Geochemical and Sr–Nd isotopic constraints on the petrogenesis of the Goesan monzodiorite pluton in the central Okcheon belt,Korea

The Permian–Triassic high pressure metamorphism and potassic magmatism in central Korea attest to the extension of the Dabie‐Sulu collision belt in central‐eastern China towards the Korean Peninsula and possibly the Japanese Islands. We present major and trace element and Sr–Nd isotope data for a ca. 230 Ma monzodiorite pluton emplaced in the Goesan area, central Okcheon belt, Korea. This pluton shows geochemical features comparable with those of the coeval monzonite–syenite–gabbro–mangerite suite documented recently in the Gyeonggi massif. The metaluminous and alkali–calcic signatures of the Goesan intrusives correspond to the Caledonian‐type post‐orogenic granitoids. The K₂O/Na₂O ratios of all analyzed samples are greater than 1, and are not correlative with their SiO₂ contents. The enrichment of both large‐ion‐lithophile elements and highly compatible elements in the Goesan pluton is probably indicative of metasomatized mantle origin. The elemental fractionation in the source region must have occurred in the distant past, possibly the Paleoproterozoic, to generate significantly negative ε_Nd(t) values (< –16). Chondrite‐normalized rare earth element patterns as well as Rb/Sr and Ba/Rb ranges suggest that the source consists of amphibole‐bearing rocks. Progressive decreases in negative Eu anomaly and Ba, Sr, Ni, Cr and V contents with increasing SiO₂ contents reflect an important role of plagioclase, biotite and hornblende for the fractionation process. Zr is undersaturated in the potassic, metaluminous melt. The initial Sr–Nd isotopic compositions of the samples are correlated with their SiO₂ contents, substantiating a role of crustal assimilation during the magmatic differentiation. The Sr–Nd elemental and isotopic modeling suggests that the Goesan pluton was initially slightly heterogeneous in its isotopic composition, and underwent concurrent assimilation and fractional crystallization. The occurrence of the Goesan pluton provides further evidence corroborating the amalgamation of allochthonous terranes within the Okcheon belt during the Permian–Triassic collisional orogeny.     

Improved design of sliding mode control for civil structures with saturation problem

A systematic and improved design procedure for sliding mode control (SMC) of seismically excited civil structures with saturation problem is provided in this paper. In order to restrict the control force to a certain level, a procedure for determining the upper limits of the control forces for single or multiple control units is proposed based on the design response spectrum of external loads. Further, an efficient procedure using the LQR method for determining sliding surfaces appropriate for different controller types is provided through the parametric evaluation of the dynamic characteristics of sliding surfaces in terms of SMC controller performance. Finally, a systematic design procedure for SMC required to achieve a given performance level is provided and its effectiveness is verified by applying it to multi‐degree‐of‐freedom (MDOF) systems. Copyright © 2004 John Wiley & Sons, Ltd.     

The tectonic boundary between the Okcheon and Taebaeksan basins,South Korea: A restraining bend of a continental transform fault between the South and North China Cratons

The geological relationship between the Okcheon and Taebaeksan basins of the Okcheon belt on the Korean peninsula is a key issue in reconstructing the tectonic evolution of the peninsula. The boundary between the two basin sequences has been variously interpreted as a conformable, unconformable, or thrust contact, without clear evidence being provided for any of these hypotheses. Detailed examination of structures and microfabrics of deformed rocks adjacent to the contact in the Bonghwajae area suggests that the boundary between the two basin sequences is a thrust. Based on the U–Pb ages of detrital zircons from metasedimentary rocks and pre‐existing geologic data from the Okcheon belt, the thrust is a relay structure between two segments of a continental transform fault along which the Okcheon Basin was juxtaposed against the Taebaeksan Basin during the Permian–Triassic suturing of the North and South China Cratons.     

