磷对金刚石增强型硬质合金复合齿性能的影响

在金刚石增强型硬质合金复合齿基体中添加不同量红磷，可降低复合齿烧结温度，实现低温活化烧结。研究表明：添加0．3％(ωB)P的复合齿基体性能最好，采用化学镀Ni-P合金添加P和球磨添加0．1％P的方式，复合齿超硬部分的磨耗比和复合齿的抗冲击功优于单纯通过球磨添加0．3％P的超硬复合齿。为了实现金刚石增强型硬质合金复合齿的低温活化烧结，磷元素最优的添加方式是化学镀结合球磨的添加方式。     

Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.     

金沙江流域(云南境内)山地灾害危险性评价

云南境内的金沙江流域是斜坡不稳定的敏感区,根据1988-2000年的区域调查和统计,区内发育山地灾害点1697处,其中流域面积大于1km2的泥石流沟808条,体积大于1×104m3的滑坡580处,体积大于1000m3的崩塌309处。用于山地灾害危险性评价的主要敏感因子包括岩土体类型、山坡坡度、降雨、土地利用、地震烈度和人类活动。在对这些因子进行了敏感性评价的基础上,应用GIS对敏感因子集成评价而产生了云南金沙江流域山地灾害危险性评价图。评价结果表明:高危险区面积占全区面积6464km2的8 77%,中危险区占全区总面积的41 51%,低危险区占41 12%,无危险区占8 60%。山地灾害危险性评价图可以帮助规划者或工程师在土地发展规划中选择最佳建设场所,以减轻灾害的影响。     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

经济欠发达地区县级城镇居民休闲时间利用特征分析--以云南蒙自县为例

随着县级城镇社会经济的迅速发展,城镇居民的休闲时间日渐增多,休闲时间的利用成为人们关注的焦点。以蒙自为案例地的中国经济欠发达地区县级城镇居民的休闲时间利用结构已经日趋多样化,但主要还是集中于看电视、散步、书报业务学习、家庭娱乐、做家务等几项传统休闲方式,家庭内休闲在城镇居民的休闲活动中占了很大比重,这反映出休闲时间利用低水平的问题。县级城镇休闲设施和休闲产业都比较落后,影响了城镇居民休闲质量的提高和休闲消费、休闲经济的发展。因此,政府及有关部门应努力改善城镇的休闲设施,大力发展休闲产业,从多方面引导居民科学、有效、合理地利用休闲时间,最终促进休闲经济的发展,提高城镇居民的生活质量。     

北秦岭二郎坪群抱树坪组沉积时代与构造环境

二郎坪群抱树坪组作为北秦岭早古生代重要的沉积记录,其研究程度较低。本文通过对抱树坪组内火山岩夹层和花岗斑岩脉进行岩石学、地球化学和锆石U- Pb测年研究,旨在进一步确定其沉积时代与构造环境。研究结果表明：豫西夏馆地区抱树坪组火山岩夹层已变质为（黑云）阳起钠长片岩,常与黑云石英片岩呈“互层状”产出;岩石原岩为安山质凝灰岩,具有相对低的SiO2（52. 56%~62. 04%）、较高的Al2O3（10. 70%~18. 55%）、低的MgO（4. 06%~6. 21%）和FeOT/MgO（1. 23~1. 81）,富集轻稀土元素和大离子亲石元素Rb、Th、U、K,相对亏损高场强元素Nb、Ta、P、Ti,具镁安山质岩石的特点;结合地球化学特征及前人研究认为,抱树坪组可能形成于活动陆缘弧后盆地。获得黑云阳起钠长片岩原岩的结晶锆石U- Pb年龄为446. 0±1. 7 Ma,以及侵入其中花岗斑岩脉的成岩年龄为430. 0±3. 0 Ma,首次将抱树坪组的形成时代准确地限定为晚奥陶世至早志留世。综合区域研究成果认为,小寨组和抱树坪组在地层层序和地层时代上符合广义二郎坪群的划分方案,但大庙组、火神庙组及由小寨组和抱树坪组构成的整体三者在形成时代上表现为近于同时性,在空间上主体呈现近平行关系,可能主体属时代大体相当的不同沉积环境的产物;在大地构造属性方面,认为二郎坪群是在约470 Ma之前由于商丹洋向北俯冲而形成的火山岛弧,在470~436 Ma转化为弧后盆地,至约430 Ma之前最终完成消减闭合。     

