Multi‐site calibration using a grid‐based event rainfall–runoff model: a case study of the upstream areas of the Nakdong River basin in Korea

Most runoff analyses using a grid‐based distributed model use one parameter group calibrated at the outlet of a watershed, instead of dividing the watershed into subwatersheds. Significant differences between the observed value and the simulation result of the subwatersheds can occur if just one parameter group is used in all subwatersheds that have different hydrological characteristics from each other. Therefore, to improve the simulation results of the subwatersheds within a watershed, a model calibrated at every subwatershed needs to be used to reflect the characteristics of each subwatershed. In this study, different parameter groups were set up for one or two sites using a distributed model, the GRM (Grid based Rainfall‐runoff Model), and the evaluations were based on the results of rainfall–runoff analysis, which uses a multi‐site calibration (MSC) technique to calibrate the model at the outlet of each site. The Hyangseok watershed in Naeseong River, which is a tributary of Nakdong River in Korea, was chosen as the study area. The watershed was divided into five subwatersheds each with a subwatershed outlet that was applied to the calibration sites . The MSC was applied for five cases. When a site was added for calibration in a watershed, the runoff simulation showed better results than the calibration of only one site at the most downstream area of the watershed. The MSC approach could improve the simulation results on the calibrated sites and even on the non‐calibrated sites, and the effect of MSC was improved when the calibrated site was closer to the runoff site. Copyright © 2014 John Wiley & Sons, Ltd.     

Approximated solution on the properties of the scavenging gap during precipitation using harmonic mean method

Wet deposition refers to both natural and artificial processes where particles are scavenged by atmospheric hydrometeors. Below-cloud atmospheric particles are removed by raindrops via Brownian diffusion, interception, and impaction. The overall scavenging coefficient has a broad and distinctive minimum for aerosol penetration between 0.1 and several micrometers in diameter. In this study, the approximated analytical solution for most penetrating particle size during precipitation was obtained. Brownian diffusion and interception were considered under the assumption of the inertial impaction can be neglected in this study conditions. Both the minimum collection efficiency and minimum scavenging coefficient particle size were estimated using the harmonic mean type approximation, with the solution compared to the numerically calculated results. The approximated results were comparable with the numerical solutions. The results showed that collection efficiency diameter is a function of terminal velocity and the collection mechanisms included. When considering Brownian diffusion and interception, most penetrating particle size increases as drop diameter increases, which shows a contrary to the study of Wang (1978) and this shows that most penetrating particle size depends on collection efficiency mechanism, flow velocity and collector diameter. Consequently, this study analytically approximated general type-solutions for scavenging gap particle size and minimum collection efficiency during precipitation.     

Numerical simulation of vertical ground heat exchangers: Intermittent operation in unsaturated soil conditions

The effect of varying the thermal properties of inhomogeneous unsaturated soil on the intermittent operation of a vertical ground heat exchanger (GHE) was simulated by a conjugate heat transfer simulation using a transient conductive heat transfer model. A three-phase soil model was used to introduce soil properties that vary with depth. The performance during the first few hours was significantly different from that of an analytical infinite line source model that assumes steady-state borehole conditions, although relatively good agreement was obtained thereafter. Unsaturated soil conditions afforded a 40% lower mean heat exchange rate than saturated conditions. This demonstrates the importance of considering unsaturated conditions in the design and performance evaluation of GHEs.     

Veterinary antibiotics contamination in water, sediment, and soil near a swine manure composting facility

Antibiotics have been commonly used to prevent animal diseases and promote livestock productivity. However, its release into the surrounding environments leads to ecological disturbance and risks to human health. This study was conducted to monitor the occurrence and seasonal variations of antibiotics in water, sediment, and soil close to a swine manure composting facility, Korea. Various types of antibiotics such as tetracyclines (TCs) including tetracycline, chlortetracycline, and oxytetracycline, and sulfonamides (SAs) including sulfamethazine, sulfamethoxazole, and sulfathiazole were measured by the high-performance liquid chromatography-tandem mass spectrometry via a solid-phase extraction. In the results it was identified that the variations of measured antibiotics’ concentrations in water, sediment, and soil are depending on the season. The observed concentration levels of TCs were higher in winter than in summer season, indicating that the low temperature is a parameter attributing to interruption of its degradation in water, sediment, and soil. The concentration levels of SAs were significantly higher than those of TCs and in general, all measured antibiotics’ concentrations were also in general higher in Korea when compared to those in other countries. The long-term monitoring of antibiotics’ residues in aquatic and terrestrial environments is necessary.     

