The internal structure of the Arosa Zone (Swiss-Austrian Alps)

The Arosa Zone, part of the main Alpine suture zone between the Austroalpine and the Penninic realms, forms a heterogeneous unit composed of rocks of oceanic and continental origin. It exhibits mélange character due to minor sedimentary mixing and local penetrative tectonic deformation during Cretaceous and Early Tertiary imbrication. Competent blocks of both Austroalpine and Penninic origin, covering up to 2.5 km², are embedded in incompetent serpentinitic or shaly-calcareous matrix. On a mesoscale, disrupted strata occur in and adjacent to thrust and shear zones. Contrasting competence between blocks and matrix partitioned deformation into brittle and ductile processes. Extension veins and shear fractures affected the competent strata whereas the matrix developed a penetrative foliation during ductile flow and accommodated high strain. Flow was mainly non-coaxial in the matrix, and coaxial extension prevailed in the blocks.In a regional tectonic setting, we define the Arosa Zone as the tectonostratigraphic unit sandwiched between the Austroalpine and Penninic units. It forms a narrow and highly imbricated zone containing both South Penninic ophiolitic and sedimentary rocks as well as blocks and slices of Austroalpine origin.

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Zusammenfassung Die Arosa Zone ist Teil der Alpinen Suturzone zwischen Ostalpin und Pennimkum und bildet eine lithologisch heterogene Einheit aus kontinentalen und ozeanischen Gesteinen. Sie zeigt den Charakter einer Melange, die aus, untergeordnet, sedimentärer Durchmischung und lokaler, aber penetrativer tektonischer Deformation während kretazisch und alttertiärer Tektonik resultiert. Kompetente Blöcke ostalpiner und penninischer Herkunft, die bis zu 3 km im Streichen verfolgbar sind, schwimmen in einer inkompetenten serpentinitischen oder tonig-karbonatischen Matrix. Im Mesobereich treten zerbrochene Gesteinsabfolgen in oder direkt an Überschiebungs- und Scherzonen auf. Unterschiedliche Kompetenz zwischen Blöcken und Matrix teilt die Deformation in spröde und duktile Prozesse auf. Die kompetenten Gesteine zeigen Extensionsspalten und Scherbrüche, in der Matrix entwickelte sich durch duktiles Fließen eine penetrative Schieferung bei hoher Strainintensität. Die Deformation in der Matrix war hauptsächlich nicht-koaxial, koaxiale Extension herrschte in den Blöcken.Im regionalen tektonischen Rahmen definieren wir die Arosa Zone als tektonostratigraphische Einheit zwischen Ostalpin und Penninikum. Sie bildet eine schmale, stark imbrikierte Zone die, aus südpenninischen ophiolithischen und sedimentären Gesteinen, sowie aus Blöcken und Spänen ostalpiner Herkunft aufgebaut wird.

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Résumé La Zone d'Arosa, partie de la zone de suture alpine entre l'Austro-alpin et le Pennique, forme une unité hétérogène composée de roches d'origines océanique et continentale. Elle présente le caractère d'un mélange qui résulte d'un brassage sédimentaire mineur, et de déformations tectoniques, locales mais pénétratives, au cours du Crétacé et du Tertiaire ancien. Des blocs compétents de l'Austro-alpin et du Pennique qui couvrent jusqu'à 2.5 km², sont enrobés dans une matrice incompétente serpentineuse ou argilo-calcaire. A moyenne échelle, les couches disloquées se rencontrent dans les zones charriées et cisaillées, ou y sont adjacentes. La différence de compétence entre les blocs et la matrice répartit la déformation en processus cassants et ductiles. Les roches compétentes montrent des fentes d'extension et des fractures de cisaillement, alors que dans la matrice, sous l'action d'un flux ductile et d'une intensité de contrainte élevée, se développe une foliation pénétrative. La déformation fut principalement non coaxiale dans la matrice et coaxiale dans les blocs d'extension.Dans un cadre tectonique régional, nous définissons la Zone d'Arosa comme une unité tectonostratigraphique prise entre l'Austro-alpin et le Pennique. Elle constitue une zone étroite et fortement imbriquée composée aussi bien de roches ophiolitiques du Sud-Pennique et de roches sédimentaires, que de blocs et d'écaillés de l'Austro-alpin.

