The application of cathodoluminescence to interpreting the diagenesis of an ancient calcrete profile

A laterally extensive calcrete profile has been identified in the Late Asbian (Lower Carboniferous) shallow marine shelf limestones of the Llangollen area, North Wales. The upper surface of the profile is defined by a laterally discontinuous palaeokarstic surface and by laminated calcareous crusts which developed within the underlying limestone. The profile contains a unique series of early pore-filling vadose cements which only occur down to 1 m below the palaeokarstic surface. Cathodoluminescence reveals that these cements pre-date the late pore-filling meteoric phreatic cements which occur throughout local Asbian lithologies. A spar cement stratigraphy has been established for the calcrete profile. Subaerial vadose cements comprise two generations of non-luminescent cement, followed by a brightly luminescent generation which occasionally shows an acicular habit. This needle-fibre calcite represents the final stage of vadose cementation. Precipitation of vadose cements was contemporary with subaerial alteration and micritization of the limestone. Textures, visible only with cathodoluminescence, provide evidence of recurrent periods of fabric dissolution. The most extensive phase of dissolution occurred immediately after the precipitation of the non-luminescent subaerial vadose cements. Several different textures have been recorded, each reflecting the morphology of a partially dissolved substrate. Dissolution textures are generally confined to the walls of the larger pores and to early brecciation fractures. These probably acted as fluid pathways in the calcrete during early subaerial diagenesis. Much of the non-marine micrite in the calcrete profile appears as needle-fibre calcite under cathodoluminescence. This acicular calcite was probably formed in response to localized supersaturation of meteoric pore fluids caused by periods of near-surface evaporation. Since needle-fibre luminescence is strongly variable, these ambient conditions are not believed to have directly controlled the activator ion concentrations of cementing pore waters. Needle-fibre calcite is considered to be a cement precipitate which has almost completely recrystallized to micrite, probably during the late stages of subaerial diagenesis. Two generations of subaerial micrite which define a ‘micrite stratigraphy’, have been distinguished under cathodoluminescence. Reconstructing the diagenetic history of this ancient calcrete profile has revealed that subaerial alteration was multistaged, with many diagenetic processes acting simultaneously during a single phase of emergence.     

On the meridional circulation and balance of momentum in the Southern Ocean of POP

 The circulation of the Southern Ocean is studied in the eddy-resolving model POP (Parallel Ocean Program) by an analysis of zonally integrated balances. The TEM formalism (Transformed Eulerian Mean) is extended to include topography and continental boundaries, thus deviations from a zonally integrated state involve transient and standing eddies. The meridional circulation is presented in terms of the Eulerian, eddy-induced, and residual streamfunctions. It is shown that the splitting of the meridional circulation into Ekman and geostrophic transports and the component induced by subgrid and Reynolds stresses is identical to a particular form of the zonally integrated balance of zonal momentum. In this balance, the eddy-induced streamfunctions represent the interfacial form stresses by transient and standing eddies and the residual streamfunction represents the acceleration of the zonal current by density fluxes in a zonally integrated frame. The latter acceleration term is directly related to the surface flux of density and interior fluxes due to the resolved and unresolved eddies. The eddy-induced circulation is extremely vigorous in POP. In the upper ocean a shallow circulation, reversed in comparison to the Deacon cell and mainly due to standing eddies, appears to the north of Drake Passage latitudes, and in the Drake Passage belt of latitudes a deep-reaching cell is induced by transient eddies. In the resulting residual circulation the Deacon cell is largely cancelled and the residual advection of the zonal mean potential density is balanced by diapycnal eddy and subgrid fluxes which are strong in the upper few hundred meters but small in the ocean interior. The balance of zonal momentum is consistent with other eddy-resolving models; a new aspect is the clear identification of density effects in the zonally integrated balance. We show that the wind stress and the stress induced by the residual circulation drive the eastward current, whereas both eddy species result in a braking. Finally, we extend the Johnson–Bryden model of zonal transport to incorporate all relevant terms from the zonal momentum balance. It is shown that wind stress and induction by the residual circulation carry an eastward transport while bottom form stress and the stress induced by standing eddies yield westward components of transport. Received: 26 June 2001 / Accepted: 2 November 2001     

Dynamic interaction of bridge–train system under non‐uniform seismic ground motion

