Geochronology,stratigraphy and geochemistry of Cambro-Ordovician,Silurian and Devonian volcanic rocks of the Saxothuringian Zone in NE Bavaria (Germany)—new constraints for Gondwana break up and ocean–island magmatism

International Journal of Earth Sciences - Stratigraphically well-defined volcanic rocks in Palaeozoic volcano-sedimentary units of the Frankenwald area (Saxothuringian Zone, Variscan Orogen) were...     

Stable Cu and Zn isotope ratios as tracers of sources and transport of Cu and Zn in contaminated soil

Copper and Zn metals are produced in large quantities for different applications. During Cu production, large amounts of Cu and Zn can be released to the environment. Therefore, the surroundings of Cu smelters are frequently metal-polluted. We determined Cu and Zn concentrations and Cu and Zn stable isotope ratios (δ⁶⁵Cu, δ⁶⁶Zn) in three soils at distances of 1.1, 3.8, and 5.3 km from a Slovak Cu smelter and in smelter wastes (slag, sludge, ash) to trace sources and transport of Cu and Zn in soils. Stable isotope ratios were measured by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) in total digests. Soils were heavily contaminated with concentrations up to 8087 μg g⁻¹ Cu and 2084 μg g⁻¹ Zn in the organic horizons. The δ⁶⁵Cu values varied little (−0.12‰ to 0.36‰) in soils and most wastes and therefore no source identification was possible. In soils, Cu became isotopically lighter with increasing depth down to 0.4 m, likely because of equilibrium reactions between dissolved and adsorbed Cu species during transport of smelter-derived Cu through the soil. The δ⁶⁶Zn_IRMM values were isotopically lighter in ash (−0.41‰) and organic horizons (−0.85‰ to −0.47‰) than in bedrock (−0.28‰) and slag (0.18‰) likely mainly because of kinetic fractionation during evaporation and thus allowed for separation of smelter-Zn from native Zn in soil. In particular in the organic horizons large variations in δ⁶⁶Zn values occur, probably caused by biogeochemical fractionation in the soil-plant system. In the mineral horizons, Zn isotopes showed only minor shifts to heavier δ⁶⁶Zn values with depth mainly because of the mixing of smelter-derived Zn and native Zn in the soils. In contrast to Cu, Zn isotope fractionation between dissolved and adsorbed species was probably only a minor driver in producing the observed variations in δ⁶⁶Zn values. Our results demonstrate that metal stable isotope ratios may serve as tracer of sources, vertical dislocation, and biogeochemical behavior in contaminated soil.     

The constancy of galactic cosmic rays as recorded by cosmogenic nuclides in iron meteorites

We measured the He, Ne, and Ar isotopic concentrations and the ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From ⁴¹Ca and ³⁶Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the studied meteorites are falls. The data for the other 47 irons confirm that terrestrial ages for iron meteorites can be as long as a few hundred thousand years even in relatively humid conditions. The ³⁶Cl‐³⁶Ar cosmic ray exposure (CRE) ages range from 4.3 ± 0.4 Ma to 652 ± 99 Ma. By including literature data, we established a consistent and reliable CRE age database for 67 iron meteorites. The high quality of the CRE ages enables us to study structures in the CRE age histogram more reliably. At first sight, the CRE age histogram shows peaks at about 400 and 630 Ma. After correction for pairing, the updated CRE age histogram comprises 41 individual samples and shows no indications of temporal periodicity, especially not if one considers each iron meteorite group separately. Our study contradicts the hypothesis of periodic GCR intensity variations (Shaviv 2002, 2003), confirming other studies indicating that there are no periodic structures in the CRE age histogram (e.g., Rahmstorf et al. 2004; Jahnke 2005). The data contradict the hypothesis that periodic GCR intensity variations might have triggered periodic Earth climate changes. The ³⁶Cl‐³⁶Ar CRE ages are on average 40% lower than the ⁴¹K‐K CRE ages (e.g., Voshage 1967). This offset can either be due to an offset in the ⁴¹K‐K dating system or due to a significantly lower GCR intensity in the time interval 195–656 Ma compared to the recent past. A 40% lower GCR intensity, however, would have increased the Earth temperature by up to 2 °C, which seems unrealistic and leaves an ill‐defined ⁴¹K‐K CRE age system the most likely explanation. Finally, we present new ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne production rate ratios of 0.32 ± 0.01 and 0.44 ± 0.03, respectively.     