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Relationships between environmental variables and zooplankton subfossils in the surface sediments of 36 shallow coastal brackish lakes with special emphasis on the role of fish

Subfossil zooplankton assemblages (Cladocera 22 taxa, Rotifera 1 taxon) were identified from the surface sediments of 36 shallow (median depth = 0.7 m) Danish coastal brackish lakes differing in epilimnic salinity (SAL, range 0.2–17.4), summer-mean total phosphorus (TP, 27–327 g l^–1) and total nitrogen (TN, 0.850–2.629 mg l^–1), as well as in submerged macrophyte coverage and planktivorous fish density (PL-CPUE). Cladoceran species richness declined significantly with increasing SAL, TP and TN, while no significant correlation was found to either PL-CPUE, macrophyte coverage or lake surface area. Bonferroni-adjusted forward selection within canonical correspondence analysis (CCA) showed that 22.1% of the variation in zooplankton data was explained by PL-CPUE, SAL and TP uniquely; each variable explaining an almost equally significant amount of variation in the zooplankton data. Predictive models to infer PL-CPUE, SAL and TP were developed using variance weighted-averaging (WA) procedures. Almost similar values of boot-strapped coefficient of determination (r²_{boot-strapped} 0.22–0.38) were produced by the WA inference models of PL-CPUE, SAL and TP, while the inference models of TP produced the lowest boot-strapped root-mean-squared-error of prediction (RMSEP_{boot-strapped} 0.29–0.36 log(TP + 1), g l^–1). Yet, zooplankton TP and SAL optima (WA) were strongly correlated (r² = 0.46), while PL-CPUE optima (WA) were independent of both TP and SAL optima, indicating that only the PL-CPUE inference models are suitable for making reconstructions.     

A survey of natural aggregate properties and characteristics important in remote sensing and airborne geophysics

Natural aggregate is vital to the construction industry. Although natural aggregate is a high volume/low value commodity that is abundant, new sources are becoming increasingly difficult to find and develop because of rigid industry specifications, political considerations, development and transportation costs, and environmental concerns. There are two primary sources of natural aggregate: (1) exposed or near-surface bedrock that can be crushed, and (2) deposits of sand and gravel. Remote sensing and airborne geophysics detect surface and near-surface phenomena, and may be useful for detecting and mapping potential aggregate sources; however, before a methodology for applying these techniques can be developed, it is necessary to understand the type, distribution, physical properties, and characteristics of natural aggregate deposits.The distribution of potential aggregate sources is closely tied to local geologic history. Conventional exploration for natural aggregate deposits has been largely a ground-based operation, although aerial photographs and topographic maps have been extensively used to target possible deposits. Today, the exploration process also considers factors such as the availability of the land, space and water supply for processing, political and environmental factors, and distance from the market; exploration and planning cannot be separated.There are many physical properties and characteristics by which to judge aggregate material for specific applications; most of these properties and characteristics pertain only to individual aggregate particles. The application of remote sensing and airborne geophysical measurements to detecting and mapping potential aggregate sources, however, is based on intrinsic bulk physical properties and extrinsic characteristics of the deposits that can be directly measured, mathematically derived from measurement, or interpreted with remote sensing and geophysical data. On the cover: Northward view of alluvial fans along San Luis Valley, southcentral colorado. This image was created in the U.S. Geological Survey (USGS) Remote Sensing laboratory by digitally draping SPOT panchromatic satellite data resampled to 30 meters pixels resolution over the 124,000 USGS DEM of the Bonanza, Whle Hill, Bushnell Peak, Graveyard Guich, Klondike Mine, and Villa Grove quadrangles.     

Evaluating sedimentary DNA for tracing changes in cyanobacteria dynamics from sediments spanning the last 350 years of Lake Tiefer See,NE Germany

Journal of Paleolimnology - Since the beginning of the Anthropocene, lacustrine biodiversity has been influenced by climate change and human activities. These factors advance the spread of harmful...     

Effects of juniper removal and rainfall variation on tree transpiration in a semi‐arid karst: evidence of complex water storage dynamics

Brush removal is widely practiced as a tool for increasing groundwater recharge, but its efficacy depends greatly on the way in which the removed species interact with the hydrological system relative to the vegetation replacing it. We examined the effects of Ashe juniper removal in the recharge zone of the Edwards Aquifer, Texas, USA, a karst aquifer. The study was conducted in an Ashe juniper (Juniperus ashei)–live oak (Quercus fusiformis) woodland on a hill slope composed of rocky, shallow soils over fractured limestone bedrock. Ashe juniper is a native species that has been encroaching grasslands and savannas over the past century. In September 2008, a plot was cleared of 90% of its juniper trees. Tree transpiration, predawn water potentials and vegetation cover across the cleared plot and an adjacent reference site were measured from May 2009 to December 2011. Stand‐level tree transpiration from May 2009 to March 2010 was diminished by a severe summer drought in 2009, from which trees were slow to recover. Subsequently, tree transpiration was 5–10× higher in the woodland compared to the clearing. For all of 2011, also a drought year, tree transpiration in the woodland exceeded precipitation inputs, indicating a high capacity for water storage at the study site. However, site differences for oak trees were generally larger than for juniper trees. While juniper removal accounted for a 431 mm year^?1 difference in tree transpiration between sites, vegetation cover in the clearing increased from 42% to 90% over two years, suggesting that understory growth was increasingly compensating for the loss of juniper transpiration. We conclude that the removal of a relatively shallow‐rooted tree, when replaced with herbaceous vegetation and low shrubs, has little effect on deep recharge. By contrast, successive years of precipitation extremes may be more effective increasing recharge by lowering the water transport capacity of trees in the aftermath of severe drought. Copyright © 2016 John Wiley & Sons, Ltd.     