The probability that an earthquake occurs when a train is running over a bridge in earthquake‐prone regions is much higher than before, for high‐speed railway lines are rapidly developed to connect major cities worldwide. This paper presents a finite element method‐based framework for dynamic analysis of coupled bridge–train systems under non‐uniform seismic ground motion, in which rail–wheel interactions and possible separations between wheels and rails are taken into consideration. The governing equations of motion of the coupled bridge–train system are established in an absolute coordinate system. Without considering the decomposition of seismic responses into pseudo‐static and inertia‐dynamic components, the equations of motion of the coupled system are formed in terms of displacement seismic ground motions. The mode superposition method is applied to the bridge structure to make the problem manageable while the Newmark‐β method with an iterative computation scheme is used to find the best solution for the problem concerned. Eight high‐speed trains running over a multi‐span steel truss‐arch bridge subject to earthquakes are taken as a case study. The results from the case study demonstrate that the spatial variation of seismic ground motion affects dynamic responses of the bridge–train system. The ignorance of pseudo‐static component when using acceleration seismic ground motions as input may underestimate seismic responses of the bridge–train system. The probability of separation between wheels and rails becomes higher with increasing train speed. Copyright © 2011 John Wiley & Sons, Ltd.     

Cuttability assessment of hard coal seams

Summary A number of field and laboratory tests have been carried out on more than 15 coal seams of compressive strengths ranging from 19 MPa to 44 MPa to evolve methods which would help in the selection of suitable coaling machines for hard coal seams. The effect of physico-mechanical properties on cuttability were studied in the laboratory for all these coal seams to identify the relevant parameters affecting the specific energy of coal cuttability. These data were subjected to regression analysis to find the best fit for estimation of laboratory specific energy of coal samples on the basis of simple laboratory and field tests for the strength parameters. Field studies were also conducted over a large number of active mechanized coal faces to study in situ cuttability along with the geo-mining conditions of the site. The field and the laboratory data so generated were correlated and an attempt is made to establish a relationship for estimating the field specific energy for a particular capacity of coaling machines by considering the geo-mining domain of the field in totality.     

Persistence of mantle lithospheric Re–Os signature during asthenospherization of the subcontinental lithospheric mantle: insights from in situ isotopic analysis of sulfides from the Ronda peridotite (Southern Spain)

The western part of the Ronda peridotite massif (Southern Spain) consists mainly of highly foliated spinel-peridotite tectonites and undeformed granular peridotites that are separated by a recrystallization front. The spinel tectonites are interpreted as volumes of ancient subcontinental lithospheric mantle and the granular peridotites as a portion of subcontinental lithospheric mantle that underwent partial melting and pervasive percolation of basaltic melts induced by Cenozoic asthenospheric upwelling. The Re–Os isotopic signature of sulfides from the granular domain and the recrystallization front mostly coincides with that of grains in the spinel tectonites. This indicates that the Re–Os radiometric system in sulfides was highly resistant to partial melting and percolation of melts induced by Cenozoic lithospheric thermal erosion. The Re–Os isotopic systematics of sulfides in the Ronda peridotites thus mostly conserve the geochemical memory of ancient magmatic events in the subcontinental lithospheric mantle. Os model ages record two Proterozoic melting episodes at ~1.6 to 1.8 and 1.2–1.4 Ga, respectively. The emplacement of the massif into the subcontinental lithospheric mantle probably coincided with one of these depletion events. A later metasomatic episode caused the precipitation of a new generation of sulfides at ~0.7 to 0.9 Ga. These Proterozoic Os model ages are consistent with results obtained for several mantle suites in Central/Western Europe and Northern Africa as well as with the Nd model ages of the continental crust of these regions. This suggests that the events recorded in mantle sulfides of the Ronda peridotites reflect different stages of generation of the continental crust in the ancient Gondwana supercontinent.     

Regional Problems in Water Use in Siberian Industrial Agglomerations

Water Resources - The basic indicators of regional water use have been identified and assessed as a component of a single social–natural–technogenic system. These indicators have been...     

Orbital Evolution of Příbram and Neuschwanstein

The orbital evolution of the two meteorites Příbram and Neuschwanstein on almost identical orbits and also several thousand clones were studied in the framework of the N-body problem for 5,000 years into the past. The meteorites moved on very similar orbits during the whole investigated interval. We have also searched for photographic meteors and asteroids moving on similar orbits. There were five meteors found in the IAU MDC database and six NEAs with currently similar orbits to Příbram and Neuschwanstein. However, only one meteor 161E1 and one asteroid 2002 QG46 had a similar orbital evolution over the last 2,000 years.     

Does I = PAT Work in Local Places?

An aspect of global change currently not well understood is how processes operating on spatial scales finer than those used in recent global circulation models (GCMs) contribute to changes in atmospheric composition and the subsequent changes in climate. We use the ‘IPAT’ formulation as a framework to test relationships among social driving forces and user group greenhouse gas (GHG) emissions in northwestern North Carolina. Using regression, correlation, and bivariate mapping to examine relationships between a suite of socioeconomic variables and GHG emissions for the residential, commercial/industrial, and agricultural end‐user categories, we find that various measures of population and affluence serve equally well as explanatory variables.