The Palaeoproterozoic Kristineberg VMS deposit, Skellefte district, northern Sweden, part I: geology

The Kristineberg volcanic-hosted massive sulphide (VMS) deposit, located in the westernmost part of the Palaeoproterozoic Skellefte district, northern Sweden, has yielded 22.4 Mt of ore, grading 1.0% Cu, 3.64% Zn, 0.24% Pb, 1.24 g/t Au, 36 g/t Ag and 25.9% S, since the mine opened in 1941, and is the largest past and present VMS mine in the district. The deposit is hosted in a thick pile of felsic to intermediate and minor mafic metavolcanic rocks of the Skellefte Group, which forms the lowest stratigraphic unit in the district and hosts more than 85 known massive sulphide deposits. The Kristineberg deposit is situated lower in the Skellefte Group than most other deposits. It comprises three main ore zones: (1) massive sulphide lenses of the A-ore (historically the main ore), having a strike length of about 1,400 m, and extending from surface to about 1,200 m depth, (2) massive sulphide lenses of the B-ore, situated 100–150 m structurally above the A-ore, and extending from surface to about 1,000 m depth, (3) the recently discovered Einarsson zone, which occurs in the vicinity of the B-ore at about 1,000 m depth, and consists mainly of Au–Cu-rich veins and heavily disseminated sulphides, together with massive sulphide lenses. On a regional scale the Kristineberg deposit is flanked by two major felsic rock units: massive rhyolite A to the south and the mine porphyry to the north. The three main ore zones lie within a schistose, deformed and metamorphosed package of hydrothermally altered, dominantly felsic volcanic rocks, which contain varying proportions of quartz, muscovite, chlorite, phlogopite, pyrite, cordierite and andalusite. The strongest alteration occurs within 5–10 m of the ore lenses. Stratigraphic younging within the mine area is uncertain as primary bedding and volcanic textures are absent due to strong alteration, and tectonic folding and shearing. In the vicinity of the ore lenses, hydrothermal alteration has produced both Mg-rich assemblages (Mg-chlorite, cordierite, phlogopite and locally talc) and quartz–muscovite–andalusite assemblages. Both types of assemblages commonly contain disseminated pyrite. The sequence of volcanic and ore-forming events at Kristineberg is poorly constrained, as the ages of the massive rhyolite and mine porphyry are unknown, and younging indicators are absent apart from local metal zoning in the A-ores. Regional structural trends, however, suggest that the sequence youngs to the south. The A- and B-ores are interpreted to have formed as synvolcanic sulphide sheets that were originally separated by some 100–150 m of volcanic rocks. The Einarsson zone, which is developed close to the 1,000 m level, is interpreted to have resulted in part from folding and dislocation of the B-ore sulphide sheet, and in part from remobilisation of sulphides into small Zn-rich massive sulphide lenses and late Au–Cu-rich veins. However, the abundance of strongly altered, andalusite-bearing rocks in the Einarsson zone, coupled with the occurrence of Au–Cu-rich disseminated sulphides in these rocks, suggests that some of the mineralisation was synvolcanic and formed from strongly acidic hydrothermal fluids. Editorial handling: P. Weihed     

Chromium(VI) distributions in the Arctic and the Atlantic Oceans and a reassessment of the oceanic Cr cycle

Chromium(VI) concentrations ranging between 3.0 and 6.1 nmol l⁻¹ and 3.1 and 7.3 nmol l⁻¹ were found in the Arctic and Atlantic Oceans, respectively. The vertical profiles show modest depletion of chromium(VI) in surface waters, but poor overall correlations between Cr(VI) and nutrient profiles. Given that Cr(VI) is the dominant oxidation state of chromium in open-ocean waters, these data are combined with literature data to reassess the distribution of Cr in oceanic waters. It is concluded that while Cr shows some characteristics of both “recycled” and “accumulated” vertical profiles, it does not fall clearly within either group.     

Management responses to the problem of incidental catch in fishing: A comparative analysis of the EU,Norway, and the Faeroe Islands

The article addresses incidental catch as a two-level management problem for systems that regulate fish catches. The first level is legal and concerns the problem of establishing clear and legitimate criteria for criminal liability. The second level is environmental and concerns the efficacy of chosen liability criteria in resource conservation. The article compares and explains the solutions chosen by Norway, the Faeroe Islands, and the EU. Each solution constitutes a distinct form of fisheries management. It is argued that national choices are determined by administrative capacity for implementation and political autonomy in the distribution of fishing rights.     

Implications of a new,biostratigraphically well-controlled,radio-isotopic age for the lower Telychian Stage of the Llandovery Series （Lower Silurian,Sweden）

Radio-isotopic analysis of single zircons from two early Telychian K-bentonites, one of which is among the most widespread Lower Paleozoic volcanic ash falls in north- ern Europe, yields overlapping weighted mean 206pb/238U ages of 438. 7± 1.0 Ma and 437.8 ± 0.5 Ma, respectively. The former age is from zircons of the Osmundsberg K-bentonite from the type locality at Osmundsberget in the Siljan area of central Sweden where it occurs in the lower part of the Spirograptus tur- riculatus Graptolite Zone and in the lower part of the Angochitina longicollis Chitinozoan Zone. Zircons giv- ing the latter age are from a bed previously identified as the Osmundsberg K-bentonite at the Kallholn Quarry in the same area. Based on new biostratigraphic data, the latter bed is now considered to be slightly younger than the Osmundsberg K-bentonite. The dated stratigraphic level of the ash layers is slightly younger than the base of the Telychian Stage and thus represents a minimum age for the Aeronian/Telychian Stage boundary. A U-Pb age of 〉 438 Ma for the base of this stage, however, is older and in conflict with estimates in the most recent compilation of the Silurian time scale. In view of the fact that only three radio-isotopic dates from the entire Llan- dovery have been previously accepted, this new and biostratigraphically exceptionally well-controlled radio-isotopic date fills an important gap in the Lower Silurian geochronology.     

