Recent water quality trends and a comparison to sediment-core records for two riverine lakes of the Upper Mississippi River basin: Lake St. Croix and Lake Pepin

Long-term water quality monitoring data from two riverine lakes in the Upper Mississippi River basin, Lakes St. Croix and Pepin, were analyzed to compare the long-term average water quality conditions and land use distributions, water quality trends and loads at lake inlets and outlets, trends from long-term versus short-term monitoring records, and the ability of paleolimnological cores to accurately infer lake water quality conditions. During the 1976–2004 period, the long-term average concentrations of nutrients, suspended solids, and chlorophyll-a were consistently lower at the Lake St. Croix inlet versus the Lake Pepin inlet, which drains a greater proportion of urban and agricultural runoff. Despite these differences, nutrient trends were similar at the inlets to both lakes; reductions in total phosphorus and ammonium concentrations were attributed to improvements in point source technologies, whereas increasing nitrate concentrations were attributed to both point source changes and nonpoint source increases. Despite improvements in several water quality variables, nitrate concentrations are increasing in both lakes, sediment trends indicate persistent nonpoint source inputs to Lake Pepin, and current total phosphorus concentrations remain well above pre-1950s levels in both lakes. Since urban development and agriculture are increasing in the Lake St. Croix and Lake Pepin Watersheds, continued point source regulation and additional nonpoint source control efforts will be needed to further improve water quality in these lakes. The 1976–2004 trends for most water quality variables were similar at inlet versus outlet sites on Lake St. Croix. Trends at Lake Pepin inlet versus outlet sites were less similar, but data availability limited the comparison to the 1993–2003 period. While the truncated data record highlighted short-term trends in both lakes, the full data record was most useful for exploring general patterns in water quality. Length of monitoring record affected our ability to detect trends at the inlets to both lakes, and altered the magnitude of detected trends. During the two decades of the 1980s and 1990s, paleolimnological estimates of retained phosphorus loads were similar to those estimated from recent water quality monitoring. These similarities support the use of paleolimnological approaches to infer past water quality conditions in Lakes St. Croix and Pepin. This is one of eight papers dedicated to the “Recent Environmental History of the Upper Mississippi River” published in this special issue of the Journal of Paleolimnology. D. R. Engstrom served as guest editor of the special issue.     

The geographic distribution of small dams in Oregon using ecoregion and landform classification

Abstract

Small dams fragment river landscapes, disrupting channel connectivity and impacting water quality and quantity. Although they impound volumetrically less total water than large dams, the ubiquity of small dams suggests their cumulative impacts could be significant. Documenting the distribution and characteristics of small dams is necessary to understanding and mitigating their impacts. In this study, we compare datasets of small dams in Oregon, compile a new comprehensive dataset, and document geographic variations in small dam distributions between different ecoregions. We used Oregon Water Resources Department dam and Oregon Department of Fish and Wildlife fish passage barrier datasets to compare dam heights and contributing drainage areas between different ecoregions. Over 61% of Oregon’s land area is above one or more small dam. We highlight the location of Oregon’s small dams at valley margins, transition zones between flat plains and mountains, and areas of high population density. Given the hidden nature of small dams, evaluation of small dam impacts using public imagery is not effective. However, knowledge of small dam distributions given their association with landforms can aid in finding unrecorded dams, assessing approaches for evaluating their geomorphic impacts, and informing their management.     

Constraints on mantle plumes on Venus: Implications for volatile history

The analysis of Venus’ gravity field and topography suggests the presence of a small number of deep mantle plumes (～9). This study predicts the number of plumes formed at the core–mantle boundary, their characteristics, and the production of partial melt from adiabatic decompression. Numerical simulations are performed using a 3D spherical code that includes large viscosity variations and internal heating. This study investigates the effect of several parameters including the core–mantle boundary temperature, the amount of internal heating, and the mantle viscosity. The smallest number of plumes is achieved when no internal heating is present. However, scaling Earth’s radiogenic heating to Venus suggests a value of ～16 TW. Cases with internal heating produce more realistic lid thickness and partial melting, but produce either too many plumes or no plumes if a high mantle temperature precludes the formation of a hot thermal boundary layer. Mantle viscosity must be reduced to at least 10²⁰ Pa s in order to include significant internal heating and still produce hot plumes. In all cases that predict melting, melting occurs throughout the upper mantle. Only cases with high core temperature (>1700 K) produce dry melting. Over time the upper mantle may have lost significant volatiles. Depending on the water content of the lower mantle, deep plumes may contribute to present-day atmospheric water via volcanic outgassing. Assuming 50 ppm water in mantle, 10 plumes with a buoyancy flux of 500 kg/s continuously erupting for 4 myr will outgas an amount of water on the order of that in the lower atmosphere. A higher level of internal heating than achieved to date, as well as relatively low mantle viscosity, may be required to achieve simulations with ～10 plumes and a thinner lid. Alternatively, if the mantle is heating up due to the stagnant lid, the effect is equivalent to having lower rates of internal heating. A temperature increase of 110 K/byr is equivalent to ?13 TW. This value along with the internal heating of 3 TW used in this study may represent the approximate heat budget of Venus’ mantle.     

