Large temporal changes in contributions of groundwater-borne nutrients to coastal waters off a volcanic island

We examined the contribution of submarine groundwater discharge (SGD) to nutrient budgets in Hwasun Bay, Jeju Island, Korea in August 2009, October 2014, and May 2015. The concentrations of dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorus (DIP) in fresh groundwater were in the range of 285?716 μM and 2.3?3.2 μM, respectively, which were each 1?2 orders of magnitude higher than those in the bay seawater. The outer-bay seawater flowing into the bay was oligotrophic (2.9 ± 1.9 μM for DIN and 0.2 ± 0.3 μM for DIP). Nutrient budget calculations were performed for each season by accounting for submarine fresh groundwater discharge (SFGD) and water residence times. In August 2009 (DIN = 1.8 μM and DIN:DIP ratio = 4.6 for the outerbay water), DIN inputs from SFGD accounted for approximately 40% of the DIN inventory in the bay seawater. In October 2014 (DIN = 1.1 μM and DIP < 0.05 μM for the outer-bay water), DIP from SFGD accounted for approximately 100% of the DIP inventory in the bay seawater. In May 2015, mean concentrations of DIN and DIP in the bay seawater were 8.6 ± 12 μM and 0.11 ± 0.04 μM, respectively, with conservative behaviors in the bay seawater in association with excessive groundwater inputs. These results imply that SGD plays a critical but different role in nutrient budgets and stoichiometry in coastal waters off a volcanic island depending on open-ocean nutrient conditions.     

Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization

Oxidation of mackinawite (FeS) and concurrent mobilization of arsenic were investigated as a function of pH under oxidizing conditions. At acidic pH, FeS oxidation is mainly initiated by the proton-promoted dissolution, which results in the release of Fe(II) and sulfide in the solution. While most of dissolved sulfide is volatilized before being oxidized, dissolved Fe(II) is oxidized into green rust-like precipitates and goethite (α-FeOOH). At basic pH, the development of Fe(III) (oxyhydr)oxide coating on the FeS surface inhibits the solution-phase oxidation following FeS dissolution. Instead, FeS is mostly oxidized into lepidocrocite (γ-FeOOH) via the surface-mediated oxidation without dissolution. At neutral pH, FeS is oxidized via both the solution-phase oxidation following FeS dissolution and the surface-mediated oxidation mechanisms. The mobilization of arsenic during FeS oxidation is strongly affected by FeS oxidation mechanisms. At acidic pH (and to some extent at neutral pH), the rapid FeS dissolution and the slow precipitation of Fe (oxyhydr)oxides results in arsenic accumulation in water. In contrast, the surface-mediated oxidation of FeS at basic pH leads to the direct formation of Fe (oxyhydr)oxides, which provides effective adsorbents for As under oxic conditions. At acidic and neutral pH, the solution-phase oxidation of dissolved Fe(II) accelerates the oxidation of the less adsorbing As(III) to the more adsorbing As(V). This study reveals that the oxidative mobilization of As may be a significant pathway for arsenic enrichment of porewaters in sulfidic sediments.     

Removing derelict fishing gear from the deep seabed of the East Sea

The East Sea, with an average depth of 1700 m, has long been subject to heavy fishing pressure, resulting in derelict fishing gear. Most derelict fishing gears, such as fishing nets, fishing ropes, and crab pots, sink to the seabed and do not degrade. This gear results in “ghost fishing,” which has adverse impacts on deep benthic habitats. Recently, the Korean government has started to remove derelict fishing gears from the deep seabed of the East Sea by bottom trawling with heavy hooks (50–80 kg) and ropes. A total of 207.8 and 252.2 tons of marine debris in 2009 and 2010, respectively, were removed from the seabed, most of which were derelict fishing gears. Contrary to monitoring surveys and clean-up in shallow waters, removal of marine debris from remote deep habitats is much more difficult and dangerous for removal crews.     

Availability of coastal groundwater discharge as an alternative water resource in a large-scale reclaimed land,Korea

This study was conducted to identify the availability of coastal groundwater discharge (CGD), subsurface fluids flowing from inland through the coastal area to sea, as an alternative water resource for a large-scale reclaimed land. The behaviors of stable isotopes indicated that groundwater originated from inland precipitation and traveled as CGD along the coast line. Most of the groundwater samples collected from domestic wells installed along the old coast line were considered to be relatively fresh from the correlation analysis among chemical constituents. The average electrical conductivity (EC) values of the samples were identified as averaging 1,125–1,297 μS cm^?1, corresponding to appropriate crop growth. A weathered-rock layer in a small catchment within the reclaimed land was proved to be a main CGD pathway, with electrical resistivity anomalies ranging from 7 to 14 Ω m. Five monitoring wells were placed in this catchment to delineate the occurrence of CGD. Long-term vertical EC profiling results for the monitoring wells indicated that CGD occurs within a depth of 30 m below the ground surface. Annual monitoring data for groundwater level and EC demonstrated that the water quality of CGD was improved by introducing fresh terrestrial groundwater. A remarkable improvement in water quality (EC decrease of 900–1,600 μS cm^?1) of CGD was observed during the saline water pumping test that explains how CGD could be an alternative water resource for the reclaimed land.     

