Nearshore suspended sediment variations,central Surinam coast

Nearshore suspended sediment concentration along the muddy Surinam coast is highly variable; maximum values are many times greater than on other muddy coasts. Water samples taken at four field stations during various stages of the tide range in concentration from 15 to 3,700 mg/l near the surface and from 100 to 30,000 mg/l near the bottom. Highest overall concentrations and greatest variability in concentration occur in water over large banks of fluid mud (thixotropic gel) that extend 2–3 km offshore and 5–10 km along-shore. On both the intertidal and subaqueous portions of these mudbanks highest concentrations are found at low tide. Results provide evidence that an exchange between fluid mud and suspended sediment takes place during each tidal cycle.     

Age trends in garnet-hosted monazite inclusions from upper amphibolite facies schist in the northern Grouse Creek Mountains, Utah

We performed in situ Th-Pb dating of monazite in upper amphibolite facies pelitic schist from the Grouse Creek Mountains in northwest Utah. Sixty-six ages from inclusions in four garnet grains range from 37 to 72 Ma and decrease with radial distance from garnet cores. The age range of 30 matrix monazite grains overlaps and extends to younger ages than inclusions (25-58 Ma). The monazite grains are not intersected by cracks in the garnets, through which dissolution, reprecipitation or Pb loss might occur, and are generally too small (<20 μm) to allow for more than one age determination on any one grain. Processes that might explain inclusion ages that decrease with radial distance from garnet cores include: (1) Pb diffusion in monazite, (2) dissolution and reprecipitation of monazite, and (3) co-crystallization of monazite and garnet. After consideration of these possibilities, it is concluded that the co-crystallization of monazite and garnet is the most plausible, with monazite neoblasts deriving REEs from the breakdown of muscovite. Garnet ages derived by regression of the inclusion ages and assuming a constant rate of volume increase during garnet growth yield model ages with a maximum difference between core and rim of 22 m.y.     

Identification and quantification of carbonyl-containing α-pinene ozonolysis products using <Emphasis Type="Italic">O</Emphasis>-<Emphasis Type="Italic">tert</Emphasis>-butylhydroxylamine hydrochloride

The yields of carbonyl-containing reaction products from the ozonolysis of α-pinene have been investigated using concentrations of ozone found in the indoor environment ([O₃] ≤ 100 ppb). An impinger was used to collect gas-phase oxidation products in water, where the derivatization agent O-tert-butylhydroxylamine hydrochloride (TBOX) and gas chromatography-mass spectrometry were used to identify carbonyl-containing species. Seven carbonyl-containing products were observed. The yield of the primary product, pinonaldehyde was measured to be 76 %. Using cyclohexane as a hydroxyl radical (?OH) scavenger, the yield of pinonaldehyde decreased to 46 %, indicating the influence secondary OH radicals have on α-pinene ozonolysis products. Furthermore, the use of TBOX, a small molecular weight derivatization agent, allowed for the acquisition of the first mass spectral data of oxopinonaldehyde, a tricarbonyl reaction product of α-pinene ozonolysis. The techniques described herein allow for an effective method for the collection and identification of terpene oxidation products in the indoor environment.     

The relationship between beam transmission and concentration of suspended particulate material in the Neuse River estuary,North Carolina

Monthly measurements made at 15 stations along the axis of the upper Neuse River estuary show a highly variable degree of correlation between concentration of suspended particulate material (SPM) and attenuation of light (c) as measured by transmissometer. Coefficients of determination along transect lines ranged from 0.12 to 0.93 and calibration slopes ranged from 0.50 to 5.63. When examined on a station-by-station basis, coefficients of determination ranged from 0.21 to 0.96 and calibration slopes ranged from 1.04 to 4.94. Surface calibrations made at individual stations over the full 13-month period were the most consistent of all observations and were considerably better than calibrations made using all of the stations on a given day. Organic content, which can dominate the suspended sediment load during some months, does not appear to explain the variations in reliability of the calibrations. However, an abundance of large aggregates with time-varying size and shape distributions may be partly responsible for variations in optical properties of the sediments, and thus may confound the relationship between SPM and c in the Neuse River estuary. Time-varying calibrations to account for non-negligible changes in optical properties may not suffice in complex estuarine environments where the in situ particle dynamics are poorly understood.     

Late Holocene coastal sand movements in the Outer Hebrides, N.W. Scotland

Lithostratigraphical and biostratigraphical investigation of coastal marshes along the Atlantic coast of the Outer Hebrides from Lewis in the north to Barra in the south discloses inland-tapering sand units within marshland areas. The inland extent of each sand unit has been radiometrically dated and the units have been collectively interpreted as a proxy for past coastal storminess. The data appear to indicate that for the study sites investigated, the majority of the sand units were produced during episodes of climate deterioration both prior to and after the well-known period of Medieval warmth (MWP). Many were produced after ca. AD 1400. It is argued that the episodes of sand blow indicated by the deposits may reflect periods of increased cyclogenesis in the Atlantic associated with increased sea ice cover and an increase in the thermal gradient across the North Atlantic region.     