Preserved organic matter in a fossil Ocean Continent Transition in the Alps: the example of Totalp,SE Switzerland

Evidence from ultraslow spreading mid-ocean ridges and both fossil and present-day Ocean–Continent Transitions (OCT) demonstrates that mantle serpentinization resulting from the interaction of mantle rock and water during tectonic exhumation is widespread. Observations at white smokers in modern ocean settings suggest that methane produced by serpentinization can support methanotrophic bio-systems, which use methane as the only source of carbon. An important question is whether such bio-systems are more generally pervasive in their association with serpentinized mantle in the subsurface. In this study, we examined whether there is evidence for such a methanotrophic system in exhumed serpentinized mantle at a magma-poor rifted continental margin, by probing for characteristic biological markers in these and associated sedimentary rocks in the Totalp unit of SE Switzerland. This unit represents a remnant of the former OCT of the southern Alpine Tethyan margin and was chosen because of its mild Alpine tectonic and low-grade metamorphic overprint during Alpine orogeny, hence giving potential for the preservation of indigenous organic matter (OM). Totalp samples are characterized by low organic carbon contents of 11–647 ppm. The majority of the samples contain hydrocarbons in the form of n-alkanes in the range C₁₇–C₃₆. Some sediments contain isoprenoids, for example pristane and phytane and a suite of steranes that are consistent with a marine origin for the OM preserved in the rocks. Traces of marine planktonic and bacterial OM are preserved in the serpentinized mantle and overlying sediments of this ancient Tethyan OCT, but there is no evidence that the OM has been generated from methanotrophic bio-systems.     

Overview of integrative tools and methods in assessing ecological integrity in estuarine and coastal systems worldwide

In recent years, several sets of legislation worldwide (Oceans Act in USA, Australia or Canada; Water Framework Directive or Marine Strategy in Europe, National Water Act in South Africa, etc.) have been developed in order to address ecological quality or integrity, within estuarine and coastal systems. Most such legislation seeks to define quality in an integrative way, by using several biological elements, together with physico-chemical and pollution elements. Such an approach allows assessment of ecological status at the ecosystem level ('ecosystem approach' or 'holistic approach' methodologies), rather than at species level (e.g. mussel biomonitoring or Mussel Watch) or just at chemical level (i.e. quality objectives) alone. Increasing attention has been paid to the development of tools for different physico-chemical or biological (phytoplankton, zooplankton, benthos, algae, phanerogams, fishes) elements of the ecosystems. However, few methodologies integrate all the elements into a single evaluation of a water body. The need for such integrative tools to assess ecosystem quality is very important, both from a scientific and stakeholder point of view. Politicians and managers need information from simple and pragmatic, but scientifically sound methodologies, in order to show to society the evolution of a zone (estuary, coastal area, etc.), taking into account human pressures or recovery processes. These approaches include: (i) multidisciplinarity, inherent in the teams involved in their implementation; (ii) integration of biotic and abiotic factors; (iii) accurate and validated methods in determining ecological integrity; and (iv) adequate indicators to follow the evolution of the monitored ecosystems. While some countries increasingly use the establishment of marine parks to conserve marine biodiversity and ecological integrity, there is awareness (e.g. in Australia) that conservation and management of marine ecosystems cannot be restricted to Marine Protected Areas but must include areas outside such reserves. This contribution reviews the current situation of integrative ecological assessment worldwide, by presenting several examples from each of the continents: Africa, Asia, Australia, Europe and North America.     

青藏高原北羌塘新生代高钾钙碱岩系火山岩角闪石类型有痕量元素地球化学

利用电子探针和激光探针剥蚀系统（LA－ICP－MS）对北羌塘新第三纪高钾钙碱岩系英安岩中角闪石的主元素和微量、角闪石强烈富集Sc、Ti、V、Cr、Co、Ni等不相容亲铁元素，而相对亏损Th、U、Pb、Rb等强不相容的大离子亲石元素。稀土元素丰度高，且无Eu异常，批示北羌塘这套高钾钙碱岩系火山岩可能是青藏高原加厚的相当于榴辉岩相物质组成的下部陆壳脱水熔融的产物。     

Pyrite paragenesis and multiple sulfur isotope distribution in late Archean and early Paleoproterozoic Hamersley Basin sediments

The sulfur isotope record in late Archean and early Paleoproterozoic rocks is of considerable importance because it provides evidence for changes in early Earth atmospheric oxygen levels and potentially constrains the origin and relative impact of various microbial metabolisms during the transition from an anoxic to oxic atmosphere. Mass independently fractionated (MIF) sulfur isotopes reveal late Archean and early Paleoproterozoic sulfur sources in different pyrite morphologies in Western Australia's Hamersley Basin. Multiple sulfur isotope values in late Archean pyrite vary according to morphology. Fine grained pyrite has positive sulfur MIF, indicating a reduced elemental sulfur source, whereas pyrite nodules have negative sulfur MIF, potentially derived from soluble sulfate via microbial sulfate reduction. The Hamersley Basin δ³⁴S–Δ³³S record suggests that the extent of oxygenation of the surface ocean fluctuated through the Late Archean from at least 2.6 Ga, more than 150 million yr before the Great Oxidation Event. In the early Paleoproterozoic, there is less distinction between pyrite morphologies with respect to sulfur isotope fractionation, and pyrite from the Brockman Iron Formation trends toward modern sulfur isotope values. An important exception to this is the strong negative MIF recorded in layer parallel pyrite in Paleoproterozoic carbonate facies iron formation. This may suggest that deeper water hydrothermal environments remained anoxic while shallower water environments became more oxidised by the early Paleoproterozoic. The results of the current study indicate that sulfide paragenesis is highly significant when investigating Archean and early Paleoproterozoic multiple sulfur isotope compositions and sulfur sources.