210Pb and 7Be as Tracers for Aerosol Transfers at Center Guizhou，China：Ⅰ．The Explanation by Weekly Interval

It′s essential to measure air concentrations and depositional fluxes of environmental radionuclides in different regions for modeling global contamination transfer and validation, tracing deposition process and dating, referencing watershed erosion trace and assessing natural radiation of ecosystem. This study introduces the research background and methods and explains weekly variations of ²¹⁰Pb and ⁷Be concentrations in surface air and precipitation at Mt. Guanfeng/Guiyang since 2001. The results indicate that ²¹⁰Pb and ⁷Be concentrations in surface air fluctuate periodically at 2~6 week interval because of the meteorological condition changes. The annual trend in ²¹⁰Pb air concentration is overall influenced by air temperature variation and periodical rainfall. ⁷Be air concentration varies up and down regualarly. The synchronization of low concentrations for both ²¹⁰Pb and ⁷Be in surface air and high ratio (²¹⁰Pb/⁷Be ≥ 0.8) indicate oceanic poor ²¹⁰Pb-⁷Be air mass invasion. The synchronization of high concentrations of ²¹⁰Pb and ⁷Be in surface air and low ratio (²¹⁰Pb/⁷Be ≤ 0.7) implies rich ⁷Be air mass invasion from altostratus atmosphere. Weekly concentrations of ²¹⁰Pb and ⁷Be in precipitation and the K_d coefficients are high in late Autumn to Spring, and low in late Spring to Autumn. Although ²¹⁰Pb and ⁷Be concentrations vary seasonally, their weekly concentrations in precipitation increase with that of air concentration. The ²¹⁰Pb and ⁷Be weekly concentrations for seasonal division is about 0.2 Bq/L and 1 Bq/L, respectively. However, the K_d coefficient decreases when ²¹⁰Pb and ⁷Be air concentrations increase. Deposition of ²¹⁰Pb and ⁷Be with precipitation mainly take place in Spring and Summer; The weekly fallout of ²¹⁰Pb and ⁷Be increases with increasing precipitation; the increase of ⁷Be is triple of that of ²¹⁰Pb and 2.5 when precipitation nears to zero. The weekly-high fallout of ²¹⁰Pb and ⁷Be with precipitation corresponds with the dramatic decrease of their air concentrations within or vicinal weeks. The ratio of ²¹⁰Pb to ⁷Be in rainfall is overall ≤ 0.5 and varies synchronously with the ratio in surface air, indicating that the two radionuclides are cleaned by precipitation from air at close speed. In the extreme freezing disaster in 2008, both ²¹⁰Pb and ⁷Be air concentrations were low and coupling with coexist of low concentration of aerosol and high nuclides activities. Weekly concentration of ⁷Be in surface air at Mt. Guanfeng demonstrates the anticipated concentration level in the low-latitude and high-elevation region; the short-term fluctuations of ⁷Be concentration indicated the hysteresis was influcenced by the strong air current submersion and the low-elevation air mass rising differently at Mt. Guanfeng and Mt. Waliguan.      

Evaluation of remedial alternatives for a petroleum contaminated unconfined aquifer with fluctuating groundwater level

This study evaluated remedial alternatives for a petroleum-contaminated site where an unconfined aquifer composed of a sandy layer of about 3–3.5 m thickness is covered by alluvial deposits and reclaimed soil of about 1.5 m thickness. Precambrian gneiss, of low permeability, lies below the sandy layer. The shallow water table is about 3 m below the surface, but shows high fluctuations of up to 1.5 m in response to precipitation events. The unsaturated soil near the water table and the groundwater are highly contaminated with petroleum hydrocarbons, especially toluene, which have apparently leaked from storage tanks. Selection of the remedial alternatives required consideration of the relevant laws on soil and groundwater conservation in Korea, the results of risk analysis and the hydrogeological conditions. The contaminated area has been divided into zones in which different remediation goals are set based on risk analysis and the degree of natural attenuation. It is estimated that the clean-up goal can be achieved in two years by the combined use of a trench drain and well point pumping to collect the contaminated groundwater for treatment, and a dual air injection system for the contaminated soil.     

