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31.
Francesco Di Benedetto Francesco D’Acapito Gabriele Fornaciai Massimo Innocenti Giordano Montegrossi Luca A. Pardi Silvia Tesi Maurizio Romanelli 《Physics and Chemistry of Minerals》2010,37(5):283-289
An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO2) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe2+ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell: = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe3+ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe4+ is stabilised by the favourable local structural arrangement. 相似文献
32.
Silvia Ceramicola Daniel Praeg Andrea Cova Daniela Accettella Massimo Zecchin 《Geo-Marine Letters》2014,34(2-3):111-129
Mud volcanoes (MVs) are abundant along the eastern Mediterranean subduction zones, recording mud breccia extrusion over long timescales (106 years), but to date relatively few have been recognised in the northern Ionian Sea on the Calabrian accretionary prism (CAP). In the present study, the seafloor distribution and recent activity of MVs is investigated across a 35,600 km2 sector of the CAP using a regional acoustic dataset (multibeam bathymetric and backscatter imagery, integrated with subbottom profiles) locally ground-truthed by sediment cores. A total of 54 MVs are identified across water depths of 150–2,750 m using up to four geophysical criteria: distinctive morphology, high backscatter, unstratified subbottom facies and, in one case, a hydroacoustic flare. Fourteen MVs are identified from 3–4 criteria, of which five have been previously proven by cores containing mud breccia beneath up to 1.6 m of hemipelagic sediments (Madonna dello Ionio MVs 1–3, Pythagoras MV and the newly named Sartori MV), while nine others are identified for the first time (Athena, Catanzaro, Cerere, Diana, Giunone, Minerva, ‘right foot’, Venere 1 and 2). Forty other as yet unnamed MVs are inferred from 1–2 geophysical criteria (three from distinctive morphology alone). All but one possible MV lie on the inner plateau of the CAP, landwards of the Calabrian Escarpment in a zone up to 120 km wide that includes the inner pre-Messinian wedge and the fore-arc basins, where they are interpreted to record the ascent from depth of overpressured fluids that interacted with tectonic structures and with evaporitic or shale seals within the fore-arc basins. The rise of fluids may have been triggered by post-Messinian out-of-sequence tectonism that affected the entire pre-Messinian prism, but Plio-Quaternary sedimentation rates and depositional styles support the inference that significant mud volcanism has taken place only on the inner plateau. Sedimentation rates across the CAP applied to a 12 khz sonar detection depth of 225 cm imply that all MVs with backscatter signatures (50 of 54) have erupted mud breccias within the last 56 ka, and within the last 12.5 ka in the fore-arc basins. Ages of eruption estimated from the depth of cored mud breccias at five MVs, and a seismo-stratigraphic relationship at a sixth, indicate episodes at the last glacial maximum ca. 20 ka BP and during the postglacial period. Eruptive episodes within the Calabrian MV province constitute recurrent geohazards, separated by longer periods of quiescent (subdued) fluid seepage that are likely to support gas hydrate formation and chemosynthetic ecosystems. 相似文献
33.
A numerical Round Robin on tunnels under seismic actions 总被引:3,自引:0,他引:3
Emilio Bilotta Giovanni Lanzano S. P. Gopal Madabhushi Francesco Silvestri 《Acta Geotechnica》2014,9(4):563-579
Although the seismic behaviour of shallow circular tunnels in soft ground is generally safer than aboveground structures, some tunnels were recently damaged during earthquakes. In some cases, damage was associated with strong ground shaking and site amplification, which increased the stress level in the tunnel lining. Pseudo-static and simplified dynamic analyses enable to assess transient changes in internal forces during shaking. Nevertheless, experimental evidences of permanent changes in internal loads in the tunnel lining would suggest that a full dynamic analysis including plastic soil behaviour should be performed when modelling the dynamic interaction between the tunnel and the ground. While sophisticated numerical methods can be used to predict seismic internal forces on tunnel structures during earthquakes, the accuracy of their predictions should be validated against field measurements, but the latter are seldom available. A series of centrifuge tests were therefore carried out at the University of Cambridge (UK) on tunnel models in sand, in the framework of a research project funded by the Italian Civil Protection Department. A numerical Round Robin on Tunnel Tests was later promoted among some research groups to predict the observed behaviour by means of numerical modelling. In this paper, the main results of five selected numerical predictions are summarized and compared with the experimental results. 相似文献
34.
Martín L. Larrea Silvia M. Castro Ernesto A. Bjerg 《Arabian Journal of Geosciences》2014,7(8):2981-2989
In the field of geology, as in many other fields, a common problem is the analysis of 2D sections. An example of this is the petrographic study of rock samples, i.e., the quantification of its mineral components and the percentages of each phase present in it. Conventionally, this quantification has been determined by point counting performed on thin sections. Although point counting is very time consuming, it is of common use in several domains including geology, biology, medicine, and materials sciences, among others. Point counting in thin sections is normally conducted through mechanical or electromechanical devices attached to a microscope; such devices are very expensive, offer limited functionality, and are very time consuming. In this contribution, we introduce an interactive visualization application called Rock.AR that reduces the amount of time required to apply this technique and simplify its work flow. It provides visual tools like distortion techniques, overview + detail, and statistics to assist the technique. A comparison between this application and similar tools through users' experiences is provided. We compare the time it takes to complete a session of point counting and the tools' usability. 相似文献
35.
Filippo Santucci de Magistris Anna d’Onofrio Augusto Penna Rodolfo Puglia Francesco Silvestri 《Natural Hazards》2014,74(3):2005-2035
The prediction of the variability of the seismic ground motion in a given built-up area is considered an effective tool to plan appropriate urban development, to undertake actions on seismic risk mitigation and to understand the damage pattern caused by a strong-motion event. The procedures for studying the seismic response and the seismic microzonation of an urban area are well established; nevertheless, some controversial points still exists and are discussed here. In this paper, the selection of a reference input motion, the construction of a subsoil model and the seismic response analysis procedures are discussed in detail, based on the authors’ experience in two Italian case histories: the seismic microzonation of the city of Benevento, which was a predictive study, and the simulation of seismic response and damage distribution in the village of San Giuliano di Puglia, which was a retrospective analysis. 相似文献
36.
F. Frontera A. Pisa G. