Microbially induced calcite precipitation along a circular flow channel under a constant flow condition

Biogrouting is a new ground improvement method that has been studied in recent years. This method involves mainly the use of a microbially induced calcite precipitation process to bind soil particles to increase the strength or to fill in the pores of soil or joints of rock for seepage control. There are two major challenges in the use of biogrout for seepage control through rock joints. The first is how to inject the biogrout solutions, and the second is to understand the mechanisms for the formation of calcite under seepage flow. In this paper, a study on the injection of biogrout solution and the formation of precipitates along a circular 1D flow channel is presented. To minimize the influence of flow, a new one-phase injection method to inject bacterial solution and cementation agents simultaneously was adopted in this study. Factors affecting the formation and distribution of precipitates along the flow channel such as flow velocity, flow rate, and aperture of flow channel were investigated. The experimental results indicated that less calcite was precipitated at locations further away from the injection point due to depletion of the reactants’ concentrations along the flow path. Using the one-phase injection method, the bacterial activity had a major effect on the accumulation of the calcite on the inner surface of the flow channel. The total calcite precipitated on the surface of the flow channel increased slightly with increasing bacterial activity or flow rate. An equation to predict the distance travelled by the biosolution has been derived based on the testing results.

     

额尔齐斯碰撞带东段结构与形成时代

阿尔泰地体与萨吾尔岛弧之间的额尔齐斯碰撞带其结构与形成时代是中亚造山带构造演化研究的热点问题之一。本文报道了额尔齐斯碰撞带东段结构与形成时代的研究结果。新的结果显示:额尔齐斯碰撞带东段由4个走向NWNNW陡立的韧性变形带组成,剖面上呈扇状挤压变形的结构;这4个韧性变形带的应变类型为收缩应变与平面应变;片理带的变形从宏观到微观都表现出对称的结构,不同变形带不同地段可具变化的流动方向而表现出"奶油饼结构",其可能整体形成于共轴挤压机制;玉勒肯与老山口韧性变形带花岗闪长质糜棱岩、花岗闪长质超糜棱岩中变质重结晶锆石U-Pb定年结果显示韧性变形时间约为360Ma。这可能意味着早石炭世时卡拉先格尔地区已进入碰撞阶段,即萨吾尔岛弧与阿尔泰地体间在360Ma时已发生碰撞。     

从多系统年代学(Multi-System Geochronology)透视云开地块古生代-中生代的构造演化

云开地块位于华南板块南缘,经历了麻粒岩-高角闪岩相的高级变质作用,是华南地区为数不多的高级变质地体。研究表明,云开地块在古生代到中生代经历了复杂的构造演化过程,分别记录了早古生代末期、早中生代、晚中生代早期和晚中生代晚期的构造影响。这些构造事件在多系统年代学图上具有很好的表现,系统地揭示了云开地块的地质演化历史。     

闽台铲状活动断裂

福建台湾大型铲状活动断裂系在深部(深5—100km)构成一系列向东倾斜、倾角为4°—10°的滑脱面,在近地表利用老断层的重新活动,形成NNE与NW向网格交叉的高角度断层。活动断裂系的地震能量释放主要集中在台湾东部。推断现代构造应力场的最大主压应力方向是NW—SE向,缓倾斜、向西撒开呈扇状特征。断裂系中各断裂的滑动速率不同,东大西小。     

HIGH INPUT IMPEDANCE TRANSISTOR AMPLIFIER FOR ACCELERATION MEASUREMENT

This paper describes a high input impedance preamplifier ,a main amplifier ,including its specification and the circuits theories .An acceleration measurement system consist of the piezoelectric acceleration 、preamplifier、cable 、main amplifier and oscilloscope for measureing the acceleration of vibration due to explosion .The features of the system are :1.good stability ,2.small zero shift ,3.The preamplifier is a new circuit which consists of four transistors 3DG6C,3DG4E. Its input impedance is as high as 1500MΩ and is able to undertake a high instantaneous impulse voltage ,4.There is no power supply set near the preamplifier .The signal transmiting cable is also the power supply cable so that the transmiting characteristic is very well .when the cable length is varied from 1 meter to 1000 meters ,the frequency response of system will not change .The decrement of output amplitude is less than 6% etc.     

内蒙古敖汉旗七家金矿闪长玢岩锆石U-Pb年代学、地球化学及地质意义

内蒙古敖汉旗七家金矿构造位置上处于兴蒙造山带与华北克拉通北缘的结合部位, 靠近兴蒙造山带一侧, 是近年来新发现的石英脉型金矿床.区内岩脉以闪长玢岩为主, 且与石英脉型矿体空间关系密切.根据岩脉与矿体的穿插关系, 将其分为成矿前闪长玢岩和成矿后闪长玢岩.LA-ICP-MS锆石U-Pb年代学表明, 成矿前闪长玢岩加权平均年龄为166.3±3.4 Ma, 成矿后闪长玢岩加权平均年龄为128.6±4.5 Ma, 与区域上两期构造-岩浆活动时间(分别为160 Ma左右和128 Ma左右)近似吻合.主量元素特征显示: 二者均属于准铝质, 高钾钙碱性系列; 微量元素特征显示: 二者均富集轻稀土元素、大离子亲石元素(Rb、K)和活泼的不相容元素(U、Pb), 相对亏损重稀土元素和高场强元素(Nb、Ta、Ti), 反映出岩浆来源具壳源特征.主微量元素特征均显示出二者具有岛弧岩浆岩的地球化学属性.另外, 成矿后闪长玢岩有较高的Nb/Ta(18.66~20.27)和Zr/Hf(37.16~39.23)比值, 暗示其岩浆来源具明显的幔源特征.岩石地球化学特征表明, 成矿前闪长玢岩可能起源于太平洋板块俯冲导致的下地壳部分熔融岩浆; 成矿后闪长玢岩可能起源于俯冲流体交代的地幔楔熔融岩浆, 并在其演化侵位过程中伴有地壳物质的混染.结合闪长玢岩成岩时代、岩石成因及区域构造演化, 反映出七家金矿的形成与太平洋板块的西向俯冲密切相关, 矿床在地壳由挤压增厚向伸展减薄的转换过程中形成.     

