Bismuth in the Atlantic and North Pacific: a natural analogue to plutonium and lead?

Bismuth has been analysed on samples from a vertical section from California to VERTEX IV, north of Hawaii, from a profile in the western Sargasso Sea and from an extensive suite of surface stations in the North and South Atlantic. Taken together with data from samples of Bermuda rain and from the Mississippi, Amazon and the Orinoco and its tributaries, a general outline of the processes controlling the Bi distribution in the ocean can be worked out. The dominant source in the open ocean is aeolian with the fluvial inputs being very small. Most of the aeolian input is probably derived from volcanoes; an anthropogenic flux may be important in the northwest Atlantic. Bismuth is scavenged in the mixed layer and regenerated at shallow depth to give a distribution in the northwest Pacific similar to that of^239,240Pu and anthropogenic Pb. Below 2 km the values are extremely low, in the range 20–50 fM, lower than the coexisting levels for²³²Th. The residence time of the element in the water column is sufficiently short that there are large concentration decreases between the Deep Waters of the Atlantic and Pacific. In the latter ocean, the element appears to reflect essentially one-dimensional processes.     

Seasonal and spatial distribution of nonylphenol and IBP in Saemangeum Bay, Korea

In order to investigate spatial and temporal distribution of organic pollutants in the Saemangeum Bay, organophosphorus pesticides (10), alkylphenols (8), chlorophenols (2), bisphenol A were analyzed from the surface seawater taken in 2002–2003. Most of the analytes were not detected in all stations except nonylphenol and S-benzyl-O,O-di-isopropyl phosphorothioate (IBP). Concentrations of nonylphenol and IBP ranged from ND to 298 ng/l and from ND to 1840 ng/l, respectively. The high levels of nonylphenol and IBP were found in the estuary areas of Mangyeong and Dongjin River. The levels of nonylphenol and IBP in surface seawater varied through seasons and the high levels of nonylphenol and IBP were in summer season (August). Based on real time monitoring of IBP and on correlation between concentrations of target compounds and contents of salinity in seawater, physical mixing and diffusion of seawater were found to be the major factors that affect the spatial distribution of IBP and nonylphenol in the Saemangeum Bay environment.     

Grain-size reduction of feldspars by fracturing and neocrystallization in a low-grade granitic mylonite and its rheological effect

Feldspar grain-size reduction occurred due to the fracturing of plagioclase and K-feldspar, myrmekite formation and neocrystallization of albitic plagioclase along shear fractures of K-feldspar porphyroclasts in the leucocratic granitic rocks from the Yecheon shear zone of South Korea that was deformed under a middle greenschist-facies condition. The neocrystallization of albitic plagioclase was induced by strain energy adjacent to the shear fractures and by chemical free energy due to the compositional disequilibrium between infiltrating Na-rich fluid and host K-feldspar. With increasing deformation from protomylonite to mylonite, alternating layers of feldspar, quartz and muscovite developed. The fine-grained feldspar-rich layers were deformed dominantly by granular flow, while quartz ribbons were deformed by dislocation creep. With layer development and a more distributed strain in the mylonite, lower stresses in the quartz-rich layers resulted in a larger size of dynamically recrystallized quartz grains than that of the protomylonite.     

Distribution and Acoustic Characteristics of Shallow Gas in the Korea Strait Shelf Mud off SE Korea

Shallow gas in the Korea Strait shelf mud (KSSM) off SE Korea, revealed by high-resolution subbottom profiles, is associated with acoustic blanking, acoustic turbidity, seepages with plumes in the water column, and seafloor depressions. The acoustic blanking, characterized by strong, consistent top reflection and wipeout below, is most dominant. The seaward edge of the acoustic blanking zone generally coincides with the 100-m water-depth contour, suggesting that the water depth (the pressure) may control the distribution of shallow gas. The acoustic turbidity, characterized by diffuse top reflection, is a dark smear, partially blanking the data below. The seepages with plumes, characterized by vertical smearing and disturbed seafloor, are seen only along the shallowest, landward edge of the acoustic blanking zone. This may suggest that the decreased gas solubility at shallow water depths, caused by the lowered pressure, increases the volume of free gas in the sediments, facilitating the gas escape. The seafloor depressions, interpreted as pockmarks, are accompanied by cone-shaped acoustic masking, which is probably the reflection from a narrow vent of gas. The gas-related acoustic anomalies appear to occur mostly in the upper, recent mud of the KSSM. Neither permeable beds nor faults, which can act as vertical migration pathways for deep thermogenic gas, are evident in the recent mud. We interpret that the bacterial degradation of organic matter in situ is the main source for the gas in the KSSM. The upwelling off SE Korea may be an important source for the increased organic matter in the area.     

Transgressive Shelf Sands around the Korean Peninsula: A Brief Review

Ocean Science Journal - Sands are distributed in a sheet form across the entire shelf of the Yellow and South seas. They are barely several meters thick except for sand waves and ridges, which are...     

