may result from numerous widely differing combinations of precipitation magnitude and watted gric cell population. Consequently, mean site moisture is also highly variable in the distribution and magnitude of the individual cell moisture values. Extreme values in several grid cells may severely bias the quadrant mean, while influencing a remote measurement much less. Although large-scale surface wetness may eventually be reliably inferred from satellite measurements, a degree of uncertainty will always exist, especially in semi-arid areas. One may be required to associate mean soil moisture with an expected distribution of wetness within a pixel.     

An Ar–Ar laser-probe study of pseudotachylites in charnockite gneisses from the Cauvery Shear Zone system, South India

The age of pseudotachylite formation in the crustal-scale Cauvery Shear Zone system of the Precambrian Southern Granulite Terrain (South India) has been analyzed by laser-probe ⁴⁰Ar–³⁹Ar dating. Laser spot analyses from a pseudotachylite from the Salem–Attur shear zone have yielded ages ranging from 1214 to 904 Ma. Some evidence for the presence of excess Ar is indicated by the scatter of ages from this locality. The host gneiss preserves Palaeoproterozoic Rb–Sr whole rock–biotite ages (2350 ± 11 to 2241 ± 11 Ma). A mylonite in the Koorg shear, ca. 200 km to the north, yielded an age of 895 ± 17 Ma the consistency of the age distribution from spot analyses precludes the presence of significant excess Ar. Despite published evidence for the growth of high-grade minerals within some components of the Cauvery Shear Zone during the Pan-African event (700–550 Ma), the pseudotachylites in this study provide no evidence for Pan-African formation. Instead they document the first evidence for Mesoproterozoic tectonism in the Cauvery Shear Zone system, thus prompting a review of the correlation between the Cauvery Shear Zone system and the large-scale shear zones located elsewhere in eastern Gondwana.     

Groundwater arsenic contamination and its health effects in India

During a 28-year field survey in India (1988–2016), groundwater arsenic contamination and its health effects were registered in the states of West Bengal, Jharkhand, Bihar and Uttar Pradesh in the Ganga River flood plain, and the states of Assam and Manipur in the flood plain of Brahamaputra and Imphal rivers. Groundwater of Rajnandgaon village in Chhattisgarh state, which is not in a flood plain, is also arsenic contaminated. More than 170,000 tubewell water samples from the affected states were analyzed and half of the samples had arsenic >10 μg/L (maximum concentration 3,700 μg/L). Chronic exposure to arsenic through drinking water causes various health problems, like dermal, neurological, reproductive and pregnancy effects, cardiovascular effects, diabetes mellitus, diseases of the respiratory and gastrointestinal systems, and cancers, typically involving the skin, lungs, liver, bladder, etc. About 4.5% of the 8,000 children from arsenic-affected villages of affected states were registered with mild to moderate arsenical skin lesions. In the preliminary survey, more than 10,000 patients were registered with different types of arsenic-related signs and symptoms, out of more than 100,000 people screened from affected states. Elevated levels of arsenic were also found in biological samples (urine, hair, nails) of the people living in affected states. The study reveals that the population who had severe arsenical skin lesions may suffer from multiple Bowens/cancers in the long term. Some unusual symptoms, such as burning sensation, skin itching and watering of eyes in the presence of sun light, were also noticed in arsenicosis patients.     

Sedimentation of particulate matter in the Dona Paula Bay, West Coast of India during November to May 1995–1997

Data on hydrography, nutrients, suspended particles, and sedimented particles were collected at weekly intervals from November to May during 1995 to 1997 at a station in the coastal waters of Dona Paula Bay, India. Suspended and sedimented particles were analyzed for total suspended matter (SPM), total sedimented particulate matter (TPM), particulate organic carbon (POC), particulate organic nitrogen (PON), chlorophylla (chla), and diatom abundance. Variations in hydrography and nutrients influenced the quantity and composition of sedimented particles. The TPM, POC, PON, and chla fluxes showed small-scale seasonal variations and were higher in the summer (February to May) than in the winter (November to January). Resuspension of carbon accounted for approximately 25% of the gross POC and was highest in April 1997 (45%). The mean net POC flux was 197±90 mg C m⁻² d⁻¹ and accounts for 4.6% of the TPM. The average C∶N (w∶w) ratio of the sedimented material was 13.2±6.6. The POC:chla ratio was relatively higher in the sedimented material as compared to the suspended material. The particulate carbon reaching the bottom sediment was 39% of the primary production. The low organic carbon concentration (approximately 0.1% of dry sediment) in the sediments implies that about 98% of the sedimented carbon was either consumed at the sedimentwater interface or resuspended/advected before it was finally buried into the sediments.     