Geochemical and Sr-Nd isotopic study of alkaline syenites in Liangtun-Kuangdonggou, Liaoning Province, China： Evidence for enriched mantle before 1.86 Ga and implications

The 1.86 Ga Liangtun-Kuangdonggou complex (LKC) is one of the oldest alkaline syenite bodies so far discovered in China. This syenite suite has elevated contents of total alkali (K2O Na2O), with an average of 10.50%, and a mean Rittmann Index (σ) of 6.48. The intrusions have slightly higher concentrations of K2O than those of Na2O on a weight percent basis, indicating the rocks belong to potassium-rich alkaline syenite series. Total rare-earth element concentrations (∑REE ) of the rocks are relatively high, ranging from 324×10 -6 to 1314×10 -6, with a mean value of 666×10 -6. The REE patterns are subparallel and rightward steep with (La/Yb)N >33, showing mild negative to positive Eu anomalies (δEu: 0.63-1.15). All samples exhibit strong LILE and LREE enrichments and TNT (Nb, Ta, Ti) and P depletions in multi-element spidergrams. On the εSr(t)-εNd(t) correlation diagram, most analytical data points plot within the enriched mantle field with low ( 87Sr/86Sr)i ratios (0.7045-0.7051) and negative εNd(t) values (-3.72--3.97), falling among those kimberlites from Fuxian County, Liaoning Provinve, from Mengyin County, Shandong Province and the Ⅱ-type kimberlites from South Africa. These characteristics imply that the LKC-rocks may have the same source as the above-mentioned kimberlites, i.e., they have close connections to the materials derived from enriched mantle reservoirs, further revealing that the upper mantle beneath the northeastern part of the North China Plate had been highly enriched before 1.86 Ga. Geodynamically, the LKC-rocks were formed in a within-plate environment with close genetic connections to rift-related alkaline magma activities possibly controlled by ancient mantle plumes.     

Cu(II) adsorption at the calcite-water interface in the presence of natural organic matter: Kinetic studies and molecular-scale characterization

We have characterized the adsorption of Suwannee River humic acid (SRHA) and Cu(II) on calcite from preequilibrated solutions at pH 8.25. Sorption isotherms of SRHA on calcite follow Langmuir-type behavior at SRHA concentrations less than 15 mg C L⁻¹, whereas non-Langmuirian uptake becomes evident at concentrations greater than 15 mg C L⁻¹. The adsorption of SRHA on calcite is rapid and mostly irreversible, with corresponding changes in electrostatic properties. At pH 8.25, Cu(II) uptake by calcite in the presence of dissolved SRHA decreases with increasing dissolved SRHA concentration, suggesting that formation of Cu-SRHA aqueous complexes is the primary factor controlling Cu(II) sorption at the calcite surface under the conditions of our experiments. We also observed that surface-bound SRHA has little influence on Cu(II) uptake by calcite, suggesting that Cu(II) coordinates to calcite surface sites rather than to surface-bound SRHA.Cu K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine-structure (EXAFS) spectroscopic results show that the local coordination of Cu adsorbed at the calcite surface is very similar in the presence and absence of SRHA. Ca backscatterers at ∼3.90 Å indicate that Cu(II) forms tetragonally distorted inner-sphere adsorption complexes in both binary and ternary systems. Subtle differences in the XANES and EXAFS between binary sorption samples and ternary sorption samples, however, prevent us from ruling out the formation of ternary Cu-SRHA surface complexes. Our findings demonstrate that SRHA plays an important role in controlling the fate and transport of Cu(II) in calcite-bearing systems.     

An Early Cretaceous slab window beneath central Tibet,SW China: Evidence from OIB‐like alkaline gabbros in the Duolong area

The geodynamic mechanism of the late Early Cretaceous magmatic flare‐up in the collisional zone between the Lhasa and Qiangtang terranes in Tibet is controversial because of a scarcity of robust evidence. To address this problem, we report geochronological, geochemical and Hf isotopic data for the newly discovered Gufeng gabbros from the Duolong Cu–Au mineral district of the western Bangong–Nujiang Suture Zone (BNSZ). The gabbro samples, dated at 126.3 ± 1.8 Ma, show geochemical similarities to typical ocean island basalt (OIB) and have positive εHf(t) values of +3.3 to +6.9. The gabbros were generated by decompression melting of deep upwelling asthenosphere. This event is best explained by slab break‐off and the resultant development of a slab window beneath central Tibet.     

Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane

Kokchetavite, a new polymorph of K-feldspar (KAlSi₃O₈), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 ų, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.