TDR pressure cell for monitoring water content retention and bulk electrical conductivity curves in undisturbed soil samples

The water retention curve (θ(ψ)), which defines the relationship between soil volumetric water content (θ) and matric potential (ψ), is of paramount importance in characterizing the hydraulic behaviour of soils. However, few methods are so far available for estimating θ(ψ) in undisturbed soil samples. We present a new design of TDR‐pressure cell (TDR‐Cell) for estimating θ(ψ) in undisturbed soil samples. The TDR‐Cell consists of a 50‐mm‐long and 50‐mm internal diameter stainless steel cylinder (which constitutes the outer frame of a coaxial line) attached to a porous ceramic disc and closed at the ends with two aluminium lids. A 49‐mm‐long and 3‐mm‐diameter stainless steel rod, which runs longitudinally through the centre of the cylinder, constitutes the inner rod of a coaxial TDR probe. The TDR‐Cell was used to determine the θ(ψ) curves of a packed sand and seven undisturbed soil samples from three profiles of agricultural soils. These θ(ψ) curves were subsequently compared to those obtained from the corresponding 2‐mm sieved soils using the pressure plate method. Measurements of bulk electrical conductivity, σ_a, as a function of the water content, σ_a(θ), of the undisturbed soil samples were also performed. An excellent correlation (R² = 0·988) was found between the θ values measured by TDR on the different undisturbed soils and the corresponding θ obtained from the soil gravimetric water content. A typical bimodal θ(ψ) function was found for most of the undisturbed soil samples. Comparison between the θ(ψ) curves measured with the TDR‐Cell and those obtained from the 2‐mm sieved soils showed that the pressure plate method overestimates θ at low ψ values. The σ_a(θ) relationship was well described by a simple power expression (R² > 0·95), in which the power factor, defined as tortuosity, ranged between 1·18 and 3·75. Copyright © 2011 John Wiley & Sons, Ltd.     

Is the supersonic turbulence observed in HII regions sustained by the presence of magnetic fields?

We describe a set of Hα emission line profiles from populations of H II regions in nearby spiral galaxies. These are characterized by a strong Gaussian central peak, and lower intensity higher velocity wing features. From the peak we extract a non-thermal velocity component, due to the internal turbulence of the region. The plot of the widths of these non-thermal components against Hα luminosity shows a lower envelope in line width, which we assign to regions in, or close to virial equilibrium, although the region mass derived on this assumption is higher than the mass obtained by summing all known mass components. We speculate that this discrepancy, as well as the supersonicity of the line widths, can be explained by the presence of turbulent magnetic fields within the H II regions, and make a very rough estimate of the fields implied, of order a few tens of microgauss.     

Hydrogeochemistry and isotope techniques to determine water interactions in groundwater-dependent shallow lakes,Wet Pampa Plain,Argentina

This paper gives an account of the implementation of hydrochemical and isotopic techniques to identify and explain the processes that govern solute exchange in two groundwater-dependent shallow lakes in the Southeastern Pampa Plain of Argentina. Water samples (lakes, streams, spring water and groundwater) for hydrochemical and stable isotopic determination were collected and the main physical–chemical parameters were measured. The combination of stable isotope data with hydrogeochemical techniques was used for the identification of sources and preferential recharge areas to these aquatic ecosystems which allowed the explanation of the lake water origin. The hydrochemical processes which explain Los Padres Lake water chemistry are evaporation from groundwater, CO₂ input, calcite dissolution, Na⁺ release by Ca²⁺ and Mg²⁺ exchange, and sulfate reduction. The model that best aligns with La Brava Lake hydrochemical constraints includes: mixing, CO₂ and calcite dissolution, cationic exchange with Na⁺ release and Mg²⁺ adsorption, and to a lesser extent, Ca/Na exchange. This model suggests that the fractured aquifer contribution to this water body is greater than 50 %. An isotopic-specific fingerprint for each lake was identified, finding a higher evaporation rate for La Brava Lake compared to Los Padres Lake. Isotopic data demonstrate the importance of these shallow lakes as recharge areas to the regional aquifer, becoming areas of high groundwater vulnerability. The Tandilia Range System, considered in many hydrogeological studies as the impermeable bedrock of the Pampean aquifer, acts as a fissured aquifer in this area, contributing to low salinity waters and with a fingerprint similar to groundwater isotopic composition.     