辽宁省精细化暴雨洪涝灾害风险评估与预评估

基于辽宁省61个国家气象站1961—2020年和998个区域自动气象观测站建站至2020年逐小时、逐日降水资料,分析了辽宁省暴雨洪涝灾害主要致灾因子,计算了暴雨洪涝孕灾环境指标,完成了辽宁省暴雨洪涝灾害危险性评估。结果表明：暴雨洪涝高危险性地区主要位于丹东;暴雨洪涝灾害人口高风险区主要位于沈阳和大连市区;经济高风险区主要位于大连和盘锦市区;水稻、玉米高风险区主要位于锦州、盘锦和丹东。利用辽宁省无缝隙智能网格预报数据对2022年7月28—29日的暴雨过程灾害风险进行了预评估,发现暴雨灾害危险性高值区域主要分布在朝阳、葫芦岛以及辽宁中部。暴雨灾害可能造成的人口、经济高风险区域主要位于辽宁西部和中部地区;暴雨灾害可能造成的水稻和玉米高风险区主要位于沈阳、铁岭和朝阳北部等地区。预计高风险区主要影响人口约为449万人,经济损失约为1432万元,受影响的水稻面积约为1.028万公顷、玉米面积约为1.798万公顷。通过灾后效果检验,发现预评估模型效果良好,可在实际的暴雨洪涝灾害风险评估业务中使用。     

中国地区三种地表反照率产品比较

利用2007—2011年MODIS、GlobAlbedo和ERA-Interim的3种地表反照率产品,借助地理信息系统(Geographic Information System, GIS)空间化技术,对中国地区3种地表反照率产品进行了对比分析。结果表明：3种产品与气象站观测值的时间分布趋势一致,冬季高夏季低,且相关性较高。3种产品中,MODIS与GlobAlbedo的绝对差异值最小,ERA-Interim与MODIS、GlobAlbedo的绝对差异值较大。3种产品在青藏高原和西北山地区域表现出较大的差异,且差异表现为冬半年高,夏半年低。3种产品之间相关性最高的是MODIS与GlobAlbedo,最低的是MODIS与ERA-Interim, 3种产品在40°N以北具有较好的相关性。且在夏季和冬季地表反照率均值的表现说明,ERA-Interim相比MODIS、GlobAlbedo难以反映地表反照率受地形和土地覆被的影响。     

Influence of Near Real-Time Green Vegetation Fraction Data on Numerical Weather Prediction by WRF over North China

The green vegetation fraction(GVF) can greatly influence the partitioning of surface sensible and latent heat fluxes in numerical weather prediction(NWP) models. However, the multiyear averaged monthly GVF climatology—the most commonly used representation of the vegetation state in models—cannot capture the real-time vegetation state well. In this study, a near real-time(NRT) GVF dataset generated from an 8-day composite of the normalized difference vegetation index is compared with the 10-yr averaged monthly GVF provided by the WRF model. The annual variability of the GVF over North China is examined in detail. Many differences between the two GVF datasets are found over dryland, grassland, and cropland/grassland mosaic areas. Two experiments using different GVF datasets are performed to assess the impacts of GVF on forecasts of screen-level temperature and humidity. The results show that using NRT GVF can lead to a widespread reduction of 2-m temperature forecast errors from April to October.Evaluation against in-situ observations shows that the positive impact on 2-m temperature forecasts in the morning is more distinct than that in the afternoon. Our study demonstrates that NRT GVF can provide a more realistic representation of the vegetation state, which in turn helps to improve short-range forecasts in arid and semiarid regions of North China. Moreover, our study shows that the negative effect of using NRT GVF is closely related to the initial soil moisture.     

Evaluation of Global Gridded Precipitation and Temperature Datasets against Gauged Observations over the Upper Tekeze River Basin,Ethiopia

The availability of satellite and reanalysis climate datasets and their applicability have been greatly promoted in hydro-climatic studies. However, such climatic products are still subject to considerable uncertainties and an evaluation of the products is necessary for applications in specific regions. This study aims to evaluate the reliability of nine gridded precipitation and temperature datasets against ground-based observations in the upper Tekeze River basin(UTB) of Ethiopia from 1982 to 2016. Precipitation, maximum temperature(T_(max)), minimum temperature(T_(min)), and mean temperature(T_(mean)) were evaluated at daily and monthly timescales. The results show that the best estimates of precipitation are from the Eart H2 Observe, WFDEI, and ERA-Interim reanalysis data Merged and Bias-corrected for the Inter-Sectoral Impact Model Intercomparison Project(EWEMBI), and the Climate Hazards Group Infra Red Precipitation with Station data(CHIRPS) datasets. The percentage biases and correlation coefficients(CCs) are within ±15% and 0.5, respectively, for both EWEMBI and CHIRPS at the two timescales. All products underestimate the drought conditions indicated by the standardized precipitation index(SPI), while the EWEMBI and CHIRPS datasets show higher agreement with the observations than other datasets. The Tmean estimates produced by the ECMWF ReAnalysis version 5(ERA5) and the Climate Hazards Group Infra Red Temperature with Station data(CHIRTS) are the closest to the observations, with CCs of 0.65 and 0.55, respectively, at the daily timescale. The CHIRTS and EWEMBI datasets show better representations of Tmax(T_(min)), with CCs of 0.69(0.72) and 0.62(0.68), respectively,at the monthly timescale. The temperature extremes are better captured by the ERA5(T_(mean)), CHIRTS(T_(max)), and EWEMBI(T_(min)) datasets. The findings of this study provide useful information to select the most appropriate dataset for hydrometeorological studies in the UTB and could help to improve the regional representation of global datasets.