Electron microscopy study of the iron meteorite Santa Catharina

Abstract— Characterization of the microstructural features of the metal of the Santa Catharina meteorite was performed using a variety of electron optical techniques. Sample USNM#6293 is chemically homogeneous on the micron scale and has a Ni content of 28.2 wt.%. Its microstructure is similar to that of the Twin City ataxite and contains clear taenite II, i.e., fcc taenite with domains of tetrataenite, < 10 nm in size. Sample USNM#3043 is a more typical Santa Catharina specimen with dark and light regions as observed with the light optical microscope. The dark regions are inhomogeneous and contain 45–50 wt.% Ni and 7–12 wt.% O. The light regions are homogeneous and contain 35 wt.% Ni and no detectable oxygen. The microstructure is that of cloudy zone, i.e., islands of tetrataenite, ～20 nm in size, in a honeycomb matrix. The honeycomb phase contains Ni rich oxide in the dark regions and contains metal, fcc taenite, in the light regions. The original metal structure of USNM#3043 is cloudy zone which formed during cooling into the low temperature miscibility gap of the Fe-Ni phase diagram. The dark regions were developed from the metal by selective corrosion of the honeycomb structure, transforming it into Ni containing oxides, possibly non-stoichiometric Fe₂NiO₄ while retaining the tetrataenite islands. Using the results of this study, many of the existing discrepancies concerning the microstructure of Santa Catharina can be explained.     

THE BLOOMINGTON (LL6) CHONDRITE AND ITS SHOCK MELT GLASSES

The Bloomington meteorite, a 67.8 gram veined, brecciated chondrite, fell during the summer of 1938 in Bloomington, Illinois. Its olivine, orthopyroxene and metal compositions (fo₆₉, en₇₄ and Fe₅₂ Ni₄₈ respectively) and its texture identify it as a brecciated LL6 chondrite of shock facies d. Shock melt glasses occur in Bloomington as sparse melt pockets and veins in clasts and as isolated masses in the black, clast-rich matrix. The vein glasses chemically resemble bulk LL-group chondrites and thus appear to reflect total melting of the host meteorite. The melt pocket and matrix glasses, like those described previously in L-group chondrites, have more varied compositions and are typically enriched in normative plagioclase. All glasses that we analyzed in Bloomington have FeO/MgO and Na/Al ratios similar to those of LL-group chondrites, indicating that melting of this meteorite involved neither a significant change in the oxidation state of iron nor loss of sodium to a vapor phase. Bloomington is a monomict breccia whose components formed in place as a result of a single episode of shock and attendant melting.     

A critical state model for sands dependent on stress and density

An elastoplastic model for sands is presented in this paper, which can describe stress–strain behaviour dependent on mean effective stress level and void ratio. The main features of the proposed model are: (a) a new state parameter, which is dependent on the initial void ratio and initial mean stress, is proposed and applied to the yield function in order to predict the plastic deformation for very loose sands; and (b) another new state parameter, which is used to determine the peak strength and describe the critical state behaviour of sands during shearing, is proposed in order to predict simply negative/positive dilatancy and the hardening/softening behaviour of medium or dense sands. In addition, the proposed model can also predict the stress–strain behaviour of sands under three-dimensional stress conditions by using a transformed stress tensor instead of ordinary stress tensor. Copyright © 2004 John Wiley & Sons, Ltd.     

Plane of elastic non-resisting tension material under foundation structures

In the frame of 2D-static problems one approaches the problem of elastic-NRT (not-resisting tension) semi-plane loaded on its limit line. This problem is intended to model the stress situation induced in the soil by a foundation structure. The solution, in terms of activated stress field, is searched for in the class of stress fields satisfying equilibrium and admissibility conditions, by applying an energy approach. Copyright © 2004 John Wiley & Sons, Ltd.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

Porphyroblast inclusion-trail orientation data: eppure non son girate*!

Extensive examination of large numbers of spatially orientated thin sections of orientated samples from orogens of all ages around the world has demonstrated that porphyroblasts do not rotate relative to geographical coordinates during highly non-coaxial ductile deformation of the matrix subsequent to their growth. This has been demonstrated for all tectonic environments so far investigated. The work also has provided new insights and data on metamorphic, structural and tectonic processes including: (1) the intimate control of deformation partitioning on metamorphic reactions; (2) solutions to the lack of correlation between lineations that indicate the direction of movement within thrusts and shear zones, and relative plate motion; and (3) a possible technique for determining the direction of relative plate motion that caused orogenesis in ancient orogens.     

Helium abundance in Novae

The⁴He abundance of the Nova Delphini 1967 is determined, using their nebular stage spectra, which is of the order 0.18 by number and 0.39 by mass. Our results and similar measurements on other novae show that the⁴He abundance in novae is about twice the amount predicted by the Big-Bang theory. The binary structure is the main cause of⁴He overabundance in novae.     

Formation of galactic subsystems in light of the magnesium abundance in field stars: The thin disk

Data from our compiled catalog of spectroscopically determined magnesium abundances in stars with accurate parallaxes are used to select thin-disk dwarfs and subgiants according to kinematic criteria. We analyze the relations between the relative magnesium abundances in stars, [Mg/Fe], and their metallicities, Galactic orbital elements, and ages. The [Mg/Fe] ratios in the thin disk at any metallicity in the range ?1.0 dex <[Fe/H] < ?0.4 dex are shown to be smaller than those in the thick disk, implying that the thin-disk stars are, on average, younger than the thick-disk stars. The relative magnesium abundances in such metal-poor thin-disk stars have been found to systematically decrease with increasing stellar orbital radii in such a way that magnesium overabundances ([Mg/Fe] > 0.2 dex) are essentially observed only in the stars whose orbits lie almost entirely within the solar circle. At the same time, the range of metallicities in magnesium-poor stars is displaced from ?0.5 dex < [Fe/H] < +0.3 dex to ?0.7 dex < [Fe/H] < +0.2 dex as their orbital radii increase. This behavior suggests that, first, the star formation rate decreases with increasing Galactocentric distance and, second, there was no star formation for some time outside the solar circle, while this process was continuous within the solar circle. The decrease in the star formation rate with increasing Galactocentric distance is responsible for the existence of a negative radial metallicity gradient (grad _R[Fe/H] = ?0.05 ± 0.01 kpc^?1) in the disk, which shows a tendency to increase with decreasing age. At the same time, the relative magnesium abundance exhibits no radial gradient. We have confirmed the existence of a steep negative vertical metallicity gradient (grad _Z[Fe/H] = ?0.29 ± 0.06 kpc^?1) and detected a significant positive vertical gradient in relative magnesium abundance (grad _Z[Mg/Fe] = 0.13 ± 0.02 kpc^?1); both gradients increase appreciably in absolute value with decreasing age. We have found that there is not only an age-metallicity relation, but also an age-magnesium abundance relation, in the thin disk. We surmise that the thin disk has a multicomponent structure, but the existence of a negative trend in the star formation rate along the Galactocentric radius does not allow the stars of its various components to be identified in the immediate solar neighborhood.