The Relation Between Humidity and Liquid Water Content in Fog: An Experimental Approach

Microphysical measurements of orographic fog were performed above a montane cloud forest in northeastern Taiwan (Chilan mountain site). The measured parameters include droplet size distribution (DSD), absolute humidity (AH), relative humidity (RH), air temperature, wind speed and direction, visibility, and solar short wave radiation. The scope of this work was to study the short term variations of DSD, temperature, and RH, with a temporal resolution of 3?Hz. The results show that orographic fog is randomly composed of various air volumes that are intrinsically rather homogeneous, but exhibit clear differences between each other with respect to their size, RH, LWC, and DSD. Three general types of air volumes have been identified via the recorded DSD. A statistical analysis of the characteristics of these volumes yielded large variabilities in persistence, RH, and LWC. Further, the data revealed an inverse relation between RH and LWC. In principle, this finding can be explained by the condensational growth theory for droplets containing soluble or insoluble material. Droplets with greater diameters can exist at lower ambient RH than smaller ones. However, condensational growth alone is not capable to explain the large observed differences in DSD and RH because the respective growth speeds are too slow to explain the observed phenomena. Other mechanisms play key roles as well. Possible processes leading to the large observed differences in RH and DSD include turbulence induced collision and coalescence, and heterogeneous mixing. More analyses including fog droplet chemistry and dynamic microphysical modeling are required to further study these processes. To our knowledge, this is the first experimental field observation of the anti-correlation between RH and LWC in fog.     

Effects of pollen leaching and microbial degradation on organic carbon and nutrient availability in lake water

Nutrient fluxes across terrestrial-aquatic boundaries and their subsequent integration into lake nutrient cycles are currently a major topic of aquatic research. Although pollen represents a good substrate for microorganisms, it has been neglected as a terrestrial source of organic matter in lakes. In laboratory experiments, we incubated pollen grains of Pinus sylvestris in water of lakes with different trophy and pH to estimate effects of pollen input and its subsequent microbial degradation on nutrient dynamics. In this ex situ experiment, we measured concentrations of organic carbon, phosphorus and nitrogen in the surrounding water as well as microbial dynamics (bacteria and fungal sporangia) at well-controlled conditions. Besides leaching, chemical and microbial decomposition of pollen was strongest within the first week of incubation. This led to a marked increase of soluble reactive phosphorus and total dissolved nitrogen (up to 0.04 and 1.5 mg L⁻¹, respectively, after 5 days of incubation) in the ambient water. In parallel, pollen grains were rapidly colonized by heterotrophic bacteria and aquatic fungi. Leaching and microbial degradation of pollen accounted for ≥80, ≥40, ≥50% for organic C, N and P, respectively, and did not significantly differ among water samples from the studied lakes. Thus, pollen introduces high amounts of bio-available terrestrial organic matter and nutrients into surface waters within a short time. A rough calculation on P input into oligotrophic Lake Stechlin indicates that pollen plays an important ecological role in nutrient cycling of temperate lakes. This requires further attention in aquatic ecology.     

Global photometric properties of Asteroid (4) Vesta observed with Dawn Framing Camera

Dawn spacecraft orbited Vesta for more than one year and collected a huge volume of multispectral, high-resolution data in the visible wavelengths with the Framing Camera. We present a detailed disk-integrated and disk-resolved photometric analysis using the Framing Camera images with the Minnaert model and the Hapke model, and report our results about the global photometric properties of Vesta. The photometric properties of Vesta show weak or no dependence on wavelengths, except for the albedo. At 554 nm, the global average geometric albedo of Vesta is 0.38 ± 0.04, and the Bond albedo range is 0.20 ± 0.02. The bolometric Bond albedo is 0.18 ± 0.01. The phase function of Vesta is similar to those of S-type asteroids. Vesta’s surface shows a single-peaked albedo distribution with a full-width-half-max ∼17% relative to the global average. This width is much smaller than the full range of albedos (from ∼0.55× to >2× global average) in localized bright and dark areas of a few tens of km in sizes, and is probably a consequence of significant regolith mixing on the global scale. Rheasilvia basin is ∼10% brighter than the global average. The phase reddening of Vesta measured from Dawn Framing Camera images is comparable or slightly stronger than that of Eros as measured by the Near Earth Asteroid Rendezvous mission, but weaker than previous measurements based on ground-based observations of Vesta and laboratory measurements of HED meteorites. The photometric behaviors of Vesta are best described by the Hapke model and the Akimov disk-function, when compared with the Minnaert model, Lommel–Seeliger model, and Lommel–Seeliger–Lambertian model. The traditional approach for photometric correction is validated for Vesta for >99% of its surface where reflectance is within ±30% of global average.     

Evidence for chemical evolution in spectra of high redshift galaxies

Using a sample of 57 VLT FORS spectra in the redshift range 1.37< z < 3.40 and a comparison sample with 36 IUE spectra of local ( ) starburst galaxies we derive CIV equivalent width values and estimate metallicities of starburst galaxies as a function of redshift. Assuming that a calibration of the CIV equivalent widths in terms of the metallicity based on the local sample of starburst galaxies is applicable to high-z objects, we find a significant increase of the average metallicities from about 0.16 Z _⊙ at the cosmic epoch corresponding to z ≈ 3.2 to about 0.42 Z _⊙ at z ≈ 2.3. A significant further increase in metallicity during later epochs cannot be detected in our data. Compared to the local starburst galaxies our high-redshift objects tend to be overluminous for a given metallicity. This revised version was published online in August 2006 with corrections to the Cover Date.