Bifurcation points in close binary evolution: Medium-mass binaries

The remaining core hydrogen burning lifetime after case B of mass transfer of the secondary (mass gaining) component in a medium mass close binary star is estimated, for mediummass binaries with primaries in the mass range 5M to 9M . From the comparison of this quantity with the helium burning time-scale of the remnant primary a critical mass ratioq _c is derived such that for larger values ofq, mass transfer from the secondary towards the primary starts before the latter has evolved into a white dwarf. Consequences for the advanced stages of medium mass binaries are discussed.     

The evolution of massive close binaries

The results of evolutionary computations for massive binary systems (initial masses of the primary 10M ) with mass ratios between 0.3 and 0.8 are summarized and compared with observations in order to verify how far one can go with the conservative assumption of mass exchange. It is found that conservative mass exchange leads to acceptable first-order models of W-R and massive X-ray binaries. However, the comparison between this theory and observation reveals that for the observed systems (W-R and X-ray binaries) a preference exists for low intial mass ratios; moreover, the X-ray luminosities of the theoretical models are systematically too low, though this may be due to the adopted wind model. In addition, the influences of several parameters (distance between the components, chemical composition, primary mass, mass ratio and atmosphere) are examined. These parameters influence the remnant mass and any further evolution only marginally. Attention is also given to the effect on the system parameters of a supernova explosion of the remnant of the mass-losing component. For a large range of systems a disruption probability smaller than 25% is found.     

Electrochemistry of reduced sulfur species in natural waters—I. The H2S-H2O system

Careful measurements of rest potentials of platinum electrodes (Eh) in the H₂S-H₂O system were made together with measurements of the pH and the potentials of Ag-Ag₂S electrodes (E_s^2?). The potentials of the platinum electrode are characteristic of H₂S chemisorption followed by H₂S discharge on the platinum. The relations between Eh, E_s^2? and pH are characteristic of the H₂S-H₂O system and of the hydrogen sulfide concentration. Thus these parameters can be employed to distinguish H₂S-H₂O systems from H₂S-S₈-H₂O systems. Field measurements on hot sulfurous springs are in agreement with laboratory data.     

Enregistrement de la variabilité hydroclimatique au cours des 6500 dernières années sur le littoral de Cabo Frio (Rio de Janeiro,Brésil)

This study concerns a core collected in Brejo do Espinho's lagoon from Cabo Frio littoral (Brazil) submitted to dry influence of local upwelling controlled by north-east trade winds from the South Atlantic and particularly strengthened during El Niño events. Diatoms study supported by sedimentological and isotopic analyses shows dry phases infrequent before 4000 yr, a highly variable climatic phase between 3600 and 2900 yr and from 2400 yr onward a dryness enhancement. To cite this article: B. Laslandes et al., C. R. Geoscience 338 (2006).     

A framework for an optimised groundwater monitoring network and aggregated indicators

The implementation of the Water Framework Directive (EU 2000) requires a groundwater quality monitoring. It is used for characterisation of the ‘good’ chemical status of each groundwater body and for the restoration or protection purposes of those bodies already at ‘good’ status. Interpretative aspects are lying in the design of monitoring network and in the way of building global indicators. Attention is given here to the global chemical status of the groundwater bodies and to the role of diffuse pollution, much of which is brought via groundwater to surface water. Monitoring ‘local’ pollution associated with individual sites is not addressed. Groundwater bodies with different contrasted hydrogeology conditions, land use and topography have been considered to establish an approach for choosing an optimised monitoring network. Then, a quality assessment system has been developed and applied for qualifying the general status of each groundwater body. The use of non-dimensional indexes allows us to process with all kinds of chemical parameters in a normalised way and, by means of adequate aggregation rules, to qualify the general quality status of a groundwater body. The obtained diagnostic, even if not fully validated, is closely linked to the pragmatic objectives contained in the EU Water Directive.     

Short-term beach–dune sand budgets on the north sea coast of France: Sand supply from shoreface to dunes, and the role of wind and fetch

Three experimental plots, covering the transition from the upper beach to the dune, on the North Sea coast of France were monitored at various intervals over a period of 18–24 months via high resolution terrain surveys in order to determine inter-site sand budget variability, as well as patterns and processes involved in sand exchanges between the upper beach and dune. The wind regime consists of a fairly balanced mix of moderate (80% of winds are below 8 m/s) onshore, offshore and shore-parallel winds. Sustained dune accretion over several years depends on the periodic local onshore welding of shoreface tidal banks that have developed in the storm- and tide-dominated setting of the southern North Sea. The only site where this has occurred in the recent past is Calais, where bank welding has created a wide accreting upper beach sand flat. At this site, significant sand supply from the subtidal sand bank reservoir to the upper beach flat occurred only once over the 18-month survey following a major storm. The bulk of the sand deposited over this large flat is not directly integrated into the adjacent embryo dunes by onshore winds but is progressively reworked in situ into developing dunes or transported alongshore by the balanced wind regime, thus resulting in alongshore stretching of the embryo dune system. The Leffrinckoucke site near Belgium shows moderate beach–dune mobility and accretion, while the Wissant site exhibits significant upper beach bedform mobility controlled by strong longshore currents that result in large beach budget fluctuations with little net budget change, to the detriment of the adjacent dunes. Accretion at these two sites, which are representative of the rest of the North Sea coast of France, is presently constrained by the absence of a shore-attached sand bank supply reservoir, while upper beach–dune sand exchanges are further limited by the narrow wave-affected upper beach, the intertidal morphology of bars and troughs which segments the aeolian fetch, and the moderate wind energy conditions. The balanced wind regime limits net sand mobilisation in favour of either the beach or the dune, and may explain the relatively narrow longshore morphology of the dune ridges bounding this coast.     

Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.     

Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.     

Transport in a 2-D saturated porous medium: A new method for particle tracking

A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed.     

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).