Nitrogen and phosphorus species in the coastal and shelf waters of Southeastern North Carolina, Mid-Atlantic U.S. coast

The diversity of small-scale wetlands, high salinity tidal creeks, salt marshes, estuaries, and a wide and shallow shelf with the Gulf Stream close to the break makes the coastal zone of south-eastern North Carolina (U.S.) a natural laboratory for the study of the cycling of nitrogen (N) and phosphorus (P) in coastal and shelf waters. We assessed the summer concentrations, forms, and ratios for each N (total dissolved N, nitrate + nitrite, ammonium and dissolved organic N) and P (total dissolved P, o-phosphate and dissolved organic P) pool as these nutrients travel from tidal creeks, salt marshes and two large estuaries to Long and Onslow Bays. Additionally, we measured ancillary physical (temperature, salinity and turbidity) and chemical (dissolved oxygen, chlorophyll a and pH) water properties. Highest concentrations of all individual N and P compounds were found in the upper parts of each tributary and were attributed to loads from agricultural and urban sources to the coastal watersheds, continuing downstream to receiving estuaries. In all areas, dissolved organic N and P species were predominant constituents of the total dissolved N and P pools (64–97% and 56–93%, respectively). The lower parts of estuaries and surface shelf waters were characterized by oceanic surface values, indicating removal of N and P downstream in all tributaries. The different watershed and hydrological characteristics also determined the different speciation of N and P pools in each estuary. Despite a high level of anthropogenic pressure on the uppermost coastal waters, there is self-regulation in this coastal ecosystem with respect to human perturbations; i.e. significant amounts of the N and P load are retained within estuarine and nearshore waters without reaching the shelf.     

Attenuated basin‐margin sequence stratigraphy of the Palaeoproterozoic Calvert and Isa Superbasins: The Fickling Group,southern Murphy Inlier,Queensland

Sedimentary rocks of the Palaeoproterozoic Calvert and Isa Superbasins are exposed across a large area of northern Australia. Despite the extent of the exposures there is little to indicate the nature of the basin margins as most outcrop boundaries are structurally or erosionally defined, or the margins, where preserved, are concealed beneath younger basins. The Murphy Inlier, which forms the boundary between the Mt Isa and McArthur Basins, is unique in that on its southern flanks a basin‐margin succession is well‐preserved as the Fickling Group. A detailed sequence‐stratigraphic analysis of outcrop sections and well logs, supplemented by seismic reflection profiles and SHRIMP U–Pb zircon ages, shows that all seven supersequences of the Isa Superbasin and one supersequence from the older Calvert Superbasin are represented in the Fickling Group. Through this high‐resolution sequence‐stratigraphic framework, it is possible to accurately correlate chronostratigraphically equivalent strata from the McNamara Group on the central Lawn Hill Platform to the Fickling Group on the southern Murphy Inlier. Each supersequence thins substantially from the McNamara Group (～11 km thick) to the Fickling Group (<1 km thick). The combined effects of truncation and onlap of sequences over the Murphy Inlier basement high are responsible for the thinning. Major time breaks of up to 25 million years occur between supersequences in the Fickling Group. Erosional hiatuses are often manifested at the base of supersequences as conglomerate beds composed of silicified detritus from older strata. Sequences in the Fickling Group were generally deposited in a proximal basin‐margin setting, while sequences in the McNamara Group were deposited in distal basin depocentres. The proximal depositional setting of Fickling Group sequences reduces the number of thick carbonaceous shale and siltstone intervals, which often host Zn–Pb–Ag and Cu deposits in the McNamara Group. Many host sequences from the McNamara Group are also absent in the Fickling Group due to truncation and onlap pinchout. Consequently, the economic potential of Palaeoproterozoic strata on the southern Murphy Inlier is less than equivalent strata from the central Lawn Hill Platform. Despite this, potential does exist for future discoveries of economic mineral deposits in the Mt Les Siltstone and Walford Dolomite units of the Fickling Group.     

First evidence for episodic flooding events in the arid interior of central Saudi Arabia over the last 60 ka

Although evidence for Quaternary environmental changes in the Arabian Peninsula is now growing, research has mostly been conducted in the United Arab Emirates (UAE) and in the Sultanate of Oman. There have been virtually no recent studies in Saudi Arabia, especially in the central region such as around Al‐Quwaiayh. In this area there are a series of outwash plains developed along the eastern edge of the Arabian Shield that formed in the late Quaternary. Four sedimentary sections, which are representative of the deposits that have accumulated, have been studied and five luminescence ages obtained. These are the first luminescence ages acquired from Quaternary sediments in central Saudi Arabia. The preserved fluvial deposits in the study area have formed during humid events at ca. 54 ka, ca. 39 ka and ca. 0.8 ka. In more recent times aeolian sands have been encroaching on to the distal parts of the outwash plains. Copyright © 2008 John Wiley & Sons, Ltd.