Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.     

液体高膨胀材料充填堵漏试验应用

介绍了钻探施工中，利用膨胀材料充填、堵漏的新工艺，其具有经济、高效、安全的特点。     

The influence of coupled physical swelling and chemical reactions on deformable geomaterials

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.     

渝东南下古生界页岩构造裂缝形成及分布控制因素

天然裂缝对页岩气储集和渗流有重要影响,但目前对页岩构造裂缝研究不够深入。本文通过露头、岩心裂缝观察和分析,探讨了渝东南下古生界页岩构造裂缝类型、形成机理及分布控制因素。基于裂缝特征及力学成因,将剪切裂缝分为高角度剪切裂缝、倾斜滑脱裂缝和水平滑脱裂缝。倾斜滑脱裂缝是在上覆岩层重力和水平构造应力共同作用下沿应力集中的软弱面发生剪切滑动形成,水平滑脱裂缝是在构造挤压应力作用条件下主要沿页理面方向的剪切或层间滑动形成;页理发育程度及岩层曲率是控制水平滑脱裂缝形成的关键因素,岩石矿物组成、构造作用及岩层厚度是控制其它类型构造裂缝形成和分布的主要因素,页岩岩石力学层的划分需要根据裂缝特征、岩性变化特征、岩石力学参数及沉积界面等综合确定,岩层厚度与层间构造裂缝密度呈负相关关系。     

四极法电阻率测量在石油管道防腐蚀中的应用

土壤电阻率是地下石油管道一个重要的腐蚀性指标,因为管道的腐蚀程度和土壤电阻率的大小密切相关。本文介绍了四极法电阻率测量的原理和实施过程,并应用于某石油管道周围土壤的勘测,对测试数据做了处理和分析,为输油管道施工设计的防腐蚀提供了科学依据。     

湖北省旱涝灾害致灾规律的初步研究

利用1960—2005年湖北省76个地区气象灾害的灾情普查数据和逐日降水量观测资料,对湖北省旱涝灾害的时空分布特征及其致灾规律进行分析。结果表明:干旱灾害的频发区呈东西走向的带状分布,而洪涝灾害的发生频次和频发区面积均明显少于干旱;干旱和洪涝灾害年平均发生站次在1996年以后出现相反的变化趋势,干旱发生站次增加,而洪涝发生站次减少,且两种灾害均主要集中发生在夏季;1996—2001年湖北省部分地区连续出现严重干旱灾害,干旱的累积增强效应导致农业经济损失出现跳跃性增长并在2001年达到最大值;洪涝的致灾强度呈准周期的起伏振荡,农作物受洪涝影响面积最大、损失最多的年份集中在20世纪90年代,农作物受害面积与农业经济损失的决定系数为0.8;受害人口与直接经济损失具有较好的相关特征,且直接经济损失随受害人口增多而增加的速度加快,但近年来人口对洪涝灾害的抵御能力也显著提高;急转干旱和急转洪涝主要发生在鄂西北和鄂东南的夏季,农作物的脆弱度增加,农业经济损失随受害面积增大而增加的速度加快,但所造成的农业经济损失远小于仅发生干旱和洪涝时的数值。     

淮河流域夏季降水异常与若干气候因子的关系

基于旋转经验正交函数分解 (REOF) 方法探讨淮河流域1961—2010年夏季降水与厄尔尼诺/南方涛动 (ENSO)、北大西洋涛动 (NAO)、印度洋偶极子 (IOD)、太平洋年代际振荡 (PDO) 之间的关系,并进一步分析各气候因子不同位相单独以及联合对淮河流域夏季降水的影响。结果表明:淮河流域夏季降水与ENSO,PDO,NAO,IOD等气候因子具有较稳定的相关性,其中,PDO和IOD是影响淮河流域夏季降水的关键因子,且PDO与夏季降水呈显著负相关关系;各气候因子的冷暖位相单独及联合对淮河流域夏季降水的影响不同,PDO的冷期以及NAO,IOD冷位相使流域北部的夏季降水量呈显著增加趋势,PDO分别联合ENSO,NAO和IOD的冷、暖位相对流域北部地区和淮河上游地区的夏季降水影响显著。