Simulation of Storm Surge and Wave Due to Typhoon Isewan (5915)

An integrally coupled wave-tide-surge model was developed and then applied to the simulation of the wave-typhoon surge for the typhoon Isewan (typhoon Vera (5915)), which is the strongest typhoon that has struck Japan and caused incalculable damage. An integrally coupled tide-surge-wave model using identical and homogeneous meshes in an unstructured grid system was used to correctly resolve the physics of wave-circulation interaction in both models. All model components were validated independently. The storm surge and wave properties such as the surge height, the significant wave height, wave period and direction were reproduced reasonably under the meteorological forcing, which was reprocessed to be close to the observations. The resulting modeling system can be used extensively for the prediction of the storm surge and waves and the usual barotropic forecast.     

Infiltration pattern in a regolith–fractured bedrock profile: field observation of a dye stain pattern

We examined the infiltration pattern of water in a regolith–bedrock profile consisting of two overburdens (OB1 and OB2), a buried rice paddy soil (PS), two texturally distinctive weathered materials (WM1 and WM2) and a fractured sedimentary rock (BR), using a Brilliant Blue FCF dye tracer. A black‐coloured coating in conducting fractures in WM1, WM2 and BR was analysed by X‐ray diffraction and scanning electron microscopy. The dye tracer penetrated to greater than 2 m depth in the profile. The macropore flow and saturated interflow were the major infiltration patterns in the profile. Macropore flow and saturated interflow were observed along fractures in WM1, WM2 and BR and at the dipping interfaces of PS–WM1, PS–WM2 and PS–BR respectively. Heterogeneous matrix flow occurred in upper overburden (OB1) and PS. Compared with OB1, the coarser textured OB2 acted as a physical barrier for vertical flow of water. The PS with low bulk density and many fine roots was another major conducting route of water in the profile. Manganese oxide and iron oxide were positively identified in the black coating material and had low crystallinity and high surface area, indicating their high reactivity with conducting contaminants. Copyright © 2006 John Wiley & Sons, Ltd.     

Long-term Trends and Temporal Heterogeneity of Water Quality in Tidally Mixed Estuarine Waters

Dynamics of water quality in the Keonggi Bay, a shallow macrotidal temperate estuary of Yellow Sea, Korea were identified using the major water quality parameters such as dissolved oxygen (DO), ammonia, nitrate, phosphate, and chemical oxygen demand (COD). The study area during the last 18 years was in eutrophic and mesotrophic water in terms of the nutrient eutrophication index even with a slight decrease in DIN and COD concentrations during recent years. Monthly values of nitrate and ammonia significantly correlated with SS and salinity, respectively, indicating that re-suspension of sediment by vertical mixing and freshwater input are critical factors of monthly fluctuation in water quality. The lack of significant autocorrelation in water quality parameters suggested a significant tidal effect on temporal water quality fluctuation in the tidally mixed estuarine system. Principal component analysis (PCA) revealed a clear pattern of long-term trends of water quality. The early 1980s were the periods of best water quality, with worst conditions during the late 1980s and early 1990s. These long-term trends of water quality were well discriminated by PCA which can be further applied for the whole ecosystem interpretation with biological variables.     

