Origin of uranium and rare earth minerals in bone detritus from rare metal deposits

In order to ascertain the forms in which uranium is present in ores of the Melovoe rare metal sedimentary deposit of uranium and rare earth minerals (South Mangyshlak), we investigated a series of typical ore samples that were collected earlier; both the uranium content and the total content of rare earth metals in them lay within 0.1–0.3%. The study was carried out by analytical electron microscopy using transmission electron microscopy and scanning electron microscopy, electron microdiffraction, and microprobing. It was ascertained that both uranium and rare earth elements are present in ore mostly associated with biogenic phosphate in the form of natural minerals, such as uraninite, ningyoite, coffinite, autenite, and churchite. Iron hydroxides and graphitized organic matter are present in some samples. It is assumed that the co-occurrence of uranium and rare earth elements, which is nontypical for the sedimentary process, resulted from secondary epigenetic processes and alternation of reducing and oxidizing environmental conditions.     

Microearthquakes along the back-arc spreading system in the eastern Bismarck Sea

OBS’s were deployed for 26 to 29 days in the eastern Bismarck Sea to investigate the back-arc spreading. Hypocenters of 186 shallow earthquakes were determined using P- and S-waves from at least five stations. In the western survey area, a transform fault zone is marked by a linear micro-earthquake activity striking N65°W and less than 5 km wide. The predominant type of their focal mechanisms is strike-slip. In the eastern area, several intermittent zones of micro-earthquakes and their strike-slip type focal mechanisms suggest the location of short-length transform faults separating en-echelon spreading ridges.     

Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.     

A pockmark field in the Patras Gulf (Greece) and its activation during the 14/7/93 seismic event

During a recent oceanographical-geophysical survey carried out in the southeastern part of the Gulf of Patras in Western Greece for the construction of an outfall, an active pockmark field was found. The pockmark field was formed in soft layered Holocene silts. The pockmarks are associated with acoustic anomalies attributed to gas-charged sediments. The pockmarks vary in size and shape from 25 to 250 m in diameter and from 0.5 to 15 m in depth and are among the largest and deepest observed in the world.

On July 14th, 1993, during the survey, a major earthquake of magnitude 5.4 on the Richter scale occurred in the area. During the 24 hour period prior to the earthquake the bottom water temperature anomalously increased on three occasions, whilst for a few days after the earthquake it was noted that the majority of the pockmarks were venting gas bublles.

It is considered that the three abrupt sea-water temperature increases were probably the result of upward migrating high-temperature gas bubbles in the water column. It is further suggested that the earthquake was the triggering mechanism and that the gas expulsion was caused by the reduction in the pore volume in the sediments resulting from changes in the stress regime prior to the earthquake. Therefore, it can be suggested that in seismic areas adjacent to pockmark fields, earthquake prediction may be achieved by monitoring the water temperature and/or the rate of gas venting in the pockmark field.

Our analysis indicates that the pockmark field in the Patras Gulf has formed slowly during the Holocene by continuous gas venting, which is periodically being interrupted by short-duration events of enhanced gas seepage triggered by earthquakes.     

Jökulhlaup-related Ice Fracture and Supraglacial Water Release During the November 1996 Jökulhlaup, Skeiðarárjökull, Iceland

During the initial stages of the November 1996 jökulhlaup at Skeiðarárjökull, Iceland, floodwaters burst onto the glacier surface via a series of fractures. This supraglacial drainage led to the formation of a number of distinct ice surface depressions, one of which is investigated in detail. The morphology and structural characteristics of this feature are described, as well as the sedimentology of an associated assemblage of debris-filled fractures. This work suggests that debris-charged subglacial floodwaters travelled up to the glacier surface, where supraglacial flow occurred initially via an extensive network of fractures, orientated parallel to the glacier margin. Supraglacial discharge became progressively more focused into a series of discrete outlets, leading to the mechanical erosion of a number of depressions on the glacier surface. The associated transfer of subglacially derived floodwaters to high levels within the glacier resulted in the rapid entrainment of large volumes of sediment which may influence the patterns, processes and products of ice-marginal sedimentation in the future.     