Estimation of soil erosion rates in a subtropical mountain watershed using 137Cs radionuclide

The formulation of watershed management strategies to protect water resources threatened by soil erosion and sedimentation requires a thorough understanding of sediment sources and factors that drive soil movement in the watershed. This paper describes a study of medium-term water-driven soil erosion rates in a mountainous watershed of the Shihmen Reservoir in Taiwan. A total of 60 sampling sites were selected along a hillslope. At each sampling site, the inventory ¹³⁷Cs activity was determined and then calculated with the diffusion and migration model to derive soil erosion rates. The rates are one to two orders of magnitude lower than estimates using the Universal Soil Loss Equation, a soil erosion model often used in Taiwan. Results of multiple regression analysis indicate that the spatial variability of soil erosion rates is associated with the relative position of a sampling site to the nearest ridge and soil bulk densities (r ² = 0.33, p < 0.01). Finally, the patterns of soil redistribution rates on the hillslope follow the ¹³⁷Cs hillslope model as soil erosion increases in the downslope direction. No deposition site is found at footslope because soil deposition is swept away by regular flooding along the stream channel. This study is an important first step in using ¹³⁷Cs as a tracer of soil redistribution in mountainous watersheds of Taiwan.     

SHRIMP U–Pb ages of detrital zircons from the Early Cretaceous Nakdong Formation,South East Korea: Timing of initiation of the Gyeongsang Basin and its provenance

To constrain the depositional age of the lowermost Nakdong Formation in the Early Cretaceous Gyeongsang Basin, SHRIMP U–Pb age determination was carried out on zircon separates. The U–Pb compositions of detrital zircons from the Nakdong Formation yield a wide range of ages from the Archean to the Cretaceous but show a marked contrast in age distribution according to the geographical locations within the basin. The provenance of the southern Nakdong Formation is dominantly the surrounding Yeongnam Massif, which is composed of Paleoproterozoic metamorphic rocks and Triassic to Jurassic plutonic rocks, whereas the central to northern Nakdong Formation records significant sediment derivation from the Okcheon Metamorphic Belt, which is distributed to the northwest, in addition to the contribution from the Yeongnam Massif. It is suggested that the maximum depositional age of the Nakdong Formation is ca 127 Ma, based on its youngest detrital zircon age population. The onset of its deposition at 127 Ma coincided with the tectonic inversion in East Asia from a compressional to an extensional geodynamic setting, probably due to the contemporaneous change in the drift direction of the Izanagi Plate and its subsequent oblique subduction.     

Sulfate Reduction and Sulfur Cycles at Two Seagrass Beds Inhabited by Cold Affinity <Emphasis Type="Italic">Zostera marina</Emphasis> and Warm Affinity <Emphasis Type="Italic">Halophila nipponica</Emphasis> in Temperate Coastal Waters

To evaluate the impact of invading seagrass on biogeochemical processes associated with sulfur cycles, we investigated the geochemical properties and sulfate reduction rates (SRRs) in sediments inhabited by invasive warm affinity Halophila nipponica and indigenous cold affinity Zostera marina. A more positive relationship between SRR and below-ground biomass (BGB) was observed at the H. nipponica bed (SRR = 0.6809 × BGB ? 4.3162, r ² = 0.9878, p = 0.0006) than at the Z. marina bed (SRR = 0.3470 × BGB ? 4.0341, r ² = 0.7082, p = 0.0357). These results suggested that SR was more stimulated by the dissolved organic carbon (DOC) exuded from the roots of H. nipponica than by the DOC released from the roots of Z. marina. Despite the enhanced SR in spring-summer, the relatively lower proportion (average, 20%) of acid-volatile sulfur (AVS) in total reduced sulfur and the strong correlation between total oxalate-extractable Fe (Fe_(oxal)) and chromium-reducible sulfur (CRS = 0.2321 × total Fe_(oxal) + 1.8180, r ² = 0.3344, p = 0.0076) in the sediments suggested the rapid re-oxidation of sulfide and precipitation of sulfide with Fe. The turnover rate of the AVS at the H. nipponica bed (0.13 day^?1) was 2.5 times lower than that at the Z. marina bed (0.33 day^?1). Together with lower AVS turnover, the stronger correlation of SRR to BGB in the H. nipponica bed suggests that the extension of H. nipponica resulting from the warming of seawater might provoke more sulfide accumulation in coastal sediments.     

40Ar/39Ar dating of the Jiali and Gaoligong shear zones: Implications for crustal deformation around the Eastern Himalayan Syntaxis

We conducted a comprehensive ⁴⁰Ar/³⁹Ar geochronological study of the Jiali and Gaoligong shear zones to obtain a better understanding of crustal deformation and tectonic evolution around the Eastern Himalayan Syntaxis (EHS). The new age data reveal that the main phase of deformation in the Jiali and Gaoligong shear zones occurred from 22 to 11 Ma and from 18 to 13 Ma, respectively. Structural data collected during this study indicate that the Jiali shear zone underwent a change in shear sense from sinistral to dextral during its movement history. Based on a comparison with the deformation histories of other major shear zones in the region, we argue that the initial sinistral motion recorded by the Jiali shear zone was coincident with that of the Ailao Shan–Red River shear zone, which marked the northern boundary of the southeastward extrusion of the Indochina block during the Early Miocene. From the Middle Miocene (～18 Ma), the Jiali shear zone changed to dextral displacement, becoming linked with the dextral Gaoligong shear zone that developed as a consequence of continued northward indentation of the Indian continent into Asia. Since this time, the Jiali and Gaoligong shear zones have been united, defining the southwestern boundary of the EHS during clockwise rotation of the eastward-extruding Tibetan block, as revealed by recent GPS data. The temporal change in regional deformation pattern from southeastward block extrusion to clockwise rotation of crustal fragments may have played an important role in the development of the eastern Himalayan drainage system around the EHS.     

