Characterization of serpentinization in olivine-orthopyroxene-H2O system revealed by thermogravimetric and multivariate statistical analyses

Thermogravimetric (TG) analyses were used to characterize the products and quantify the extent of serpentinization as a stepwise weight loss during heating (TG loss) or its derivative (DTG). Multivariate analyses are powerful tools for extracting information from complicated spectrum data; however, no studies have applied them to characterize serpentinites. In this study, hydrothermal experiments of olivine-H₂O, olivine–orthopyroxene-H₂O and orthopyroxene-H₂O were conducted at 250–400°C and under vapor-saturated pressure. The product minerals observed were serpentine+brucite+magnetite in the olivine-H₂O experiments and serpentine±talc in the orthoyroxene-H₂O and olivine-orthopyroxene-H₂O experiments. These results are consistent with those of previous studies; however, the positions and width of DTG peaks for individual minerals were varied depending on the experimental conditions. To extract systematics from the TG spectra, non-negative matrix factorization (NMF), an unsupervised machine learning technique, was applied to the DTG spectra of the experimental products. NMF revealed that the DTG profiles were explained by a linear combination of six basis spectra, which corresponded to the characteristic products, including three types of serpentine minerals (low-, medium-, and high-T), two types of brucite (low-and high-T), two type of talc (talc+serpentine mixture, well-crystallized talc) with different crystallinity, and noise during the TG measurement. Systematic changes in the factor loading revealed that, in the olivine-H₂O systems, the products changed from medium-T serpentine+low-T brucite to high-T serpentine+high-T brucite as serpentinization progressed. In the olivine-orthopyroxene system, low-T serpentine or poorly crystallized talc+serpentine mixture was initially formed, followed by the formation of well-crystallized talc, resulting in dehydration. Applying NMF to DTG showed the mineralogical differences between olivine and orthopyroxene systems and increases of the crystallinity during the progress of serpentinization, suggesting its potential for characterizing various serpentinites within oceanic lithospheres that suffer from several stages of alteration and weathering at different temperatures.     

Habitat selection by marine larvae in changing chemical environments

The replenishment and persistence of marine species is contingent on dispersing larvae locating suitable habitat and surviving to a reproductive stage. Pelagic larvae rely on environmental cues to make behavioural decisions with chemical information being important for habitat selection at settlement. We explored the sensory world of crustaceans and fishes focusing on the impact anthropogenic alterations (ocean acidification, red soil, pesticide) have on conspecific chemical signals used by larvae for habitat selection. Crustacean (Stenopus hispidus) and fish (Chromis viridis) larvae recognized their conspecifics via chemical signals under control conditions. In the presence of acidified water, red soil or pesticide, the ability of larvae to chemically recognize conspecific cues was altered. Our study highlights that recruitment potential on coral reefs may decrease due to anthropogenic stressors. If so, populations of fishes and crustaceans will continue their rapid decline; larval recruitment will not replace and sustain the adult populations on degraded reefs.     

Development of a flood water level estimation method using satellite images and a digital elevation model for the Mekong floodplain

We have developed a flood water level estimation method that only employs satellite images and a DEM. The method involves three steps: (1) discriminating flood areas and identifying clumps of each flood area, (2) extracting the edges of the identified flood area using a buffering technique, and (3) performing spatial interpolation to transform the extracted elevation to flood water levels. We compared the estimated flood water levels with the observed ones. The RMSE using the RADARSAT was 1.99 and 1.30 m at river and floodplain points, respectively, whereas the RMSE using the MODIS was 4.33 and 1.33 m at the river and floodplain points, respectively. Given that most errors are attributed to the DEM, the method exhibited good performance. Furthermore, the method reproduced the flow directions and flood water level changes during the flooding period. Thus, we demonstrated that the characteristics of flood inundation can be understood even when ground observation data cannot be obtained.     

