Boron and Oxygen Isotope Composition of Certified Reference Materials NIST SRM 610/612 and Reference Materials JB-2 and JR-2

We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ¹¹ B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ¹¹ B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.     

Monthly and annual statistical distributions of daily rainfall at the Fabra Observatory (Barcelona, NE Spain) for the years 1917–1999

Summary Three empirical distributions of the daily rainfall collected at the Fabra Observatory from 1917 to 1999 are fitted to different statistical models. The first two are designated as the distributions of cumulative amounts and cumulative times. The third distribution accounts for the time interval between two consecutive rainy days with rain amounts equalling or exceeding a threshold amount. Whereas the distribution of cumulative amounts follows an exponential model at monthly and annual scale, except for a few cases, the distribution of the cumulative times is well modelled by a Weibull function, whether monthly or annual scales are considered. The distribution of time intervals also follows a Weibull distribution for the different thresholds considered. In addition, the combination of the two first distributions leads to the normalised rainfall curve, NRC, which is also reproduced satisfactorily by a beta (type 1) distribution. It is worth mentioning that the NRCs follow the expected behaviour with respect to the coefficient of variation of daily rain amounts at monthly and annual scales. In addition, a better understanding of fluctuations and time trends affecting the daily pluviometric regime is achieved by analysing the annual NRCs. The impact of some features of this rain regime, developed for Barcelona, a crowded metropolitan area, on many human activities, may provides the focus of future interdisciplinary analyses.     

The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.     

Spatial and temporal rockfall activity in a forest stand in the Swiss Prealps—A dendrogeomorphological case study

Rockfall is a major threat to settlements and transportation routes in large parts of the Alps. While protective forest stands in many locations undoubtedly reduce rockfall risk, little is known about the exact frequency and spatial distribution of rockfall activity in a given place or about how these parameters can be assessed. Therefore, the objective of the present study was to reconstruct rockfall events with dendrogeomorphological methods and to analyse the spatial and temporal rockfall activity in a subalpine forest stand. The study site is located in the transit zone of frequently passing, rather small rockfall fragments (mean diameter of 10 to 20 cm). In all, 33 stem discs from previously felled Picea abies trees found at the foot of Schwarzenberg in Diemtigtal (Swiss Prealps) were sampled, and a total number of 301 rockfall events were dated to between A.D. 1724 and 2002.Results showed that the spatial distribution of rockfall changed slightly with time, and that rockfall activity increased considerably over the last century. In contrast, rockfall magnitude presumably remained on a comparable level. The seasonal occurrence of rockfall showed a clear peak during the dormant season of trees, most probably in early spring. Furthermore, on a 10-year moving average basis, rockfall rates were positively correlated with mean annual as well as summer and winter temperatures. This means that higher temperatures resulted in increased rockfall activity. On the other hand, no correlation with annual or seasonal precipitation totals was revealed. Overall, this study provides an appropriate method for the detailed assessment of spatial and temporal variations in rockfall activity in a given place.     

Analysis of the Difference Light Curve of the Gravitational Mirage QSO 0957+561

From optical data of Q0957+561 for 1995/1996 seasons (in the g band) and 1996/1997 seasons (in the R band) they are derived upper limits on the amplitude of the rapid microlensing fluctuations of 0.07 mag and 0.05 mag, respectively. The photometry in the R band (1996/1997 seasons) was taken at Teide Observatory (IAC-80 Telescope), Instituto de Astrofisica de Canarias, Spain. In this contribution, we also study the microlensing history (from 1981 to 1996) of the Twin QSO, which is a curious system with two optical images of similar brightness. This revised version was published online in July 2006 with corrections to the Cover Date.     

The fate of foramol (“temperate-type”) carbonate platforms

On rimmed shelves of Bahamian-type, characterized by chlorozoan associations and typical of tropical seas, carbonate production keeps pace with normal sea-level rise except when rapid rise or drastic environmental changes occurs. On the other hand, open temperate carbonate shelves are characterized by low carbonate production of the foramol association (molluscs, benthic foraminifera, bryozoans, coralline algae, etc.) and generally show seaward relict sediments, because carbonate production cannot keep pace with normal rate of sea-level change.

Several examples of recent drowning foramol carbonate platforms (e.g., large areas of the Mediterranean Sea, eastern-northeastern Yucatan Shelf) as well as analogous ancient drowned foramol-type carbonate platforms (e.g., early to middle Miocene of the Southern Apennines; Miami Terrace) may support the idea that the drowning of many ancient carbonate platforms has been favoured by their biogenic (foramol sensu lato) constitution. Because of their typically low rate of growth, foramol carbonate platforms are fated to be drowned even if the sea-level rise is one with which the normal growth of chlorozoan platforms can keep pace. Similar conditions may also occur in tropical areas where variations in environmental conditions, such as the presence of cold waters, changes in salinity and increased nutrients, preclude the development of chlorozoan associations.     