A New Insight into Probabilistic Seismic Hazard Analysis for Central India

The Son-Narmada-Tapti lineament and its surroundings of Central India (CI) is the second most important tectonic regime following the converging margin along Himalayas-Myanmar-Andaman of the Indian sub-continent, which attracted several geoscientists to assess its seismic hazard potential. Our study area, a part of CI, is bounded between latitudes 18°–26°N and longitudes 73°–83°E, representing a stable part of Peninsular India. Past damaging moderate magnitude earthquakes as well as continuing microseismicity in the area provided enough data for seismological study. Our estimates based on regional Gutenberg–Richter relationship showed lower b values (i.e., between 0.68 and 0.76) from the average for the study area. The Probabilistic Seismic Hazard Analysis carried out over the area with a radius of ~300 km encircling Bhopal yielded a conspicuous relationship between earthquake return period (T) and peak ground acceleration (PGA). Analyses of T and PGA shows that PGA value at bedrock varies from 0.08 to 0.15 g for 10 % (T = 475 years) and 2 % (T = 2,475 years) probabilities exceeding 50 years, respectively. We establish the empirical relationships $ {\text{ZPA}}_{(T = 475)} = 0.1146\;[V_{\text{s}} (30)]^{ - 0.2924}, $ and $ {\text{ZPA}}_{(T = 2475)} = 0.2053\;[V_{\text{s}} (30)]^{ - 0.2426} $ between zero period acceleration (ZPA) and shear wave velocity up to a depth of 30 m [V _s (30)] for the two different return periods. These demonstrate that the ZPA values decrease with increasing shear wave velocity, suggesting a diagnostic indicator for designing the structures at a specific site of interest. The predictive designed response spectra generated at a site for periods up to 4.0 s at 10 and 2 % probability of exceedance of ground motion for 50 years can be used for designing duration dependent structures of variable vertical dimension. We infer that this concept of assimilating uniform hazard response spectra and predictive design at 10 and 2 % probability of exceedance in 50 years at 5 % damping at bedrocks of different categories may offer potential inputs for designing earthquake resistant structures of variable dimensions for the CI region under the National Earthquake Hazard Reduction Program for India.     

Variation in Coronal Activity from Solar Cycle 24 Minimum to Maximum Using Three-Dimensional Reconstructions of the Coronal Electron Density from STEREO/COR1

Three-dimensional electron density distributions in the solar corona are reconstructed for 100 Carrington rotations (CR 2054?–?2153) during 2007/03?–?2014/08 using the spherically symmetric method from polarized white-light observations with the inner coronagraph (COR1) onboard the twin Solar Terrestrial Relations Observatory (STEREO). These three-dimensional electron density distributions are validated by comparison with similar density models derived using other methods such as tomography and a magnetohydrodynamics (MHD) model as well as using data from the Solar and Heliospheric Observatory (SOHO)/Large Angle and Spectrometric Coronagraph (LASCO)-C2. Uncertainties in the estimated total mass of the global corona are analyzed based on differences between the density distributions for COR1-A and -B. Long-term variations of coronal activity in terms of the global and hemispheric average electron densities (equivalent to the total coronal mass) reveal a hemispheric asymmetry during the rising phase of Solar Cycle 24, with the northern hemisphere leading the southern hemisphere by a phase shift of 7?–?9 months. Using 14 CR (\(\approx13\)-month) running averages, the amplitudes of the variation in average electron density between Cycle 24 maximum and Cycle 23/24 minimum (called the modulation factors) are found to be in the range of 1.6?–?4.3. These modulation factors are latitudinally dependent, being largest in polar regions and smallest in the equatorial region. These modulation factors also show a hemispheric asymmetry: they are somewhat larger in the southern hemisphere. The wavelet analysis shows that the short-term quasi-periodic oscillations during the rising and maximum phases of Cycle 24 have a dominant period of 7?–?8 months. In addition, it is found that the radial distribution of the mean electron density for streamers at Cycle 24 maximum is only slightly larger (by \(\approx30\%\)) than at cycle minimum.     

