Rb-Sr and K-Ar systems of biotite in surface environments regulated by weathering processes with implications for isotopic dating and hydrological cycles of Sr isotopes

Biotite is widely used for Rb-Sr and K-Ar isotopic dating and influences Sr isotope geochemistry of hydrological regimes. The isotopic system of biotite behaves diversely in response to surface weathering; i.e. the complete preservation of original Rb-Sr and K-Ar isotopic ages or dramatic reduction. In this study, we have explored the relation between the behavior of isotopic systems and complex weathering processes of biotites in the weathering profiles distributed on the Mesozoic granitoids in South Korea. In the lower parts of the profiles, biotite in the early stages of weathering was transformed into either oxidized biotite or hydrobiotite, with a mass release of ⁸⁷Sr and ⁴⁰Ar forced by the rapid oxidation of ferrous iron. During the transformation to oxidized biotite, ⁸⁷Sr and ⁴⁰Ar were preferentially released relative to Rb and K, respectively, via solid-state diffusion through the biotite lattice, resulting in a drastic reduction of original isotopic age. The reduction of Rb-Sr age was greater than that of K-Ar age because K was preferentially released over Rb whereas ⁸⁷Sr and ⁴⁰Ar were released proportionally to each other. However, during the transformation of biotite to hydrobiotite (i.e., to regularly interstratified biotite-vermiculite), ⁸⁷Sr, Rb, ⁴⁰Ar, and K were completely retained in the alternating biotite interlayer, and thus the original isotopic age can be preserved. In the upper parts of the profiles, where iron oxidation was almost completed, ⁸⁷Sr, Rb, ⁴⁰Ar, and K were gradually and proportionally released, with no further significant change in isotopic age during the gradual transformation of the early-formed oxidized biotite into hydrobiotite and vermiculite or during their final decomposition to kaolinite. The ratios and amounts of isotopes released from weathered biotites are dependent upon the degree of iron oxidation and the pathways of mineralogical transformation. Regional and local variations in isotopic systems affected by particular weathering processes should be considered when dating biotite or biotite-bearing rocks in weathering environments, modeling the transfer of Sr isotopes to hydrologic regimes, and tracking the provenance of sediments.     

Evaluation of heavy metal contamination and implication of multiple sources from Hunchun basin, northeastern China

Present concentrations and distributions of heavy metals through profiles, surface soil, and stream sediment samples in the Hunchun area, north-eastern China, were investigated to determine the elemental background values. This study also aims to characterize potentially toxic materials such as pulverized fly ash (PFA) from power stations or ash and slag from coal used domestically in urban areas, agrochemicals applied inappropriately, and urban sewage sludges from Hunchun City, as well as to ascertain the possibility of natural enrichment through site characterization by mineralogical and geochemical investigation. The distribution of contaminants in the alluvial soils (fluvisol) of this area has been influenced by several interacting factors. The parent alluvial materials from weathered products of amphiboles have made coatings such as ferrihydrite, goethite, and hematite. This natural inheritance factor is supported by the fact that the concentrations of weak acid-extractable (plant-available) heavy metals are very low, except for Fe and Mn. However, in agricultural soils and adjacent stream sediments, an anthropogenic input of Cd, Pb, Ni and Cr by agrochemicals is strongly suggested. Also, F contamination by coal combustion and the dissolution of F-bearing minerals could cause some future problems. Wide distribution and significantly high concentrations of Cd, Fe, Mn, and F in soils throughout the combination of pollutants originating from lithogenic and the anthropogenic sources pose potential problems in utilizing water resources. Received: 14 June 1999 · Accepted: 27 December 1999     

Star formation and figure rotation in the early-type galaxy NGC 2974

We present Galaxy Evolution Explorer ( GALEX ) far-ultraviolet (FUV) and near-ultraviolet (NUV) imaging of the nearby early-type galaxy NGC 2974, along with complementary ground-based optical imaging. In the ultraviolet, the galaxy reveals a central spheroid-like component and a newly discovered complete outer ring of radius 6.2 kpc, with suggestions of another partial ring at an even larger radius. Blue FUV–NUV and UV-optical colours are observed in the centre of the galaxy and from the outer ring outwards, suggesting young stellar populations (≲1 Gyr) and recent star formation in both locations. This is supported by a simple stellar population model which assumes two bursts of star formation, allowing us to constrain the age, mass fraction and surface mass density of the young component pixel by pixel. Overall, the mass fraction of the young component appears to be just under 1 per cent (lower limit, uncorrected for dust extinction). The additional presence of a nuclear and an inner ring (radii 1.4 and 2.9 kpc, respectively), as traced by [O  iii ] emission, suggests ring formation through resonances. All three rings are consistent with a single pattern speed of  78 ± 6  km s⁻¹ kpc⁻¹, typical of S0 galaxies and only marginally slower than expected for a fast bar if traced by a small observed surface brightness plateau. This thus suggests that star formation and morphological evolution in NGC 2974 at the present epoch are primarily driven by a rotating asymmetry (probably a large-scale bar), despite the standard classification of NGC 2974 as an E4 elliptical.     