A discontinuity in the late Pleistocene alluvial deposits,Hwacheon‐ri,Gyeongju, Korea: Occurrences and paleoenvironmental implication

A sedimentary discontinuity is present in the late Pleistocene alluvial deposits exposed along the cliff in stream side, Gyeongju, Korea. Sedimentological study, Optically Stimulated Luminescence (OSL) age dating, and X‐ray diffraction (XRD), and X‐ray fluorescence spectrometer (XRF) analyses were conducted in order to interpret the origin of the discontinuity surface. Based on the sedimentological study, these deposits can be divided into three distinct stages, in ascending order: (Stage 1) development of a braided stream flowing from south to north and deposition by debris flows from the mountain aside the stream during and/or after deposition of the braided stream; (Stage 2) deposition by intermittent events during a state of stagnation after the abandonment or migration of the previously existed braided stream; and (Stage 3) deposition of gravels from debris flows from the mountain aside the stream. Hornfelsic gravels are common in Stage 1, whereas andesitic gravels are predominant in Stage 3, suggesting the provenance change from Stage 1 to Stage 3. The discontinuity surface is laterally extensive and marked by a distinct carbonaceous dark grey horizon between Stage 2 and Stage 3. It is characteristic that rootlets mineralized by vivianite are present, and iron‐oxide crusts are cutting across irregularly below the discontinuity surface. It is thus interpreted that the shift of depositional environment from an alluvial plain (Stage 2) (125 ka) to an alluvial fan (Stage 3) (94–55 ka) was an alluvial response to sea level change from the interglacial to the glacial. The development of iron‐oxide crusts and diagenetic vivianite in the discontinuity surface suggests humid condition persisted during the paleoclimatic shift from the last interglacial to the last glacial stages.     

Distribution and Variability of the Meiobenthic Assemblages near the Korean Polymetallic Nodule Claim Area of the Clarion-Clipperton Fracture Zone (Subequatorial NE Pacific)

This study was carried out as part of a baseline long-term environmental project in the proposed mining areas for an environmental impact assessment of future mining in the Clarion-Clipperton Fracture Zone (CCFZ). The community structure and distributional pattern of meiobenthos were investigated in the deep-sea bottom of the Clarion-Clipperton Fracture Zone of the northeastern Pacific in July 1998, 1999, 2001, 2003 and August 2004, 2005. Twenty one meiobenthic groups were found at the stations in the study area. The most abundant meiobenthos comprised nematodes followed by benthic foraminiferans and harpacticoid copepods. The maximum density of meiobenthos was 306 ind/10 cm² at the station located at 11°N (water depth, 4833 m), and the minimum density was 6 ind/10 cm² at the station located at 14°N (water depth, 5037 m). Oligotrophic conditions in the CCFZ seem to directly reflect the lower standing stocks of meiobenthos in the CCFZ compared to other deep-sea plains of similar depth. The latitudinal distribution pattern of meiobenthos in the study area seemed to be related with surface water primary productivity, which was connected to the water circulation pattern of the Pacific Ocean near the Equator, diverging at 8ºN latitude and converging at 5°N. The horizontal distribution of meiobenthic organisms in the study area showed high densities at the stations within 135–136°W. The densities of meiobenthic organismas within the CCFZ were high at stations with few manganese nodules on the sediment surface at low-latitude sites. In 1998, the observed relative high values of meiobenthic abundance were at stations from 5° to 6°N. Other stations from 7° to 10°N showed no significant fluctuations during the interannual sampling periods. It is considered that the inter-annual fluctuation of meiobenthos abundance is intimately related with a regime shift that may have occurred in the north Pacific between 1998 and 1999, the El Niño period. Vertical distribution of meiobenthic organisms showed the highest individual numbers in the surface sediment layers of 0～2 cm depth and a steep decreasing trend as sediment becomes deeper at the stations of high latitude located in 16～17°N. Size distribution analyses showed that organisms that fit into the sieve mesh size of 0.063 mm were abundant.     