Development of water management strategies in southern Mesopotamia during the fourth and third millennium B.C.E.

The last two decades witnessed increasing scholarly interest in the history of water management in southern Mesopotamia. Thanks to many geoarchaeological research projects conducted throughout the central and southern Iraqi floodplains, a general understanding of the macrophases of anthropogenic manipulation of this vast hydraulic landscape has been achieved. However, current narratives mostly rely on studies at a regional scale and are based on excessively long chronological phases (often spanning a whole millennium). A finer-tuned analysis at a submillennial scale is needed to better appreciate the dynamics that led to the development of artificial canals and irrigation systems and the creation of harbours in cities and other navigation-related facilities. The Iraqi-Italian QADIS project is addressing this issue through a systematic geoarchaeological investigation in the south-eastern area of the Qadisiyah province. We aim to update the current narrative by analysing case studies involving specific periods of occupation. We performed 17 boreholes to propose a date on the functioning period of the hydraulic works in five selected archaeological sites of this region. This approach allowed us to understand changes in water management strategies in both the short and the medium term (i.e., on a scale of centuries). In this paper, we present the results for the fourth and third millennia B.C.E. This period witnessed a crucial passage from the basic exploitation of natural watercourses for irrigation and occasional navigation to the emergence of the first system of artificial canals and intraurban harbours.     

A multi-arc approach for chaotic orbit determination problems

Chaotic dynamical systems are characterized by the existence of a predictability horizon, connected to the notion of Lyapunov time, beyond which predictions of the state of the system are meaningless. In order to study the main features of orbit determination in the presence of chaos, Spoto and Milani (Celest Mech Dyn Astron 124:295–309, 2016) applied the classical least-squares fit and differential correction algorithm to determine a chaotic orbit and a dynamical parameter of a simple discrete system—Chirikov standard map (cf. Chirikov in Phys Rep 52:263, 1979)—with observations distributed beyond the predictability horizon. They found a time limit beyond which numerical calculations are affected by numerical instability: the computability horizon. In this article, we aim at pushing forward such inherent obstacle to numerical calculations in chaotic orbit determination by applying the classical and the constrained multi-arc method (cf. Alessi et al. in Mon Not R Astron Soc 423:2270–2278, 2012) to the same dynamical system. These strategies entail the determination of an orbit when observations are grouped in separate observed arcs. For each arc, a set of initial conditions is determined and, in the case of the constrained multi-arc method, all subsequent arcs are constrained to belong to the same trajectory. We show that the use of these techniques in place of the standard least-squares method has significant advantages: Not only can we perform accurate numerical calculations well beyond the computability horizon, in particular, the constrained multi-arc strategy improves considerably the determination of the dynamical parameter.     

An XMM-Newton proton response matrix

Soft protons constitute an important source of background in focusing X-ray telescopes, as Chandra and XMM-Newton experience has shown. The optics in fact transmit them to the focal plane with efficiency similar to the X-ray photon one. This effect is a good opportunity to study the environment of the Earth magnetosphere crossed by the X-ray satellite orbits, provided that we can link the spectra detected by the instruments with the ones impacting on the optics. For X-ray photons this link has the form of the so-called response matrix that includes the optics effective area and the energy redistribution in the detectors. Here we present a first attempt to produce a proton response matrix exploiting ray-tracing and GEANT4 simulations with the final aim to be able to analyse XMM-Newton soft proton data and link them to the external environment. If the procedure is found to be reliable, it can be applied to any future X-ray missions to predict the soft particles spectra impacting on the focal plane instruments.     

Biogeomorphology of the Mediterranean Posidonia oceanica seagrass meadows

Here we review the multiple interactions between the endemic Mediterranean seagrass, Posidonia oceanica, and coastal geomorphologic processes as an outstanding example of biogeomorphology, taking into account recent advances in the field. Seagrass meadows are among the most important elements for the functioning of marine coastal ecosystems, and represent a major focus for research and conservation. Being considered a priority habitat, P. oceanica meadows are protected by several European Union directives and national laws. In this paper we examine: the role of sedimentary features in controlling the development of the meadows; the interplay between P. oceanica leaf litter (i.e. beached necromass) cast ashore and erosional‐depositional processes on the beaches; the interactions between meadows and nearshore hydrodynamics, and; possible linkages between geomorphological features of the seafloor and the architecture of meadows. Finally, we provide perspectives for future research on P. oceanica and other Mediterranean seagrass meadows in a biogeomorphological context with specific reference to climate change. Copyright © 2016 John Wiley & Sons, Ltd.