Species composition and spatial distribution of euphausiids of the yellow sea and relationships with environmental factors

We investigated species composition and spatial distribution of the euphausiid community in the Yellow Sea and identified the relationship with environmental factors (temperature, salinity, chlorophyll a, nitrate, phosphate, and silicate) using bimonthly data from June, 1997 to April, 1998. The environment varied during the sampling period. In warm seasons, thermocline was well developed rendering lower temperature and higher salinity and nutrient concentrations in the bottom layer. During cold seasons the water column was well mixed and no such vertical stratification was noted. Horizontal distribution of temperature, however, differed slightly between near-coast and offshore areas because of the shallow depth of the Yellow Sea, and between southern and northern areas because of the intrusion of water masses such as Yellow Sea Warm Current and Changjiang River Diluted Water. Four euphausiid species were identified:Euphausia pacifica, E. sanzoi, Pseudeuphausia sp. andStylocheron affine. E. sanzoi andS. affine were collected, just one juvenile each, from the southern area in June and December, respectively.Pseudeuphausia sp. were collected in the eastern area all the year round except June.E. pacifica occurred at the whole study area and were the predominant species, representing at least 97.6% of the euphausiid abundance. Further, the distribution pattern of the species was varied in regards to developmental stages (adult, furcilia, calyptopis, egg). From spring to fall,E. pacifica adults were abundant in the central area where the Yellow Sea Bottom Cold Water prevailed. Furcilia and calyptopis extended their distribution into nearly all the study area during the same period. From late fall to winter, adults were found at the near-coastal area with similar pattern for furcilia and calyptopis. The distribution pattern ofE. pacifica was consistent regarding temperature, salinity, and three nutrients during the sampling period, whereas chlorophyll a showed a different pattern according to the developmental stages. The nutrients should indirectly affect via chlorophyll a and phytoplankton concentration. With respect to these results, we presented a scenario about how the environmental factors along with the water current affect the distribution ofE. pacifica in the Yellow Sea.     

Verification and validation of a seismic response analysis code for framed structures using the ASI‐Gauss technique

In this report, the capabilities of the adaptively shifted integration (ASI)‐Gauss code in the analysis of the seismic responses of framed structures are verified and validated by comparing the results with detailed numerical simulations performed by the parallel finite element analysis code, E‐Simulator, and with experimental results obtained by E‐Defense. The numerical results obtained by both codes showed good agreement with the experimental results obtained by E‐Defense. Furthermore, seismic waves with unnaturally large magnitudes are applied to a high‐rise building model to demonstrate the ability of the ASI‐Gauss code to analyze the collapse behaviors of building frames. Copyright © 2013 John Wiley & Sons, Ltd.     

Age and Growth of Southern Bluefin Tuna,Thunnus maccoyii,Based on Otolith Microstructure

Ocean Science Journal - Age and growth of southern bluefin tuna (SBT, Thunnus maccoyii) were estimated based on otoliths collected by Korean tuna longline vessels in the Atlantic and Indian Oceans...     

Effect of highly pervious geological features on ground-water flow into a tunnel

Current practice for estimating water inflow rate relies mostly on analytical solutions which assume a homogeneous, isotropic porous medium around a tunnel. Field measurements indicate that current engineering practice does not consistently make adequate estimate of ground-water flow into a tunnel during excavation due to various factors that analytical solutions do not properly take into account. Among the various factors affecting ground-water flow, the significance of a highly pervious feature located near the tunnel is discussed in this research. The highly pervious feature, which is located near an underground opening and connected to a large source of water, can provide a path for relatively high-head water to the joints intersecting the opening. This paper describes the influence of a highly pervious feature on the ground-water flow regime around a tunnel and the change of inflow rate as the tunnel approaches a highly pervious feature.     

Assessment of internal stability of sand–fine mixture using particle detachment model and its implications on suffusion

Acta Geotechnica - This study investigated the microscale assessment of the stability of fine particles from calculated hydrodynamic and adhesive torques of attached fine particles on sand...