Distribution of barium and fulvic acid at the mica-solution interface using in-situ X-ray reflectivity

The interfacial structures of the basal surface of muscovite mica in solutions containing (1) 5 × 10⁻³ m BaCl₂, (2) 500 ppm Elliott Soil Fulvic Acid I (ESFA I), (3) 100 ppm Elliott Soil Fulvic Acid II (ESFA II), (4) 100 ppm Pahokee Peat Fulvic Acid I (PPFA), and (5) 5 × 10⁻³ m BaCl₂ and 100 ppm ESFA II were obtained with high resolution in-situ X-ray reflectivity. The derived electron-density profile in BaCl₂ shows two sharp peaks near the mica surface at 1.98(2) and 3.02(4) Å corresponding to the heights of a mixture of Ba²⁺ ions and water molecules adsorbed in ditrigonal cavities and water molecules coordinated to the Ba²⁺ ions, respectively. This pattern indicates that most Ba²⁺ ions are adsorbed on the mica surface as inner-sphere complexes in a partially hydrated form. The amount of Ba²⁺ ions in the ditrigonal cavities compensates more than 90% of the layer charge of the mica surface. The electron-density profiles of the fulvic acids (FAs) adsorbed on the mica surface, in the absence of Ba²⁺, had overall thicknesses of 4.9-10.8 Å and consisted of one broad taller peak near the surface (likely hydrophobic and positively-charged groups) followed by a broad humped pattern (possibly containing negatively-charged functional groups). The total interfacial electron density and thickness of the FA layer increased as the solution FA concentration increased. The sorbed peat FA which has higher ash content showed a higher average electron density than the sorbed soil FA. When the muscovite reacted with a pre-mixed BaCl₂-ESFA II solution, the positions of the two peaks nearest the surface matched those in the BaCl₂ solution. However, the occupancy of the second peak decreased by about 30% implying that the hydration shell of surface-adsorbed Ba²⁺ was partially substituted by FA. The two surface peaks were followed by a broad less electron-dense layer suggesting a sorption mechanism in which Ba²⁺ acts dominantly as a bridging cation between the mica surface and FA. When the muscovite reacted first with FA and subsequently with BaCl₂, more Ba²⁺ could be adsorbed on the FA-coated mica surface. The peak closest to the mica included Ba²⁺ ions adsorbed directly on the mica in an amount similar to that in the BaCl₂ solution but more broadly distributed. A second peak observed within the FA layer suggests that the FA coating provides additional sites for Ba²⁺ sorption. The results indicate that enhanced uptake of heavy metals can occur when an organic coating already exists on a mineral surface.     

Estimation and Projection of Non-Linear Relative Sea-Level Rise in the Seto Inland Sea,Japan

Future sea-level rise (SLR) in and around the Seto Inland Sea (SIS), Japan, is estimated in 2050 and 2100 using ensemble empirical mode decomposition (EEMD) and long-term sea-level records. Ensemble empirical mode decomposition, an adaptive data analysis method, can separate sea-level records into intrinsic mode functions (IMFs) from high to low frequencies and a residual. The residual is considered a non-linear trend in the sea-level records. The mean SLR trend at Tokuyama in the SIS from EEMD is 3.00?mm?y^?1 from 1993 to 2010, which is slightly lower than the recent altimetry-based global rate of 3.3?±?0.4?mm?y^?1 during the same period. Uncertainty in SLR is estimated by considering interdecadal variations in the sea levels. The resulting SLR in 2050 and 2100 for Tokuyama is 0.19?±?0.06?m and 0.56?±?0.18?m, respectively. The stations along the coast of the Pacific Ocean display a greater and more rapid SLR in 2100 compared with other stations in the SIS. The SLR is caused not only by mass and volume changes in the sea water but also by other factors, such as local subsidence, tectonic motion, and river discharge. The non-linear trend of SLR, which is the residual from EEMD, is interpreted as the sum of the local factors that contribute to the sea-level budget.     

