U-Pb, Hf and O isotope evidence for two episodes of fluid-assisted zircon growth in marble-hosted eclogites from the Dabie orogen

A combined study of internal structure, U-Pb age, and Hf and O isotopes was carried out for metamorphic zircons from ultrahigh-pressure eclogite boudins enclosed in marbles from the Dabie orogen in China. CL imaging identifies two types of zircon that are metamorphically new growth and recrystallized domain, respectively. The metamorphic zircons have low Th and U contents with low Th/U ratios, yielding two groups of ²⁰⁶Pb/²³⁸U age at 245 ± 3 to 240 ± 2 Ma and 226 ± 4 to 223 ± 2 Ma, respectively. Anomalously high δ¹⁸O values were obtained for refractory minerals, with 9.9 to 21.4‰ for garnet and 16.9‰ for zircon. This indicates that eclogite protolith is sedimentary rocks capable of liberating aqueous fluid for zircon growth during continental subduction-zone metamorphism. Most of the zircons are characterized by very low ¹⁷⁶Lu/¹⁷⁷Hf ratios of 0.000001-0.000028, indicating their growth in association with garnet recrystallization. A few of them falling within the older age group have comparatively high ¹⁷⁶Lu/¹⁷⁷Hf ratios of 0.000192-0.000383, suggesting their growth prior to the formation of garnet in the late stage of subduction. The variations in the Lu/Hf ratios for zircons can thus be used to correlate with garnet growth during eclogite-facies metamorphism. In either case, the zircons have variable ε_Hf (t) values for individual samples, suggesting that their protolith is heterogeneous in Hf isotope composition with localized fluid availability in the bulk processes of orogenic cycle. Nevertheless, a positive correlation exists between ²⁰⁶Pb/²³⁸U ages and Lu-Hf isotope ratios for the metamorphically recrystallized zircons, suggesting that eclogite-facies metamorphism in the presence of fluid has the identical effect on zircon Lu-Hf and U-Th-Pb isotopic systems. We conclude that the zircons of the older group grew in the presence of fluid during the subduction prior to the onset of peak ultrahigh-pressure metamorphism, whereas the younger zircons grew in the presence of fluid released during the initial exhumation toward high-pressure eclogite-facies regime.     

Are the South and North Liaohe Groups of North China Craton different exotic terranes? Nd isotope constraints

The Liaohe Group is an important Paleoproterozoic stratigraphic unit in the northeastern part of the North China Craton and is traditionally subdivided into the North and South Liaohe Groups. Associated with both the North and South Liaohe Groups are voluminous Paleoproterozoic granitoid rocks, named the Liaoji granitoids. Different tectonic models, including terrane amalgamation, continent–arc collision and rift closure, have been proposed to interpret the tectonic setting and evolution of the North and South Liaohe Groups and associated Liaoji granitoids. At the centre of the controversy between these models is whether or not the North and South Liaohe Groups developed on the same Archean basement. Nd isotopic geochemistry of the Liaoji granitoids provides important constraints on this controversial issue. The Liaoji granitoids associated with the North and South Liaohe Groups display similar ε_Nd values, restricted to a narrow range from 0 to 2, implying that these granitoid rocks were derived from the same or a similar magma source. Moreover, the Liaoji granitoids associated with the North and South Liaohe Groups have similar Nd model ages (T_DM), ranging from 2.4 to 2.6 Ga, suggesting that the protoliths of the Liaoji granitoids associated with both groups may have formed simultaneously, and that the basement rocks underneath the Liaoji granitoids and associated North and South Liaohe Groups belong to the same continental block rather than two different blocks. Combining lithological, structural and geochronological considerations, we interpret the North and South Liaohe Groups as having developed on a single late Archean basement that underwent Paleoproterozoic rifting associated with the intrusion of the Liaoji granitoids and the formation of the Liaohe Group, and closed upon itself in the Paleoproterozoic.     

3-D seismic structure of the source area of the 1993 Latur, India, earthquake and its implications for rupture nucleations

The Latur earthquake (M_w 6.1) of 29 September 1993 is a rare stable continental region (SCR) earthquake that occurred on a previously unknown blind fault. In this study, we determined detailed three-dimensional (3-D) P- and S-wave velocity (V_p, V_s) and Poisson's ratio (σ) structures by inverting the first P- and S-wave high-quality arrival time data from 142 aftershocks that were recorded by a network of temporary seismic stations. The source zone of the Latur earthquake shows strong lateral heterogeneities in V_p, V_s and σ structures, extending in a volume of about 90 × 90 × 15 km³. The mainshock occurred within, but near the boundary, of a low-V_p, high-V_s and low-σ zone. This suggests that the structural asperities at the mainshock hypocenter are associated with a partially fluid-saturated fractured rock in a previously unknown source zone with intersecting fault surfaces. This might have triggered the 1993 Latur mainshock and its aftershock sequence. Our results are in good agreement with other geophysical studies that suggest high conductivity and high concentration of radiogenic helium gas beneath the source zone of the Latur earthquake. Our study provides an additional evidence for the presence of fluid related anomaly at the hidden source zone of the Latur earthquake in the SCR and helps us understand the genesis of damaging earthquakes in the SCR of the world.     

