Non-equilibrium alcohol flooding model for immiscible phase remediation: 2. Model development and application

A non-equilibrium, two-phase, three-component compositional model for the simulation of alcohol flooding has been developed and tested. Inter-phase mass transfer algorithms allow for transfer of all three components at high concentrations and high mass flux rates using a two-film model. The model has been used to simulate alcohol floods where the alcohol has an affinity for either the water-rich phase, or the organic-rich phase. Calibration, using experimental effluent data from an alcohol flood which used a 2-propanol (IPA)-water-tetrachlorethene (PCE) ternary system, indicates that inter-phase mass transfer parameters can be non-unique. Sensitivity studies, completed using the non-equilibrium model for the IPA-water-PCE system, indicate that experimentally derived organic-rich phase composition data should lead to better estimates of the non-wetting phase film thickness. For alcohol flooding experiments where the primary mechanism of non-aqueous phase liquid (NAPL) removal is enhanced dissolution, near-equilibrium conditions may be achieved with NAPL recovery similar for conditions of near-equilibrium and equilibrium. However, for systems where remobilization is the primary mechanism of NAPL recovery, it is expected that although local conditions may approach equilibrium, the resulting NAPL recovery can be significantly lower than would be attained if equilibrium conditions persisted.     

Chlorine-36 and the initial value problem

 Chlorine-36 is a radionuclide with a half-life of 3.01×10⁵a. Most ³⁶Cl in the hydrosphere originates from cosmic radiation interacting with atmospheric gases. Large amounts were also produced by testing thermonuclear devices during 1952–58. Because the monovalent anion, chloride, is the most common form of chlorine found in the hydrosphere and because it is extremely mobile in aqueous systems, analyses of both total Cl^– as well as ³⁶Cl have been important in numerous hydrologic studies. In almost all applications of ³⁶Cl, a knowledge of the initial, or pre-anthropogenic, levels of ³⁶Cl is useful, as well as essential in some cases. Standard approaches to the determination of initial values have been to: (a) calculate the theoretical cosmogenic production and fallout, which varies according to latitude; (b) measure ³⁶Cl in present-day precipitation and assume that anthropogenic components can be neglected; (c) assume that shallow groundwater retains a record of the initial concentration; (d) extract ³⁶Cl from vertical depth profiles in desert soils; (e) recover ³⁶Cl from cores of glacial ice; and (f) calculate subsurface production of ³⁶Cl for water that has been isolated from the atmosphere for more than one million years. The initial value from soil profiles and ice cores is taken as the value that occurs directly below the depth of the easily defined bomb peak. All six methods have serious weaknesses. Complicating factors include ³⁶Cl concentrations not related to cosmogenic sources, changes in cosmogenic production with time, mixed sources of chloride in groundwater, melting and refreezing of water in glaciers, and seasonal groundwater recharge that does not contain average year-long concentrations of ³⁶Cl. Received, December 1996 · Revised, August 1997 · Accepted, August 1997     

The hydrothermal system of Volcan Puracé, Colombia

This paper presents chemical and isotopic data for thermal waters, gases and S deposits from Volcan Puracé (summit elevation 4600 m) in SW Colombia. Hot gas discharges from fumaroles in and around the summit crater, and thermal waters discharge from three areas on its flanks. The waters from all areas have D values of-75±1, indicating a single recharge area at high elevation on the volcano. Aircorrected values of³He/⁴He in thermal waters range from 3.8 to 6.7 R_A, and approach those for crater fumarole gas (6.1–7.1 R_A), indicating widespread addition of magmatic volatiles. An economic S deposit (El Vinagre) is being mined in the Rio Vinagre fault zone at 3600 m elevation. Sulfur isotopic data are consistent with a magmatic origin for S species in thermal waters and gases, and for the S ore deposit. Isotopic equilibration between S species may have occurred at 220±40°C, which overlaps possible equilibration temperatures (170±40°C) determined by a variety of other geothermometers for neutral thermal waters. Apparent CH₄–CO₂ equilibration temperatures for gases from thermal springs (400±50°C) and crater fumaroles (520±60°C) reflect higher temperatures deeper in the system. Hot magmatic gas ascending through the Rio Vinagre fault zone is though to have precipitated S and generated thermal waters by interaction with descending meteoric waters.     

GIS Methodology for Characterizing Historical Conditions of the Willamette River Flood Plain, Oregon

Recent environmental developments have stimulated an interest in conservation and restoration of the historical Willamette River flood plain, both to protect against flooding and to provide wildlife habitat. In order to best utilize scarce resources, we characterized historical and modern river channel and flood‐plain conditions to evaluate changes and help prioritize restoration sites. Using cartographic and photographic data sources, we developed a Geographic Information System (GIS) to map active channels, side channels, islands and tributaries for four separate dates, as well as riparian and flood‐plain vegetation characteristics for pre‐European settlement and modern time periods. Coverages based on flood records and other boundaries were used to partition the flood plain into spatial subsets for analysis. The GIS allowed comparisons between historical and present conditions for a variety of environmental factors. Much of the pre‐settlement channel complexity has been removed. Total channel length in 1995 was 26% less than in 1850, with almost 58% of the river's side channels disconnected from the system. In addition, we found a 72% loss of flood‐plain forest from 1850 to 1995, since it was converted to agricultural and urban land uses. Selected river and flood‐plain variables were made available for a spatial model to prioritize potential locations for flood‐plain restoration.     

Sediment transport in Washington and Norfolk submarine canyons

A sediment study suggests that Washington and Norfolk canyons off the Mid-Atlantic States are not inactive, but have served periodically since the Late Pleistocene as conduits of sediment originating on the adjacent shelf and upper slope. Large quantities of sand occur in the canyon heads as thin beds and laminae, and on the continental slope as mixtures of sand (to $\text{>40\%}$), silt and clay that are extensively reworked by burrowing organisms. Sandy turbidites occur in the canyons on the rise. Basinward dispersal, from the outer shelf and uppermost slope, is recorded by heavy mineral suites and bioclastic components, primarily foraminifera of shallow marine origin, in the lower slope and upper continental rise canyon cores. The down-axis movement of material, presumably episodic, in the Holocene to recent results from offshelf spillover into canyon heads, failure on the steep walls bordering canyons on the slope, and resuspension by bottom currents.     

Plate tectonics and offshore boundary delimitation: Tunisia-Libya case at the International Court of Justice

The first major offshore boundary dispute where plate tectonics constituted a significant argument was recently brought before the International Court of Justice by Libya and Tunisia concerning the delimitation of their continental shelves. Libya placed emphasis on this concept to determine natural prolongation of its land territory under the sea. Tunisia contested use of the entire African continental landmass as a reference unit and views geography, geomorphology and bathymetry as relevant as geology. The Court pronounced that “It is the outcome, not the evolution in the long-distant past, which is of importance.” Moreover, it is the present-day configuration of coasts and seabed that are the main factors, not geology.