Chitinozoans and scolecodonts from the Silurian and Devonian of Japan

Silurian and Devonian chitinozoans and scolecodonts are recorded from strata of the Hida‐Gaien Terrane, central Honshu. Silurian chitinozoans include Eisenackitina, Bursachitina, and the species Angochitina elongata. The latter provides a precise biostratigraphical tie between the Japanese succession and the Type Ludlow Series of the Welsh Borderland, UK, and indicates a Ludlow age (Gorstian or early Ludfordian) for the upper member of the Yoshiki Formation in the Ichinotani Valley. Chitinozoans from other Yoshiki Formation localities contain other specimens of Lagenochitinidae. Scolecodonts are more common than chitinozoans in the palynological residues, but are mostly represented by fragments or minor apparatus elements with a low biostratigraphical value. However, material from the Yoshiki and Fukuji Formations includes several species of Mochtyella as well as representatives of Oenonites, Kettnerites, Lunoprionella, Vistulella? and possibly other placognath taxa. Scolecodonts are also present in the Silurian Middle Member of the Gionyama Formation, Kyushu, including a well‐preserved jaw of Pistoprion, and fragments of putative Kettnerites and Oenonites. These finds of scolecodonts suggest close similarity in assemblages between Paleozoic polychaete faunas of Japanese terranes and those of Baltica‐Laurentia.     

Shuffled-cards structure and different P/T conditions in the Sanbagawa metamorphic belt, Sakuma-Tenryu area, central Japan

The Sanbagawa metamorphic terrain of the study area is divided into two units, the Shirakura and Sejiri units. The metamorphic thermal structure is interpreted on the basis of the degree of graphitization (GD) of carbonaceous material in pelitic schists. The areal variations of the metamorphic grade are presented by the distribution of GD calculated using the Lc and d₀₀₂ of carbonaceous material. As a result, the two units are classified into four metamorphic zones, respectively: A₁, A₂, B₁ and B₂ for the Shirakura Unit; and I₁, I₂, II₁ and II₂ for the Sejiri Unit. The metamorphic grades of A₁, A₂, I₁ and I₂ are included in the chlorite zone, and that of B₁, B₂, II₁ and II₂ in the garnet zone of the Sanbagawa metamorphism. The degree of graphitization at the boundary between A₂ and B₁ zones is the same as that between I₂ and II₁ zones. Detailed study on the variation of GD suggests that the present‐day structure of the study area is best interpreted as a model of shuffled‐cards structure. An estimated minimum thickness of a stack of continuous cards is about 25 m. The compositions of garnet in pelitic schists and of amphibole in basic schists are different from those in the identical metamorphic range of the Shirakura and Sejiri units. It is suggested that rocks of the Shirakura Unit were metamorphosed under higher P/T conditions than those of the Sejiri Unit.     

Spreading of river water in Suruga Bay

We have investigated the spreading of river water in Suruga Bay by performing numerical experiments and conducting field surveys with drifting buoys. There are clear seasonal variations in the large river discharges into the bay: increased discharge in the rainy summer season and decreased discharge in the dry winter season. The numerical model reproduces the main feature that has been observed in the actual sea: the river water extends gradually from the northwestern to the southeastern regions in the bay, especially in summer. The river water spreading is greatly influenced by the bottom topography of the bay: the Fuji River water spreads over a deep continental slope as a surface-advected plume and extends well offshore, since a large bulge (anticyclonic eddy at the river mouth) extends well offshore and effectively transports the river water offshore. On the other hand, the Oi River water tends to flow parallel to isobaths (along a coastline) on a shallow continental shelf as a bottomadvected plume. Moreover, the influences of seasonal variations in the stratification and a bay-scale, wind-driven circulation are also investigated. Trajectories of the drifting buoys, which were released around the Fuji River mouth, certainly suggest that the bulge exists there.     