Occurrence, physiological responses and toxicity of nickel in plants

The focus of the review is on the specific aspects of nickel’s effects on growth, morphology, photosynthesis, mineral nutrition and enzyme activity of plants. The mobility of nickel in the environment and the consequent contamination in soil and water is of great concern. Also, the detrimental effects of excessive nickel on plant growth have been well known for many years. Toxic effects of nickel on plants include alterations in the germination process as well as in the growth of roots, stems and leaves. Total dry matter production and yield was significantly affected by nickel and also causes deleterious effects on plant physiological processes, such as photosynthesis, water relations and mineral nutrition. Nickel strongly influences metabolic reactions in plants and has the ability to generate reactive oxygen species which may cause oxidative stress. More recent evidence indicates that nickel is required in small amounts for normal plant growth and development. Hence, with the increasing level of nickel pollution in the environment, it is essential to understand the functional roles and toxic effects of nickel in plants.     

Analysis of an anti-dip landslide triggered by the 2008 Wenchuan earthquake in China

The Guantan landslide, with a total displaced mass of about 468 × 10⁴ m³, was triggered by the 2008 Wenchuan earthquake and succeeding rainfall in Jushui Town, Sichuan Province, China. The landslide occurred on an anti-dip hard rock slope with a weak rock founding stratum of 200 m in thickness. To investigate the failure mechanism of the Guantan landslide, dynamic behaviors of hard and soft rock slopes were investigated by means of large scale shaking table tests. The laboratory models attempted to simulate the field geological conditions of the Guantan landslide. Sinusoidal waves and actual seismic waves measured from the Wenchuan Earthquake were applied on the slope models under 37 loading configurations. The experimental results indicated that deformation mainly developed at a shallow depth in the upper part of the hard rock slope and in the upper (near the crest) and lower (near the toe) parts of the soft rock slope. An equation for predicting the depth of sliding plane was proposed based on the location of the maximum horizontal acceleration. Finally, it was concluded that the failure process of the Guantan landslide occurred in three stages: (1) toppling failure caused by compression of the underlying soft rock strata, (2) formation of crushed hard rock and sliding surface in soft rock as the result of seismic shocks, particularly in the horizontal direction, and (3) aftershock rainfall accelerates the process of mass movement along the sliding plane.     

A Study on Crack Damage Stress Thresholds of Different Rock Types Based on Uniaxial Compression Tests

When rock samples are loaded until macroscopic fractures develop, the failure process can be divided into several stages based on axial and lateral strain responses or the acoustic emission sequence during uniaxial compression tests. Several stress thresholds may be identified: the crack closure stress σ _cc, crack initiation stress σ _ci, crack damage stress σ _cd, and uniaxial compressive strength σ _ucs; these may be used as a warning indicator for rock rupture. We investigated the crack damage stress σ _cd, its threshold, and a possible relationship between σ _cd and the uniaxial compressive strength. The σ _cd of different rock types were compiled from previous studies based on uniaxial compression tests. The results showed that the overall averages and standard deviations of σ _cd /σ _ucs for igneous, metamorphic, and sedimentary rocks were ~0.78 (±0.11), ~0.85 (±0.11), and ~0.73 (±0.18), respectively. There were no significant differences in σ _cd /σ _ucs between the different rock types, except that the sedimentary rock had a slightly larger standard deviation attributed to the variation of porosity in the samples, while the metamorphic rock had higher average σ _cd /σ _ucs resulting from the small statistical sample size. By excluding the higher-porosity (>10 %) rock samples, the averages and standard deviations of σ _cd /σ _ucs for igneous, metamorphic, and sedimentary rocks were ~0.78 (±0.09), ~0.85 (±0.09), and ~0.78 (±0.11), respectively. The results imply that the rock origin process (i.e., igneous, metamorphic, and sedimentary) has a minimal effect on σ _cd /σ _ucs. The ratio σ _cd/σ _ucs could be an essential intrinsic property for low-porosity rocks, which could be used in rock engineering for predicting the failure process.