A Comparison of Benzene and Toluene Plume Lengths for Sites Contaminated with Regular vs. Ethanol-Amended Gasoline

This article describes various statistical analyses of plume-length data to evaluate the hypothesis that the presence of ethanol in gasoline may hinder the natural attenuation of hydrocarbon releases. Plume dimensions were determined for gasoline-contaminated sites to evaluate the effect of ethanol on benzene and toluene plume lengths. Data from 217 sites in Iowa (without ethanol; set 1) were compared to data from 29 sites in Kansas that were contaminated by ethanol-amended gasoline (10% ethanol by volume; set 2). The data were log-normally distributed, with mean benzene plume lengths (± standard deviation) of 193 ± 135 feet for set 1 and 263 ± 103 feet for set 2 (36% longer). The median lengths were 156 feet and 263 feet (69% longer), respectively. Mean toluene plume lengths were 185± 131 feet for set 1 and 211 ±99 feet for set 2 (14% longer), and the median lengths were 158 feet and 219 feet (39% longer), respectively. Thus, ethanol-containing BTEX plumes were significantly longer for benzene (p < 0.05), but not for toluene. A Wilcoxon signed rank test showed that toluene plumes were generally shorter than benzene plumes, which suggests that toluene was attenuated to a greater extent than benzene. This trend was more pronounced for set 2 (with ethanol), which may reflect that benzene attenuation is more sensitive to the depletion of electron acceptors caused by ethanol degradation. These results support the hypothesis that the presence of ethanol in gasoline can lead to longer benzene plumes. The importance of this effect, however, is probably site-specific, largely depending on the release scenario and the available electron acceptor pool.     

In Situ Monitoring of Vapor Phase TCE Using a Chemiresistor Microchemical Sensor

A chemiresistor microchemical sensor has been developed to detect and monitor volatile organic compounds in unsaturated and saturated subsurface environments. A controlled study was conducted at the HAZMAT Spill Center at the Nevada Test Site, where the sensor was tested under a range of temperature, moisture, and trichloroethylene (TCE) concentrations. The sensor responded rapidly when exposed to TCE placed in sand, and it also responded to decreases in TCE vapor concentration when clean air was vented through the system. Variations in temperature and water vapor concentration impacted baseline chemiresistor signals, but at high TCE concentrations the sensor response was dominated by the TCE exposure. Test results showed that the detection limit of the chemiresistor to TCE vapor in the presence of fluctuating environmental variables (i.e., temperature and water vapor concentration) was on the order of 1000 parts per million by volume, which is about an order of magnitude higher than values obtained in controlled laboratory environments. Automated temperature control and preconcentration is recommended to improve the stability and sensitivity of the chemiresistor sensor.     

The role of sediment specific gravity and availability on cluster evolution

The objective of this experimental study was to account for the role of sediment availability and specific gravity on cluster formation and cluster geometric characteristics (spacing and size). To isolate the effects of sediment availability and specific gravity on cluster evolution, mono‐sized spheres were used to simulate the cluster evolutionary cycle. Overall, twelve experimental runs were carried out in the laboratory flume. Six of these tests were performed by using glass spheres (specific gravity, SG = 2·58) and the other six by employing an equal combination of glass and Teflon spheres (SG = 2·12) of the same diameter to evaluate the role of specific gravity on cluster evolution. The three sediment availability conditions that were investigated here simulated isolated gravel elements, pool–riffle sequences and densely packed gravel‐bed. An advanced image analysis technique was employed to track the evolution of cluster microforms and provide quantitative information about the size and shape of clusters and the number of clusters per unit area. The results of this study showed that: (1) sediment availability affects the architecture and size of cluster microforms; and (2) clusters consisting of mono‐sized sediments start disintegrating at twice the incipient conditions. By performing complementary tests for the isolated gravel elements case, it was found that the evolutionary cycle of individual clusters could be described as follows, in order of increasing stress: no cluster→two particle cluster→comet→triangle→rhomboid→break up. Copyright © 2003 John Wiley & Sons, Ltd.     

Weathering control over geomorphology of supermature Proterozoic Delhi quartzites of India

Quartz and quartzite are thought to be resistant as a mineral and a rock respectively; however, we have shown that the presence of small amounts of pyrite in the quartzites makes them vulnerable to weathering. We observe that weathering of Proterozoic quartzite in the semi‐arid conditions around Delhi proceeded from fractures towards the inside and produced weathering rinds. The chemical index of alteration (CIA), which is actually a measure of weathering of aluminosilicate minerals, increases from the core outwards, through the rinds. Although aluminosilicate minerals occur only as minor phases (<2 per cent), their weathering indicates a movement of the weathering front from the periphery towards the core. We have suggested a coupled mechanism in which the dissolution of pyrites by moving water produced a sulphate‐bearing acidic solution and ferrous iron, which reacted with aluminosilicate minerals and quartz, respectively. This initially makes the Delhi quartzite porous and subsequently friable. The total disintegration of grain to grain contacts imparted friability to this quartzite to produce silica sand. Subsequent physical erosion of loose sand, produced during rind development in the outermost zones, has given rise to features like tors, spheroids, gullies, cavities and small‐scale caves on these quartzites. Thus, the terrain has acquired ruggedness in semi‐arid conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Short‐term erosion rates from a 7Be inventory balance