Moisture Transport Through Sprayed Concrete Tunnel Linings

Waterproofing of permanent sprayed concrete tunnel linings with sprayed membranes in a continuous sandwich structure has been attempted since 2000 and has seen increased use in some countries. The main function of a sprayed membrane from a waterproofing perspective is to provide crack bridging and hence prevent flow of liquid water into the tunnel through cracks and imperfections in the concrete material. However, moisture can migrate through the concrete and EVA-based membrane materials by capillary and vapor diffusion mechanisms. These moisture transport mechanisms can have an influence on the degree of saturation, and may influence the pore pressures in the concrete material as well as risk of freeze–thaw damage of the concrete and membrane. The paper describes a detailed study of moisture transport material parameters, moisture condition in tunnel linings and climatic conditions tunnels in hard rock in Norway. These data have been included in a hygrothermal simulation model in the software WUFI for moisture transport to substantiate moisture transport and long-term effects on saturation of the concrete and membrane material. The findings suggest that EVA-based membranes exhibit significant water absorption and vapor transport properties although they are impermeable to liquid water flow. State-of-the-art sprayed concrete material applied with the wet mix method exhibits very low hydraulic conductivities, lower than 10^?14 m/s, thus saturated conductive water flow is a very unlikely dominant transport mechanism. Moisture transport through the lining structure by capillary flow and vapor diffusion are calculated to approximately 3 cm³/m² per day for lining thicknesses in the range of 25–35 cm and seasonal Nordic climate variations. The calculated moisture contents in the tunnel linings from the hygrothermal simulations are largely in agreement with the measured moisture contents in the tunnel linings. The findings also indicate that the concrete material exhibits a reduction of saturation on the immediate inside of the membrane. Near the location of the waterproofing membrane on either side, the concrete material exhibits degrees of capillary saturation between 85 and 95 %. Moisture content in the membrane is found to be consistently in the range of 12–17 % by weight, corresponding to a degree of saturation of 30–35 %. Possible effects of such moisture contents are lower risk of freezing degradation, higher tensile bonding strengths at the membrane interfaces, and a reduced risk of pore pressure in the concrete material.     

Drought is the major limiting factor for tree-ring growth of high-altitude Canary Island pines on Tenerife

This is a detailed study of 50 wood cores sampled from 25 Canary Island pines ( Pinus canariensis ) growing in a subtropical climate close to the tree limit (at Lomo de Retamar, 2000–2100 m a.s.l.) on the southern, leeward side of Tenerife.
The Canary Island pines form tree-rings and, similarly to temperate pines, earlywood is formed during spring. But many pines fail to form tree-rings every year and one purpose for this paper has been to find a way to overcome this problem. Another purpose has been to see what correlations, if any, exist between the ring widths and meteorological data. Meteorological data have been collected since 1916 at the nearby Izaña meteorological observatory. It was also important to find the limiting factor for growth of Canary Island pines close to the tree limit.
Through cross-dating, missing rings were found to be typical for younger parts of older trees; in the same years younger trees instead had low growth. Some trees lacked more than 20 rings in a century. This study shows that it is possible to compensate for missing rings, at least when the number of missing rings is less than 10%.
Correlation studies showed that the growth of the tree rings was mainly due to the precipitation factor, particularly the annual precipitation one year before the ring formation, but also due to temperature. Strangely enough, multiple linear regression gave the highest correlation coefficient (0.50) for a combination of annual precipitation one year earlier and temperature four years earlier.     

Lead in the North Sea and the north east Atlantic Ocean

Lead has been determined in 105 water samples from the north east Atlantic and from the North Sea. Rigorous precautions were applied to avoid contamination during sampling and analysis.Two different analytical methods were used: ASV and AAS. Determinations with ASV were carried out on board, directly after sampling. After two months storage, acidified samples were analysed by AAS after freon dithiocarbamate extraction and nitric acid back extraction. Particulate lead was determined by AAS after an acid digestion.The profiles of lead concentration versus depth show around 160 pM at the surface and around 20 pM at the bottom, both in the Atlantic and in the Norwegian Sea. The shapes of the profiles are different, however, depending on the hydrography of the area sampled. The profiles from the north east Atlantic coincide with a recently published profile from the north west Atlantic. Moreover, these profiles have lead concentrations about a factor of three higher than those in the Pacific.Considering the high lead input to the North Sea, the lead concentrations found there are remarkably low, probably because of scavenging effects in estuaries leading to a short residence time in the water column. The dominant lead input in offshore regions is from the atmosphere. The highest lead levels are found in the northern North Sea, around 300 pM in surface water.In the Atlantic, particulate lead is a minor part of the total lead whereas in the North Sea the particulate fraction is larger, up to 40%.