Assessment of tributyltin contamination in a shipyard area using a mussel transplantation approach

Mussels (Mytilus galloprovincialis) were transplanted to seven stations around a large shipyard for 126 days to evaluate tributyltin (TBT) contamination. Although the application of TBT-based paints to ships is totally banned in Korea, butyltin compounds were found to accumulate in mussels following transplantation. Concentrations of TBT and total butyltins in transplanted mussels near the shipyard were in the range of 40-350 ng Sn/g and 74-530 ng Sn/g on a dry weight basis, respectively. Obviously, low TBT concentrations (6.0-53 ng Sn/gdw) were determined in mussels at four stations outside the shipyard. A negative gradient of TBT concentrations and TBT portion to total butyltin concentrations were found in both the surface water and transplanted mussels according to distance from the shipyard. In addition, TBT concentrations in surface water and transplanted mussels showed significant correlation (r(2) = 0.71; p < 0.001). These results indicate that the shipyard still releases fresh TBT into surrounding waters even after TBT regulation in Korea, and mussel transplantation is useful in evaluating TBT contamination in shipyard area.     

Simulation of the 1953 storm surge in the North Sea

The 1953 North Sea floods, the Big Flood, was one of the worst natural disasters in Europe in modern times and is probably one of the most studied severe coastal floods. Several factors led to the devastating storm surge along the southern North Sea coast in combination of strong and sustained northerly winds, invert barometric effect, high spring tide, and an accumulation of the large surge in the Strait of Dover. However, the storm waves and their roles during the 1953 North Sea storm surge are not well investigated. Therefore, the effect of wave setup due to breaking waves in the storm surge processes is investigated through numerical experiments. A coupled process-based tide-wave-surge model was used to investigate and simulate the storm surge in the North Sea during January 31–February 1, 1953 and validated by comparing with historical water level records at tide gauges and wave observations at light vessels in the North Sea. Meteorological forcing inputs for the period, January 27–February 3, 1953 are reproduced from ERA-20C reanalysis data with a constant correction factor for winds. From the simulation results, it is found that, in addition to the high water due to wind setup, wave setup due to breaking waves nearshore play a role of approximately 10% of the storm surge peaks with approximately 0.2 m. The resulting modeling system can be used extensively for the preparedness of the storm surge and wave of extreme condition, and usual barotropic forecast.     

Dolomitization of Carbonate Periplatform Deposit,Machari Formation (Middle to Late Cambrian),Korea

The petrography, the geochemistry and the burial history all constrain the origin and modification history of dolomites in an ancient periplatform carbonate slope deposit,the Machari Formation (late Miclclle to early Late Cambrian),Korea. The formation is mainly composed of rhythmic bedding. laminated to bedded lime mudstone alternating with argillaceous lime mudstone. The rhythmic bedding is a product of the deposition of offshore periplatform ooze and hemipelagic clay on a periplatform slope. This formation also shows minor and intermittent influx of other lithofacies including the bioclastic-peloidal packstone, peloidal wackestone, and intraclasts deposited as turbidites. Five types of dolomite occur in the Machari Formation, whose occurrence.texture and geochemistry provide an insight into origin and modification history.     

Fatigue strength assessment of MARK-III type LNG cargo containment system

The aim of this paper is to investigate the fatigue strength of the GTT Mark-III type LNG insulation system. The LNG insulation system consists of several composite layers with various connections; plywood, triplex, reinforced polyurethane foam and mastic. Consequently, the LNG insulation system may include mechanical failures such as cracks as well as delaminations within the layers due to sloshing impact loads and fatigue loadings. In addition, these failures may cause a significant decrease of structural integrity. In this study, a series of fatigue tests have been carried out for Mark-III type LNGC insulation systems at room temperature considering the effect of sloshing impact. The load levels have been determined based on the ultimate strength of reinforced polyurethane foam. The aim of the study is to investigate the typical failure characteristics of the MARK-III LNG insulation system and to obtain the S–N data under fatigue loading. A consolidated single S–N curve is obtained based on a systematic finite element procedure. Future use of the S–N data in fatigue analysis requires that the response analysis is carried out using a finite element model with the same mesh density and material properties. This study can be used as a fundamental study for the fatigue assessment of the LNGC insulation system as well as a design guideline.     