Detailed soil erosion studies bene?t from the ability to quantify the magnitude of erosion over time scales appropriate to the process. An inventory balance for ⁷Be was used to calculate sediment erosion in a 30·73 m² plot during a series of runoff‐producing thunderstorms occurring over three days at the Deep Loess Research Station in Treynor, Iowa, USA. The inventory balance included determination of the pre‐ and post‐storm ⁷Be inventories in the soil, the atmospheric in?ux of ⁷Be during the event, and pro?les of the ⁷Be activity in the soil following the atmospheric deposition. The erosion calculated in the plot using the ⁷Be inventory balance was 0·058 g cm^?2, which is 23 per cent of the annual average erosion determined using ¹³⁷Cs inventories. The calculated erosion from the mass balance is similar to the 0·059 g cm^?2 of erosion estimated from the amount of sediment collected at the outlet of the 6 ha ?eld during the study period and the delivery ratio (0·64). The inventory balance of ⁷Be provides a new means for evaluating soil erosion over the time period most relevant to quantifying the prediction of erosion from runoff. Copyright © 2003 John Wiley & Sons, Ltd.     

Computer Simulation of Shaped Charge Detonation Using Meshless Particle Method

Shaped charges are widely applied in the defense industry and civil engineering for penetrating hardened targets. Simulations of shaped charges are generally based on traditional grid-based numerical methods. Different from the existing literature, the SPH method is applied in this paper to simulate the detonation process of shaped charge explosive. The combination of the meshless, Lagrangian and particle nature inherent in the SPH method is very attractive in dealing with large deformations and large inhomogeneities in extremely transient situations such as detonation process. The SPH method and some related numerical aspects are briefly discussed first, followed by applications in simulating shaped charge detonations. The effects of different detonation cavity angles and different charge head lengths are investigated. The results demonstrate that major shaped charge detonation phenomena are captured with revealing observations.     

Neotectonic Control on the Geomorphic Evolution of the Gangotri Glacier Valley, Garhwal Himalaya

The paper records evidences of neotectonic activities in the Gangotri glacier valley that are found to be responsible for the present-day geomorphic set-up of the area since the last phase of major glaciation. Geomorphological features indicate the presence of a large glacier in the valley in the geological past. Prominent planar structures present in the rocks were later on modified into sets of normal faults in the present-day Himalayan tectonic set-up giving rise to graben structures. The block nearest the snout is traversed by the NW-SE trending Gaumukh fault. A number of terraces mark the entrenchment of Bhagirathi River in this part. The contrasting drainage morphometric parameters of two sides of the valley and asymmetric recessional patterns of the tributary glaciers further document movement along the fault. The distribution and orientation of debris fans also seem to be controlled by neotectonic activity. The neotectonic activity that followed the process of deglaciation has brought the glacially carved, wide U- shaped valley in contact with the present-day fluvially incised narrow and relatively deep valley. The wider segments have become sites of active deposition of glacially eroded debris. The low gradient and excessive filling has resulted in the river attaining a braided nature in these segments.     

Local site effects in Latur, India: an empirical study based on the aftershocks of the Killari earthquake of September 29, 1993

The site amplification is estimated at five seismic stations of the Latur region using the horizontal to vertical spectral ratios of 33 aftershocks of the main Killari earthquake of September 29, 1993 (UTC). Spectral amplifications, ranging from a factor of 2–6 are found to vary with frequency at different places. Significant amplification is found at four sites within the Latur region, at Basavakalyan, Kasgi, Killari, and Mudgad Eakoji villages. Our results show a positive correlation between the site amplification and the damage pattern in area. The pattern and the nature of the site amplification estimated in the present study corroborates also with the analytical models and the borehole data indicating alternating layers of unconsolidated sediments and basaltic rocks.     

Classification of artificial (man-made) ground

The legacy inherited from anthropogenic processes needs to be addressed in order to provide reliable and up-to-date ground information relevant to development and regeneration in the urban environment. The legacy includes voids as well as anthropogenic deposits (artificial ground). Their characteristics derive from former quarrying and mining activities industrial processes creating derelict ground, variably consolidated made ground, and contaminated groundwater and soils. All need to be systematically assessed to inform the planning process and provide the basis for engineering solutions. Site-specific investigation needs to be conducted on the back of good quality geoscientific data. This comes from ‘field’ survey, remotely sensed data interpretation, historical maps, soil geochemical sampling, and geotechnical investigation. Three-dimensional and, in the future, four dimensional, characterization of superficial deposits is required to reach an understanding of the potential spatial lithological variability of artificial ground and the geometry of important surfaces, i.e. the boundary conditions. The classification scheme for artificial ground outlined in this paper and adopted by the British Geological Survey, will help in achieving this understanding.