Numerical experiments on wind-driven circulations and associated transport processes in Suruga Bay

The dynamics of the wind-driven circulations and surface transport processes in Suruga Bay have been examined by performing numerical experiments. While strong winds exist outside the bay, the winds inside the bays are greatly reduced, which generates a strong wind stress curl in winter and autumn. In particular, in winter, a strong positive curl region is located across the bay mouth, and a strong surface circulation with counterclockwise rotation is generated beneath it. The circulation is nearly geostrophic, but is not affected by the bottom topography in the deep bay. It is suggested that intense surface water exchange through the bay mouth occurs in winter, whereas it is not active in the other seasons when no significant vorticity is supplied on the bay mouth from the atmosphere. Moreover, we propose a hypothesis that the atmospheric wind stress curl will cause the frequent appearance of the counterclockwise circulation in winter in the real ocean.     

A new ornithomimid dinosaur with North American affinities from the Late Cretaceous Qiupa Formation in Henan Province of China

A partial skeleton of the ornithomimid dinosaur, discovered from the Late Cretaceous Qiupa Formation of Luanchuan County, Tantou Basin, Henan Province, China, is described here and assigned to a new genus and species, Qiupalong henanensis, with unique features (a notch on the lateral surface of the lateral posterior process of the proximal end of tibia and a small pit at the contact between astragalus and calcaneum). A phylogenetic analysis in this study suggests that it is a derived ornithomimid and form a monophyly with North American ornithomimids (Struthiomimus altus and Ornithomimus edmontonicus), sharing two characters (straight pubic shaft and large acute angle between pubic shaft and boot). Some characters (small anterior process of the pubic boot and curved pedal unguals) are seen in basal ornithomimosaurs as well, but these features in Q. henanensis are reversal. Qiupalong is the first definitive ornithomimid from outside of the Gobi Desert and is the southern-most occurrence of Late Cretaceous ornithomimid from eastern Asia, demonstrating southern extension of ornithomimid distribution in Asia.     

Simulation analysis of ground liquefaction induced by earthquake

A dynamic effective stress analysis with the finite element method has long been recommended to predict the liquefaction phenomena of sandy soil by authors and Zienkiewicz et al. as well as the similar approaches by the others. Our approach of the analysis is summarized in the first.

Until recently, however, these approaches has not commonly been used as the means of design, although its capability of prediction is appreciated by geotechnicians. This method has been neglected because of the lack of verification studies of soil models of sand and mathematical formulation for boundary problems of liquefaction phenomena. Therefore the verification of the numerical method to evaluate liquefaction potential are urgent requirement of the recent engineering practice. To respond this requirement, extensive numerical studies on the liquefation simulations are performed by DIANA program for shaking table tests which have been conducted by the authors. The test models are soil-structure type models with combination of homogenous ground and partially improved ground by compaction.

The good performance of our approach is proved by the results of numerical simulation showing good agreement with experimental data in terms of response acceleration, excess pore pressure, and deformation profile. It is also demonstrated that the numerical results can provide substantial information to understand the mechanisms of soil ground behavior which is not easily obtained by experiments.

The procedure to identify soil constants for the reflecting surface model is also reported in details.     

Evaluating Global Warming Potentials with historical temperature

Global Warming Potentials (GWPs) are evaluated with historical temperature by applying them to convert historical CH₄ and N₂O emissions to equivalent CO₂ emissions. Our GWP analysis is based on an inverse estimation using the Aggregated Carbon Cycle, Atmospheric Chemistry, and Climate Model (ACC2). We find that, for both CH₄ and N₂O, indices higher than the Kyoto GWPs (100-year time horizon) would reproduce better the historical temperature. The CH₄ GWP provides a best fit to the historical temperature when it is calculated with a time horizon of 44 years. However, the N₂O GWP does not approximate well the historical temperature with any time horizon. We introduce a new exchange metric, TEMperature Proxy index (TEMP), that is defined so that it provides a best fit to the temperature projection of a given period. By comparing GWPs and TEMPs, we find that the inability of the N₂O GWP to reproduce the historical temperature is caused by the GWP calculation methodology in IPCC using simplifying assumptions for the background system dynamics and uncertain parameter estimations. Furthermore, our TEMP calculations demonstrate that indices have to be progressively updated upon the acquisition of new measurements and/or the advancement of our understanding of Earth system processes.