Manganoan garnet rocks associated with the Broken Hill Pb–Zn–Ag orebody, Australia

Summary The Palaeoproterozoic Broken Hill Pb–Zn–Ag stratiform orebody is intimately associated with manganoan garnet-bearing rocks. On stratigraphic and chemical grounds it is argued that garnet-rich metasediments below, equivalent to and above massive sulphide were hydrothermal precipitates. Other manganoan garnet rocks formed during pre-metamorphic hydrothermal alteration, syn-metamorphic dehydration and reaction of manganese with prograde pelitic rocks, reaction between cataclastic manganese-bearing sulphide rocks injected along axial planes, shears and faults and pelitic wall rocks and reaction between dolerite dykes and sulphide rocks.     

The Skaergaard Layered Series. Part VI. Excluded Trace Elements

In contrast to the smooth trends of major elements and mineralcompositions, the excluded trace elements in the SkaergaardLayered Series have an irregular distribution that does notconform to the normal trends of Rayleigh-type fractionation.Their concentrations are about constant or even decline throughthe Lower and Middle Zones before increasing sharply to reachmaximum concentrations 100–200 m above the Sandwich Horizon.As in the case of included elements, the relative concentrationsof excluded elements in coexisting phases deviate widely fromthose predicted by experimentally determined partition coefficientsunder presumed magmatic conditions. This is seen most clearlyin the immiscible melanogranophyres and conjugate ferrogabbros.Although the major elements conform to the experimentally determinedrelations for immiscible liquids, the trace elements do not;they follow a totally independent trend. The abrupt increasein the concentrations of excluded elements in the upper partof the intrusion could plausibly be attributed to an additionof new magma or to a density inversion that resulted in upwardmigration of a late liquid or fluid, but these possibilitiesare inconsistent with the compositional and spatial relationsof the upper parts of the intrusion. Although a late residualliquid certainly migrated upward, the most likely explanationfor the observed distribution of excluded elements is that thepartition coefficients were altered by volatile components,which gradually increased during the early stages of crystallizationthen began to exsolve near the top of the Middle Zone. KEY WORDS: igneous differentiation; Skaergaard intrusion     

ELF propagation parameters for uniform models of the Earth–ionosphere waveguide

Uniform models for the Earth–ionosphere cavity are considered with particular attention to the physical properties of the ionosphere for the extremely low frequency (ELF) range. Two consistent features have long been recognized for the range: the presence of two distinct altitude layers of maximum energy dissipation within the lower ionosphere, and a “knee”-like change in the vertical conductivity profile representing a transition in dominance from ion-dominated to electron-dominated conductivity. A simplified two-exponential version of the Greifinger and Greifinger (1978) technique widely used in ELF work identifies two slopes in the conductivity profile and, providing accurate results in the ELF communication band (45–75 Hz), simulates too flat a frequency dependence of the quality factor within the Schumann resonance frequency range (5–40 Hz). The problem is traced to the upward migration, with frequency increasing, of the lower dissipation layer through the “knee” region resulting in a pronounced decrease of the effective scale height for conductivity. To overcome this shortcoming of the two-exponential approximation and still retain valuable model analyticity, a more general approach (but still based on the Greifinger and Greifinger formalism) is presented in the form of a “knee” model whose predictions for the modal frequencies, the wave phase velocities and the quality factors reasonably represent observations in the Schumann resonance frequency range.     

Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

Modeling Lake Ladoga Zoobenthos and Studying Its Role in Phosphorus Exchange at the Water–Bed Interface

A zoobenthos submodel is included in an ecosystem model. The new model is used to assess the role of zoobenthos in the phosphorus exchange at the water–bed interface, in particular, the phosphorus cycle in the water body ecosystem is described more accurately. The calculated zoobenthos distribution over the bed of a lake can be used in modeling the lake ichthyocenoses.     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.