Petrology and geochemistry of greywackes from Goa-Dharwar sector,western Dharwar Craton: Implications for volcanoclastic origin

Late Archaean Supracrustals of the Goa-Dharwar sector (GDS) are composed of a thick sequence of greywacke sequence with narrow intercalations of quartzite, BIF and carbonates. Mafic volcanics occupy the base of the sequence. The greywackes are predominantly tuffacious containing chlorite-sericite and hornblende. Arkosic variations containing biotite dominate the western part of the sector. Fine-grained variations occur as isolated narrow lenses within other types of greywackes. The conglomeratic greywackes are localized along the western and the eastern margins of the sector. All of the greywackes are all typically immature containing coarser clasts of mostly plagioclase (18–23%) and quartz (32–34%). Lithic fragments of felsic volcanic rocks are common. The matrix is dominated by mafic material. Biotite and amphibole are related to metamorphic recrystallization. Chlorite, sericite, epidote, carbonate and chert are products of the interplay of diagenesis and low-grade metamorphism. Fe-Ti oxide, sphene, apatite and zircon are usual accessories. But for slight enrichment in K₂O, the major element chemistry of the GDS greywackes is similar to the chemistry of Late Archaean greywackes. They also compare in respect of V, Co, Hf contents, K₂O/Na₂O, SiO₂/Al₂O₃, Na₂O/Al₂O₃, Ba/Rb, Th/U, La/Th, Sm/Nd ratios, steep REE patterns with distinct LREE enrichment and HREE depletion. The GDS greywackes however are distinctly enriched in Rb, Ba, Sr, Th, U, Cu, Zr, Ce/Ce* and depleted in Cr, Ni, and Zn. The conglomeritic and biotite bearing verities contain considerable proportions of clasts derived from the basement tonalitic/granitic terrain. The common tuffacious greywackes containing hornblende and biotite-sericite however include only volcanic clasts and bear evidence of derivation from submarine weathering of predominantly felsic volcanics erupted on a large scale to form a magmatic arc in the later stages of geosynclinal deposition. Geochemical data suggest that the GDS greywackes were laid down in progressively changing basin geometry from a passive to active continental margin and island arc setting.     

Hydrothermal plume mapping as a prospecting tool for seafloor sulfide deposits: a case study at the Zouyu-1 and Zouyu-2 hydrothermal fields in the southern Mid-Atlantic Ridge

Seafloor hydrothermal polymetallic sulfide deposits are a new type of resource, with great potential economic value and good prospect development. This paper discusses turbidity, oxidation–reduction potential, and temperature anomalies of hydrothermal plumes from the Zouyu-1 and Zouyu-2 hydrothermal fields on the southern Mid-Atlantic Ridge. We use the known location of these vent fields and plume data collected in multiple years (2009, 2011, 2013) to demonstrate how real-time plume exploration can be used to locate active vent fields, and thus associated sulfide deposits. Turbidity anomalies can be detected 10 s of km from an active source, but the location precision is no better than a few kilometers because fine-grained particles are quasi-conservative over periods of many days. Temperature and oxidation–reduction potential anomalies provide location precision of a few hundred meters. Temperature anomalies are generally weak and difficult to reliably detect, except by chance encounters of a buoyant plume. Oxidation–reduction potential is highly sensitive (nmol concentrations of reduced hydrothermal chemicals) to discharges of all temperatures and responds immediately to a plume encounter. Real-time surveys using continuous tows of turbidity and oxidation–reduction potential sensors offer the most efficient and precise surface ship exploration presently possible.