Large-Eddy Atmosphere–Land-Surface Modelling over Heterogeneous Surfaces: Model Development and Comparison with Measurements

A model is developed for the large-eddy simulation (LES) of heterogeneous atmosphere and land-surface processes. This couples a LES model with a land-surface scheme. New developments are made to the land-surface scheme to ensure the adequate representation of atmosphere–land-surface transfers on the large-eddy scale. These include, (1) a multi-layer canopy scheme; (2) a method for flux estimates consistent with the large-eddy subgrid closure; and (3) an appropriate soil-layer configuration. The model is then applied to a heterogeneous region with 60-m horizontal resolution and the results are compared with ground-based and airborne measurements. The simulated sensible and latent heat fluxes are found to agree well with the eddy-correlation measurements. Good agreement is also found in the modelled and observed net radiation, ground heat flux, soil temperature and moisture. Based on the model results, we study the patterns of the sensible and latent heat fluxes, how such patterns come into existence, and how large eddies propagate and destroy land-surface signals in the atmosphere. Near the surface, the flux and land-use patterns are found to be closely correlated. In the lower boundary layer, small eddies bearing land-surface signals organize and develop into larger eddies, which carry the signals to considerably higher levels. As a result, the instantaneous flux patterns appear to be unrelated to the land-use patterns, but on average, the correlation between them is significant and persistent up to about 650 m. For a given land-surface type, the scatter of the fluxes amounts to several hundred W $\text{ m }^{-2}$ , due to (1) large-eddy randomness; (2) rapid large-eddy and surface feedback; and (3) local advection related to surface heterogeneity.     

High Resolution Simulation of the Variability of Surface Energy Balance Fluxes Across Central London with Urban Zones for Energy Partitioning

The parameterization of surface heat-flux variability in urban areas relies on adequate representation of surface characteristics. Given the horizontal resolutions (e.g. $\approx $ 0.1–1 km) currently used in numerical weather prediction (NWP) models, properties of the urban surface (e.g. vegetated/built surfaces, street-canyon geometries) often have large spatial variability. Here, a new approach based on Urban Zones to characterize Energy partitioning (UZE) is tested within a NWP model (Weather Research and Forecasting model; WRF v3.2.1) for Greater London. The urban land-surface scheme is the Noah/Single-Layer Urban Canopy Model (SLUCM). Detailed surface information (horizontal resolution 1 km) in central London shows that the UZE offers better characterization of surface properties and their variability compared to default WRF-SLUCM input parameters. In situ observations of the surface energy fluxes and near-surface meteorological variables are used to select the radiation and turbulence parameterization schemes and to evaluate the land-surface scheme and choice of surface parameters. For radiative fluxes, improved performance (e.g. $>$ 25 W m $^{-2}$ root-mean-square error reduction for the net radiation) is attained with UZE parameters compared to the WRF v3.2.1 default for all three methods from the simplest to the most detailed. The UZE-based spatial fluxes reproduce a priori expectations of greater energy storage and less evaporation in the dense city centre compared to the residential surroundings. Problems in Noah/SLUCM partitioning of energy between the daytime turbulent fluxes are identified with the overestimation of the turbulent sensible heat and underestimation of the turbulent latent heat fluxes.     

Igneous and shock processes affecting chassignite amphibole evaluated using chlorine/water partitioning and hydrogen isotopes

Amphibole in chassignite melt inclusions provides valuable information about the volatile content of the original interstitial magma, but also shock and postshock processes. We have analyzed amphibole and other phases from NWA 2737 melt inclusions, and we evaluate these data along with published values to constrain the crystallization Cl and H₂O content of phases in chassignite melt inclusions and the effects of shock on these amphibole grains. Using a model for the Cl/OH exchange between amphibole and melt, we estimate primary crystallization OH contents of chassignite amphiboles. SIMS analysis shows that amphibole from NWA 2737 currently has 0.15 wt% H₂O. It has lost ~0.6 wt% H₂O from an initial 0.7–0.8 wt% H₂O due to intense shock. Chassigny amphibole had on average 0.3–0.4 wt% H₂O and suffered little net loss of H₂O due to shock. NWA 2737 amphibole has δD ≈ +3700‰; it absorbed Martian atmosphere‐derived heavy H in the aftermath of shock. Chassigny amphibole, with δD ≤ +1900‰, incorporated less heavy H. Low H₂O/Cl ratios are inferred for the primitive chassignite magma, which had significant effects on melting and crystallization. Volatiles released by the degassing of Martian magma were more Cl‐rich than on Earth, resulting in the high Cl content of Martian surface materials.