Comparison of sedimentation-compression curves obtained by nuclear and gravimetric methods for Wilkinson Basin,Gulf of Maine,sediments

Accurate measurements of bulk density are important in the construction of sedimentation-compression curves of water-saturated, fine-grained cohesive sediments for consolidation studies. The bulk density of five cores was measured nondestructively on a laboratory nuclear transmission densitometer and the water content, expressed as void ratio, was derived from an empirical relationship between bulk density and water content. Bulk density and water content measured destructively was determined every 10 cm for a comparison with the nuclear data. Agreement between nuclear and gravimetric methods was within ± 0.02 g/cm³ for bulk density ranging from 1.2 to 1.4 g/cm³. Sedimentation-compression curves made using both methods were in generally good agreement.In the Wilkinson Basin, void ratio gradually decreases with increasing effective overburden pressure. This indicates that consolidation by dewatering the surficial sediments is normal and that the environmental conditions during deposition remained relatively constant.     

Self-affinity dimensions of topography and its implications in morphotectonics: an example from Taiwan

This paper discusses the self-affinity dimensions of landscape surfaces at a short-range scale and the link to morphotectonic features of the young orogenic belts of Taiwan. The variogram method is adopted to estimate such parameters as the fractal dimension (D), the ordinate-intercept (γ) and the range (R) from data subsets of the digital elevation model (DEM) in a moving-window operation. The fractal morphology expressed by D and γ is found to be useful in defining geomorphic provinces that are related to tectonic features. The mountainous terrain is characterized by high gamma values and low fractal dimensions in contrast to the coastal plains where low gamma values and high fractal dimensions are found. A zone, defined by the fractal parameters (2.4<D<2.6 and 0<γ<2.4), is found to coincide with the most tectonically active zone of Taiwan. Active faults often occur at the boundary between landscapes with contrasting fractal patterns. In the flat lowlands along the western coast, the fractal morphology displays a west-facing amphitheatric pattern, which may be related to the indentation of the pre-Miocene Peikang Basement High. The fractal morphology may reflect some subtle changes in surface textures of a landscape sculpted by surface processes, which in turn are influenced by tectonic activities. The surface roughening and diffusive smoothing may concur to shape the landscape surface at the short ranges we discuss in this study.     

A comparison of several wave spectra for the random wave diffraction by a semi-infinite breakwater

A comparison of the diffraction of multidirectional random waves using several selected wave spectrum models is presented in this paper. Six wave spectrum models, Bretschneider, Pierson–Moskowitz, ISSC, ITTC, Mitsuyasu, and JONSWAP spectrum, are considered. A discrete form for each of the given spectrum models is used to specify the incident wave conditions. Analytical solutions based on both the Fresnel integrals and polynomial approximations of the Fresnel integrals and numerical solutions of a boundary integral approach have been used to obtain the two-dimensional wave diffraction by a semi-infinite breakwater at uniform water depth. The diffraction of random waves is based on the cumulative superposition of linear diffraction solution. The results of predicted random wave diffraction for each of the given spectrum models are compared with those of the published physical model presented by Briggs et al. [1995. Wave diffraction around breakwater. Journal of Waterway, Port, Coastal and Ocean Engineering—ASCE 121(1), 23–35]. Reasonable agreement is obtained in all cases. The effect of the directional spreading function is also examined from the results of the random wave diffraction. Based on these comparisons, the present model for the analysis of various wave spectra is found to be an accurate and efficient tool for predicting the random wave field around a semi-infinite breakwater or inside a harbor of arbitrary geometry in practical applications.     

A note on estimation of the Jacobian elliptic parameter in cnoidal wave theory

A new and simple calculating technique for the Jacobian elliptic parameter is presented in this study. The technique is very useful in generating a train of cnoidal waves in both laboratory and numerical wave tanks. Upon specification of water depth, the wave height and either the wave period or the wavelength, the proposed technique uses the Newton–Raphson method to estimate the Jacobian elliptic parameter directly, without trial and error procedures or look-up in tables. It is shown that the technique provides equally accurate results as the ad hoc methods previously used.