The Mw 7.4 Colima, Mexico, Earthquake of 21 January 2003: The Observed Damage Matrix in Colima City and its Comparison with the Damage Probability Matrix

The Mw 7.4 earthquake of 21 January 2003 occurred within the Mexican subduction zone and produced many damages of masonry constructions in the towns of Colima state, México. The macroseismic investigation of damages produced by the earthquake in Colima city was realized for 3,332 constructions within the area of study representing about 20% of the total city area and covered with the different type of constructions. The 7-grade scale of damage was used to describe the damage distribution. The damage matrix, constructed for the area, showed that the damage distribution varied from 63% of constructions with relatively slight damages (grades 1–3) to 29% of constructions that had significative damages (grades 4–5) and 8% of completely destructed or demolished masonry. The damage matrices, constructed for 12 subzones of the area of study, reflected two tendencies in the damage distributions: the predominance of slight damages of the recent constructions situated in the northern and eastern parts of the area and the predominance of significant damages of the older constructions in the southern and western parts of the area. It was observed a significant dependence of damage index upon the age of constructions and the type of masonry. The comparison of the observed damage matrix with the damage probability matrix calculated for Colima masonry in 1999 gives MM intensity VII in Colima.     

Temporal Trends of Dissolved Trace Metals in Jamaica Bay,NY: Importance of Wastewater Input and Submarine Groundwater Discharge in an Urban Estuary

Jamaica Bay, NY, is a highly urbanized estuary within the boroughs of New York City conspicuously lacking published information on dissolved trace metal concentrations. The current study examines the distribution and cycling of trace metals in that embayment with data gathered during cruises in November 2004, April 2005, and June 2006. Most of the metal distributions (Fe, Zn, Co, Ag, Cu, Pb, Ni) in the water column are explained by the input of substantial volumes of treated wastewater effluent. However, several lines of evidence suggest that submarine groundwater discharge (SGD) is also an important source of dissolved Fe, Zn, Co, Ni, and isotopically distinct stable Pb ratios (²⁰⁶Pb, ²⁰⁷Pb, ²⁰⁸Pb) in the Bay. Conversely, the recirculated seawater component of SGD is an apparent sink for dissolved Mo. This study provides the first measurements of dissolved trace metals in the Jamaica Bay water column and subterranean estuary and provides evidence for trace metal input due to SGD.     

Cretaceous–Tertiary tectonic inversion of the Cotiella Basin (southern Pyrenees,Spain)

The Cotiella Nappe includes one of the most important Mesozoic basins of the southern Pyrenees, which was subsequently inverted during the Tertiary compression. The Late Cretaceous Cotiella Basin is here interpreted as the western sector of the Cretaceous Cotiella-Bóixols basin (100᎜ km wide), located in the central part of the southern Pyrenees. The present-day complex structure of the Cotiella Nappe is the result of the inversion process, linked to the emplacement of basement thrust sheets of the Axial zone. In its western sector, the Cotiella Nappe consists of several superimposed thrust sheets, with complex geometry, becoming simpler towards the east, with a single thrust surface and smaller displacements. The Cotiella-Bóixols basin underwent strong subsidence during the Early Cretaceous at its eastern sector, and its depocentre migrated westward during the Late Cretaceous. The reconstruction of the sedimentary basin to the pre-compressional stage shows that during the Mesozoic the Cotiella-Bóixols basin was located to the south of a basement high, which later became the Pyrenean Axial Zone. From a balanced cross section, it can be inferred that the Cotiella, north-verging extensional system was connected with the north-Pyrenean rift by means of a 10-km deep horizontal detachment. The compressional Tertiary detachment within the upper crust was shallower than the extensional detachment, and individualised four basement thrust sheets, which form the Axial Zone antiform.     

Analysis of the mobilization of solid loads and heavy metals in runoff waters from granite quarries

The cutting operations of dimension stone at quarries produce a large amount of fines that, in turn, cause a negative environmental impact over local surface waters. This article presents a detailed analysis of the mobilized contamination associated with runoff waters in a large granite quarry (～200 ha) which is located in Porriño (Galicia, NW Spain), the most important production centre of dimension stone in Spain. There, an intensive monitoring survey was developed in order to characterize the hydrology of the system as well as the release and transport of pollutants. This was accomplished by means of different control sections for the flow and by the collection of 52 random water samples. Automatic samplers were also used to collect 192 water samples associated with runoff generated by significant rain events. For each of the samples collected, a wide battery of analytic determinations was performed, including solid loads, turbidity, organic pollution, nutrient and selected metals. Upon careful examination it has been possible to obtain different parameters related to the contamination control, like the “event mean concentration” (EMC), maximum concentrations and specific sediment loads. Moreover, a comprehensive statistical study including parameter correlation and cumulative probability analyses helped to understand the pollutant mobilization behaviour within the quarry system. It can be concluded that mobilized contamination shows the anomalous presence of some metals, whose concentrations are in excess when compared to the natural rock. This excess metal amount must be attributed to an anthropogenic source associated to mining and cutting operations.