Changes in event-based streamflow magnitude and timing after suburban development with infiltration-based stormwater management

Green stormwater infrastructure implementation in urban watersheds has outpaced our understanding of practice effectiveness on streamflow response to precipitation events. Long-term monitoring of experimental suburban watersheds in Clarksburg, Maryland, USA, provided an opportunity to examine changes in event-based streamflow metrics in two treatment watersheds that transitioned from agriculture to suburban development with a high density of infiltration-focused stormwater control measures (SCMs). Urban Treatment 1 has predominantly single family detached housing with 33% impervious cover and 126 SCMs. Urban Treatment 2 has a mix of single family detached and attached housing with 44% impervious cover and 219 SCMs. Differences in streamflow-event magnitude and timing were assessed using a before-after-control-reference-impact design to compare urban treatment watersheds with a forested control and an urban control with detention-focused SCMs. Streamflow and precipitation events were identified from 14 years of sub-daily monitoring data with an automated approach to characterize peak streamflow, runoff yield, runoff ratio, streamflow duration, time to peak, rise rate, and precipitation depth for each event. Results indicated that streamflow magnitude and timing were altered by urbanization in the urban treatment watersheds, even with SCMs treating 100% of the impervious area. The largest hydrologic changes were observed in streamflow magnitude metrics, with greater hydrologic change in Urban Treatment 2 compared with Urban Treatment 1. Although streamflow changes were observed in both urban treatment watersheds, SCMs were able to mitigate peak flows and runoff volumes compared with the urban control. The urban control had similar impervious cover to Urban Treatment 2, but Urban Treatment 2 had more than twice the precipitation depth needed to initiate a flow response and lower median peak flow and runoff yield for events less than 20 mm. Differences in impervious cover between the Urban Treatment watersheds appeared to be a large driver of differences in streamflow response, rather than SCM density. Overall, use of infiltration-focused SCMs implemented at a watershed-scale did provide enhanced attenuation of peak flow and runoff volumes compared to centralized-detention SCMs.     

Effective utilization of seismic reflection technique with moderate cost in uranium exploration

In participation with numerous industrial partners, the Seismic Laboratory of the University of Saskatchewan has conducted a variety of active seismic reflection experiments; both on the west and east sides of the Athabasca Basin. Results of the investigations at Shea Creek, McArthur River and Keefe Lake illustrate that the seismic investigations deliver effective, highly relevant primary structural images of the subsurface, with resolution that no other geophysical technique can match. Correlation of similar seismic signatures, on several distant but inter-related seismic sections, allowed spatial extension of promising exploration target zones previously unrecognized. Within the three-dimensional seismic volume, comparable reflectivity patterns defined the complex areal distribution of mineralization-related fault systems. Beyond these novel contributions, extended analysis of seismic signal attributes (amplitude and frequency), optical televiewer, and full-wave sonic data offer detailed lithological characterization, including alteration zones, clay content, as well as porosity and fracture density information. Although these structural and geologically relevant anomalies are primary indicators of mineralization, presenting novel exploration advantages, the seismic method is still not a standard component of the Athabasca Basin exploration approach, due to the negative perception that ‘it is very expensive’. Comparing the costs of all geophysical techniques to the cost of a single logged drill hole illustrates that the results of a properly designed seismic data acquisition program not only leads to more effective planning of a drilling program, but also would lead to a much quicker recognition of the major mineralized zone(s), and a reduction in the number of required exploration boreholes. This integrated approach to exploration would then translate into a significant reduction of the total exploration expenditures. Unquestionably, the drilling of boreholes provides the most explicit, reliable information to a certain depth, but only within a very small area. Directly connecting the borehole information to seismic results extends the local reliable data; permitting reduction of the number of boreholes to create accurate two-dimensional or three-dimensional subsurface images and reduction of the expenditures of the total exploration program.     

Nanodiamonds and silicate minerals in ordinary chondrites as determined by micro‐Raman spectroscopy

We present here the Raman spectroscopic study of silicate and carbonaceous minerals in three ordinary chondrites with the aim to improve our understanding the impact process including the peak metamorphic pressures present in carbon‐bearing ordinary chondites. The characteristic Raman vibrational peaks of olivines, pyroxenes, and plagioclase have been determined on three ordinary chondrites from India, Dergaon (H5), Mahadevpur (H4/5), and Kamargaon (L6). The Raman spectra of these meteorite samples show the presence of nanodiamonds at 1334–1345 cm^?1 and 1591–1619 cm^?1. The full‐width at half maximum (FWHM) of Raman peaks for Mahadevpur and Dergaon reflect the nature of shock metamorphism in these meteorites. The frequency shift in Raman spectra might be because of shock effects during the formation of the diamond/graphite grains.