Instrumentation and Numerical Analysis of Cylindrical Diaphragm Wall Movement During Deep Excavation at Coastal Area

ABSTRACT

The lateral deflection of a cylindrical diaphragm wall and the associated ground movement induced by deep excavation are analyzed by performing site instrumentations and numerical analyses in the coastal area of Korea. Wall lateral deflection, rebar stress, and pore water pressure were measured and analyzed in eight directions. Variations of soil properties with the decrease of confining pressure are compared by performing various in situ tests before ad after excavation. To calculate the wall lateral deflection accurately, the effects of small strain nonlinearity, confining pressure, and the hysteresis loading/unloading loop developed during excavation are considered in the proposed numerical analysis. By comparing numerical results with measured ones, the importances of considering small strain nonlinearity and confining pressure reduction in the nonlinear (FEM) are emphasized. Also, the effects of wall stiffness on the performance of cylindrical diaphragm walls are studied for future similar excavation in the coastal area.     

Ripples in intertidal mud—a conceptual explanation

On protected mudflats and along sheltered tidal channel margins, wave- and current-generated ripples are frequently observed on surficial and subsurface mud beds, although such bedforms are generally not thought to occur in cohesive sediments. In this paper, examples of such ripple marks in the German Wadden Sea (back-barrier tidal flats of Spiekeroog island) and also along the west coast of Korea (Baeksu tidal flats) are documented and analyzed. The mud ripples are 5–8 cm in spacing and 0.3–0.8 cm in height, and are composed of slightly sandy to virtually pure mud (80–98% mud content). For the Spiekeroog study area, a comparison of in situ particle-size measurements of suspended matter and of dispersed mud collected from the ripples shows that the former consists of low-density flocs which are considerably larger than the constituent grains of the latter. To assess local wave effects, near-bed orbital velocities and orbital diameters were calculated on the basis of standard wave theory using estimated wave parameters at the time of the study (June 2004) as well as wave data recorded nearby within the back-barrier tidal basin. The relationships between grain size, morphometric ripple parameters, and the near-bed orbital diameter show the wave-generated mud ripples to be of the orbital post-vortex type. It is demonstrated that only short-period shoaling (intermediate water depth) waves with periods of 1.5–2.5 s and heights of 0.1–0.5 m are able to generate and maintain such ripples. Corresponding near-bed orbital velocities range from 8–32 cm s^–1 and near-bed orbital diameters from 6.25–10 cm. It can be anticipated that increased current shear and turbulence associated with higher and longer waves prevent ripple formation due to the resuspension of settled mud, and the breakdown of suspended flocs and aggregates into smaller particles which then tend to remain in suspension. The most plausible explanation for the formation of the mud ripples is that mud flocs and aggregates deposited from suspension around high-water slack tide under moderate weather conditions initially respond as single (non-cohesive) particles which are hydraulically equivalent to ambient very fine sands. During exposure at low tide, gradual loss of water transforms the rippled mud into increasingly more cohesive mud drapes which are more resistant to erosion. Unless destroyed during high-energy events, the mud ripples may remain intact long enough to become buried and thereby preserved. Indeed, occasional but persistent observations of ripples in sub-Recent to ancient mudrocks document their preservation potential.     

Changes of biochemical properties and heavy metal bioavailability in soil treated with natural liming materials

This study evaluated the efficiency of naturally occurring lime-based waste materials (oyster shells, eggshells, and mussel shells) on immobilization of selected heavy metals (Cd and Pb) and a metalloid (As) in a contaminated agricultural soil. A 30-day incubation experiment was performed using soil mixture with natural liming materials or calcite (CaCO₃) at 0, 1, 3, 5, and 10 wt %. Soil biochemical properties including pH, electrical conductivity (EC), exchangeable cations, organic matter (OM), total nitrogen (TN), microbial populations, and enzyme activities were determined to ensure the changes in soil quality during incubation. The results showed that the application of natural liming materials led to an increase in soil pH similar to that of CaCO₃. Soil concentrations of Cd, Pb, and As extracted with 0.1 or 1 M HCl, and diethylene triamine pentacetic acid (DTPA) were decreased significantly after adding liming materials, accompanied by increased microbial population and enzyme activities of dehydrogenase, phosphatase, β-glucosidase, and arylsulfatase. Additionally, eggshells and mussel shells induced significant increases in OM and TN in the soil. Application of natural liming materials offers a cost-effective way to immobilize heavy metals and metalloids in soils.