Modeling the seismic response of basin-edge structure by a sequential waveform method

A sequential waveform method is developed to simulate the seismic response of basin-edge structure excited by a plane incident P-wave. The full procedure involves: (a) a previous parameterization of the investigated model using the seismic wave velocities and depths of the sedimentary stratifications; (b) an input motion determined from the records at stations installed on hard rock; (c) forward computation of the P-SV elastic wave field by means of a two-dimensional finite difference (FD) method; (d) the optimization of the model vector using simulated annealing technique and comparing the simulated seismic response of the tested structure with the observed wave field; (e) the correction of the initial model by trial-and-error by testing the differences between synthetics and observed data, and (f) the final solution obtained by iteration using the conjugate gradient algorithm. The search of an optimal basin-edge model has been parallel processed by varying the shapes and velocities of strata on the basis of the fitting of relative timing, amplitude and phase between the output and the observed data. The input motion and sensitivity have been checked and the validity of the method has been demonstrated by numeric analysis. Using the teleseismic records generated by 7 earthquakes recorded at 26 broadband seismic stations, we have studied the seismic velocity structure of the southern edge of the Jiyang depression located in the Bohai Bay basin, northern China. Two cross sections show an agreement between the velocity results and the geological sections available in the region. In addition, we obtain evidence of three hidden faults under the sections and features that suggest major extensions at the Paleogene.     

Detection of spectral variability of the optical component of the IR source IRAS 20508+2011

Our high-resolution spectral observations have revealed variability of the optical spectrum of the cool star identified with the IR source IRAS 20508+2011. We measured the equivalent widths of numerous absorption lines of neutral atoms and ions at wavelengths 4300–7930 Å, along with the corresponding radial velocities. Over the four years of our observations, the radial velocity derived from photospheric absorption lines varied in the interval V _r⊙ = 15–30 km/s. In the same period, the Hα profile varied from being an intense bell-shaped emission line with a small amount of core absorption to displaying two-peaked emission with a central absorption feature below the continuum level. At all but one epoch, the positions of the metallic photospheric lines were systematically shifted relative to the Hα emission: ΔV _r = V _r(met) ? V _r(Hα, emis) ≈ ?23 km/s. The Na D doublet displayed a complex profile with broad (half-width ≈ 120 km/s) emission and photospheric absorption, as well as an interstellar component. We used model atmospheres to determine the physical parameters and chemical composition of the star’s atmosphere: T _eff = 4800 K, log g = 1.5, ξ_t = 4.0 km/s. The metallicity of the star differs little from the solar value: [Fe/H]_⊙ = ?0.36. We detected overabundances of oxygen [O/Fe]_⊙ = +1.79 (with the ratio [C/O] ≈ ?0.9), and α-process elements, as well as a deficit of heavy metals. The entire set of the star’s parameters suggests that the optical component of IRAS 20508+2011 is an “O-rich” AGB star with luminosity M _v ≈ ?3^m that is close to its evolutionary transition to the post-AGB stage.     

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.     

A simple hypoplastic model for normally consolidated clay

The paper presents a simple constitutive model for normally consolidated clay. A mathematical formulation, using a single tensor-valued function to define the incrementally nonlinear stress–strain relation, is proposed based on the basic concept of hypoplasticity. The structure of the tensor-valued function is determined in the light of the response envelope. Particular attention is paid towards incorporating the critical state and to the capability for capturing undrained behaviour of clayey soils. With five material parameters that can be determined easily from isotropic consolidation and triaxial compression tests, the model is shown to provide good predictions for the response of normally consolidated clay along various stress paths, including drained true triaxial tests and undrained shear tests.     

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.     

桂北地区早石炭世杜内期的长身贝类的发现及其生物古地理意义

在广西北部兴安县高尚镇金子山剖面下石炭统鹿寨组底部，新发现了长身贝类腕足化石，包括1新种、1个相似种、6个未定种和2个属种未定类型。这些长身贝类以Productellidae和Productidae科的分子为主，另有少量Echinoconchidae和Monticuliferidae科的分子。这些长身贝类全部属于生活在静水环境中的薄壳类型，无一与华南同期地层中已知类型相同。它们之间的差异可能反映了不同沉积环境条件对腕足动物群属种的控制。在鹿寨组底部发现的长身贝类以及近年在桂林南边村和黔南睦化剖面腕足动物群的发现显示出华南台缘斜坡―盆地相区杜内阶中的腕足动物群具有极高的属种分异度，不但有大量见于世界其他地方同期动物群中的分子，也包含有不少原本认为只在维宪阶或更高层位出现的类型或全新的类型，说明华南台缘斜坡―盆地相区不但与世界其他地区的腕足动物群之间存在密切的生物地理区系联系，而且华南台缘斜坡―盆地相区是杜内期腕足动物起源和辐射演化的重要策源地之一。许多属种可能是在这里起源，并迁移扩散到其他地方。     

新近沉积粉细砂层地基的试验与评价

通过对邯郸市某车间地基的勘察．分析和探讨了新近沉积粉细砂地层的勘察手段、其物理力学性质，及其利用载荷试验确定承载力的标准取得了较为满意的结果，提出的一些分析方法，对新近沉积的粉细砂地层的勘察具有一定的借鉴作用。