Optimization of Chemical Oxygen Demand Determination in Seawater Samples Using the Alkaline Potassium Permanganate Method

Chemical oxygen demand (COD) is a practical parameter that is used to estimate the amount of organic pollutants in aqueous systems. It is generally used as a guideline to control the quality of waste treatment effluent globally and is a management tool to evaluate the total pollution load in the highly developed coastal regions of Korea. It is a preferred method because of the speed and simplicity of the analysis and because there are fewer instrumentation requirements. The Ministry of Oceans and Fisheries (MOF) of the Republic of Korea developed a standard procedure for the measurement of COD. It has been revised several times, and the most recent revision was made in 2013 (MOF 2013–230). In this study, we modified the standard COD measurement procedure (MOF 2013–230), especially the sample digestion apparatus, to enhance analytical efficiency for a large sample number (batch), which is called a Korea Institute of Ocean Science and Technology (KIOST) modified MOF 2013–230. We examined uncertainty related to each experimental step and optimized laboratory conditions to reduce such uncertainties. The detection limit and estimated expanded uncertainty related to the KIOST modified MOF 2013–230 was 0.18 and 0.11 mg O₂/L at a 95% confidence level (k = 2), respectively. This study also provides several tips to maintain consistent COD measurements in seawater using the alkaline potassium permanganate method.     

Subtidal Marine Algal Community and Endangered Species in Dokdo and Ulleungdo,Two Oceanic Islands in the East Sea of Korea

Ocean Science Journal - Dokdo and Ulleungdo islands harbor diverse marine algae and are therefore uniquely well-suited for research on marine algae distribution and ecological changes. However,...     

Effects of sodium cyanide (nacn) on the endogenous rhythm of the oxygen consumption rate in the black rockfishsebastes schlegeli

Laboratory bioassays were conducted to test the acute toxicity effects of sudden exposure to sodium cyanide (NaCN) on the endogenous rhythm of the oxygen consumption rate (OCR) in the black rockfishSebastes schlegeli. The OCR of the black rockfish (n = 14, total length = 20.4 ± 1.16 cm, wet weight = 158 ± 25 g) was measured with an automatic intermittentflow-respirometer. OCR decreased significantly when experimental fish were exposed to NaCN. When exposed to 10 ppb NaCN, fish were able to recover their OCR rhythmic activities. When fish were exposed to 20 ppb, however, the metabolic activity rhythms were not recovered. These results suggest that exposure to NaCN concentrations over 20 ppb cause severe physiological damage to the endogenous rhythms of black rockfish.     

A Numerical Study of Sea-Fog Formation over Cold Sea Surface Using a One-Dimensional Turbulence Model Coupled with the Weather Research and Forecasting Model

The formation mechanism of a cold sea-fog case observed over the Yellow Sea near the western coastal area of the Korean Peninsula is investigated using numerical simulation with a one-dimensional turbulence model coupled with a three-dimensional regional model. The simulation was carried out using both Eulerian and Lagrangian approaches; both approaches produced sea fog in a manner consistent with observation. For the selected cold sea-fog case, the model results suggested the following: as warm and moist air flows over a cold sea surface, the lower part of the air column is modified by the turbulent exchange of heat and moisture and the diurnal variation in radiation. The modified boundary-layer structure represents a typical stable thermally internal boundary layer. Within the stable thermally internal boundary layer, the air temperature is decreased by radiative cooling and turbulent heat exchange but the moisture loss due to the downward vapour flux in the lowest part of the air column is compensated by moisture advection and therefore the dewpoint temperature does not decrease as rapidly as does the air temperature. Eventually water vapour saturation is achieved and the cold sea fog forms in the thermal internal boundary layer.     

Holocene environmental changes on the east coast of Korea

We present a record of Holocene environmental change on the east coast of Korea, inferred using pollen, carbon-isotopic composition (??¹³C), total organic carbon, total sulfur, carbon/nitrogen ratios, particle size analysis and major element geochemistry in a sediment core from Soonpogae Lagoon. A multi-proxy paleoenvironmental approach had not previously been applied in Korea and allowed us to reconstruct climate and vegetation change, sea-level rise, lagoon development, and human impact on the east coast of Korea over the last 8,000?years. Evidence from Soonpogae Lagoon supports the following three conclusions: (1) As a drying trend prevailed on the east coast of Korea after ~5,900?cal?yr BP, chemical weathering weakened and herbaceous plants became more important than during the previous humid phase (Holocene Climate Optimum), (2) Sea-level rise on the east coast slowed dramatically about 6,800?cal?yr BP, resulting in low rates of sedimentation in Soonpogae Lagoon, and (3) Soonpogae Lagoon was almost completely isolated from the sea by sand barriers when human impact intensified ~2,100 BP.