Numerical analysis of effects of tidal variations on storm surges and waves

This study examines the effects of tides on surges, wave setups and waves, in terms of tidal amplitudes and phases, by using a coupled numerical model of Surge, WAve and Tide (called as SuWAT). The SuWAT model, composed of depth integrated nonlinear shallow water equations and Simulating WAves Nearshore (SWAN) model, is able to simultaneously run with an arbitrary number of nested domains by using the Message Passing Interface. The results for an idealized case indicate that surge and wave setup are increased in the phase of low water and decreased in the high water phase; on the other hand, waves change in a reverse manner. Such changes are enhanced by large tidal variations. The conventional method (e.g., surge plus tide independently) has the possibility of overestimation for the total water level. The hindcast results for Typhoon Ewiniar in 2006 show that the run with tides is more accurate 10% than that without tides in coastal areas of Korea. The nested scheme improves the accuracy up to 40% for the prediction of water levels in the simulations. It is shown that the present coupled model, SuWAT, is capable of predicting both water levels and waves under storm events with reasonable accuracy against the observations.     

Ship measurements of submicron aerosol size distributions over the Yellow Sea and the East China Sea

During the spring of 2005, the total particle concentrations and the submicron aerosol size distributions were measured on board the research vessel over the south sea of Korea and the Korean sector of the Yellow Sea. Similar measurements were made over the East China Sea in autumn 2005. The aerosol properties varied dynamically according to the meteorological conditions, the proximity to the land masses and the air mass back trajectories. The average total particle concentration was the lowest over the East China Sea, 4335 ± 2736 cm^− 3, but the instantaneous minimum, 837 cm^− 3, for the entire ship measurement was recorded during the Yellow Sea cruise. There was also a long (more than 6 h) stretch of low total particle concentrations that fell as low as 1025 cm^− 3 during the East China Sea cruise when the ship was the farthest from the shores and the air mass back trajectories resided long hours over the sea. These observations lead to the suggestion of ~ 1000 cm^− 3 as the background total particle concentration over the marine boundary layer in the studied region of the Yellow Sea and the East China Sea, implying significant anthropogenic influence even for the background value. In the mean time, average aerosol size distributions were unimodal and the mode diameter ranged between 52 and 86 nm, excluding the fog periods, which suggests that the aerosols measured in this study experienced relatively less aging processes within the marine boundary layer.     

Geochemistry of Quaternary sediments of the Jeongokri archaeological site,Korea: implications for provenance and palaeoenvironments during the Late Pleistocene

The geochemical characteristics of an approximately 6‐m‐long sediment core collected from the Jeongokri archaeological site (Hantan River, Korea) were examined to determine the provenance of the sediments and to reconstruct the palaeoenvironment of the study area during the Late Pleistocene (200–127 ka). The core sediments were subdivided into two parts based on grain size: an upper (0–380 cm depth) and lower part (>380 cm depth). The lower part was deposited primarily by fluvial processes during an interglacial period [marine isotope stage (MIS) 7] with warm and humid conditions. Conversely, the upper part was mainly deposited by aeolian processes during a cold and dry glacial period (MIS 6). Geochemical characteristics, represented by major, trace and rare earth element (REE) compositions, and textures of the Jeongokri core sediments show distinct differences between the upper and lower parts. The mineralogy and major, trace and REE compositions indicate that the influence of felsic source rocks (e.g. granite) was dominant in the lower sediments, which were derived from the Hantan River. In contrast, increased quartz content and the very fine and homogeneous grain size in the upper sediments indicate an aeolian origin. REE ratios and distribution patterns, and geochemical signatures indicate that these sediments were derived predominantly from Chinese loess deposits and partially from local sediments from the Korean Peninsula; the possible source area of the upper sediments is the northern part of the Yellow Sea basin. The Yellow Sea basin, having mixed geochemical signatures between Chinese loess and Korean‐derived sediments, was exposed because of low sea levels during MIS 6. The exposed Yellow Sea basin was located in the path of winter‐monsoon winds, which may have carried a great deal of airborne sediments from the basin to the Jeongokri area. Copyright © 2011 John Wiley & Sons, Ltd.