Effect of magnetic field on a shock-induced thermal instability

The effect of a magnetic field on a thermal instability has been studied in a radiatively cooling region behind an interstellar shock of moderate propagation velocity ( 10 km s^–1). It is shown that the presence of a magnetic field of a few microgauss is very effective in preventing the thermal instability from building-up density concentrations. In the absence of the magnetic field, the shock-induced thermal instability will amplify a pre-shock density inhomogeneity by more than an order of magnitude. However, in the field's presence, the amplified density contrast is shown to be only a factor 2. Implications for the trace of a sweeping broom in the Pleiades nebula are discussed.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

First report of the small bird track Koreanaornis from the Cretaceous of North America: implications for avian ichnotaxonomy and paleoecology

Although body fossils of shorebirds and shorebird-like species are extremely rare from the Cretaceous, rapid increase in the discovery of bird footprint sites provides valuable alternate evidence to help fill gaps in the story of the early evolution of shorebird-like species. Newly discovered bird tracks from the Albian-Cenomanian Dakota Formation in northeastern Utah represent the first report of the ichnogenus Koreanaornis from North America and only the second report of bird tracks from this formation. These tracks are not attributable to Aquatilavipes as previously claimed. Three well-preserved trackways are described and provisionally referred to Koreanaornis cf. hamanensis (Kim). However, a review of the ichnotaxonomy of shorebird ichnites reveals that this ichnotaxon also closely resembles the Miocene ichnospecies Avipeda sirin (Vyalov). This latter comparison points to the need for a thorough evaluation of the similarity between Mesozoic and Cenozoic avian ichnotaxa, which may be over-split in some cases and under-differentiated in others.The new material helps distinguish ichnogenus Koreanaornis from the larger bird track Aquatilavipes, which is more abundant and widespread in North America. In some cases Aquatilavipes has been incorrectly used as a catch-all ichnogenus both in North America and Asia. The Dakota Formation stratigraphy at the tracksite indicates that the track makers lived in a marginal marine paleoenvironment. However, despite the widespread distribution of such facies, often replete with dinosaur tracks, the bird track record of the Dakota Formation, and the Cretaceous of the western USA remains relatively sparse in comparison with other areas such as east Asia.     

Evaluating the transport and removal of chromate using pyrite and biotite columns

To remove chromate from a wastewater, a porous permeable reactive barrier system (PRBS), using pyrite and biotite, was adapted. This study included bench‐scale column experiments to evaluate the efficiency of the PRBS and investigate the reaction process. The total chromium concentration of the effluent from the biotite and pyrite columns reached the influent concentration of 0·10 mM after passing through more than 150 pore volumes (PVs) and 27 PVs respectively, and remained constant thereafter. The Cr^VI concentration in the effluent from the biotite column became constant at about 0·08 mM , accounting for approximately 80% of the influent concentration, after passing through 200 PVs. Moreover, in the pyrite column, the Cr^VI concentration remained at about 0·01 mM , 10% of the input level, after passing through 116 PVs. This shows that both columns maintained their levels of chromate reduction once the Cr^VI breakthrough curves (BTCs) had reached the steady state, though the steady‐state output concentration of total chromium had reached the influent level. The variances of the iron concentration closely followed those of the chromium. The observed data for both columns were fitted to the predicted BTCs calculated by CXTFIT, a program for estimating the solute transport parameters from experimental data. The degradation coefficient µ of the total chromium BTCs for both columns was zero, suggesting the mechanisms for the removal of chromate limit the µ of the Cr^VI BTCs. The Cr^VI degradation of the pyrite column (6·60) was much greater than that of the biotite column (0·27). In addition, the Cr^VI retardation coefficient R of the pyrite column (253) was also larger than that of the biotite column (125). The R values for the total chromium BTCs from both columns were smaller than those of the Cr^VI BTC. Whereas the total chromium BTC for the pyrite column showed little retardation (1·5), the biotite column showed considerable retardation (80). The results for the 900 °C heat‐treated biotite column were analogous to those of the control column (quartz sand). This suggests that the heat‐treated biotite played no role in the retardation and removal of hexavalent chromium. The parameters of the heat‐treated biotite were calculated to an R of 1·2 and µ of 0·01, and these values confirmed quantitatively that the heated biotite had little effect on the transport of Cr^VI. These solute transport parameters, calculated by CXTFIT from the data obtained from the column tests, can provide quantitative information for the evaluation of bench‐ or field‐scale columns as a removal technology for Cr^VI in wastewater or contaminated groundwater. Copyright © 2006 John Wiley & Sons, Ltd.     

Bibliography on spatiotemporal databases

Abstract

There now exist several microcomputer processing systems which incorporate algorithms and display techniques appropriate for the class of objects known as images. Zooming, histogram equalization, contrast stretching, ratioing, edge enhancement, and filtering are common options used in these systems. In the present discussion a system is proposed for the equivalent processing of general resolution elements (resells), instead of the homogeneous picture elements (pixels) which are found in image processing systems. The resel processing system requires a new, generalized, repertoire of processing algorithms and a high resolution display. A summary is provided of the facilities and procedures required, a computational metaphor using computer spreadsheets is described, and the applicability to censels (census data elements) and to medical data is suggested.     

Thermal history of the Cretaceous Sindong Group, Gyeongsang Basin, Korea based on fission track analysis

ABSTRACT Apatite and zircon fission track (FT) analyses were carried out to reconstruct the thermal history of the Lower Cretaceous Sindong Group, which is the lowermost stratal unit of the Gyeongsang Basin, Korea. Zircon FT central ages show a wide range from 83 ± 5 to 157 ± 18 Ma, and single-grain age spectra have multiple age populations, whereas all apatites have very consistent FT ages of c . 60 Ma, suggesting a totally reset cooling age. Co-existence of both older and younger ages compared with the depositional age and relatively short mean track length indicate that the Sindong zircons were partially annealed. The Sindong Group was heated into the zircon partial annealing zone (ZPAZ) around 80 Ma, and cooled below the apatite closure temperature at c . 60 Ma. Based on the zircon FT results combined with vitrinite reflectance data, the maximum palaeotemperature to which the Sindong Group had been subjected can be inferred to be about 260 °C. Zircon FT data from a granite body that is in contact with the Sindong Group and sandstones close to the granite body indicate that thermal influence caused by Upper Cretaceous intrusive rocks was limited in close vicinity of the intrusion and that the major heat source of the Sindong Group was burial. The thickness of uplifted and eroded section is estimated to be about 7 km.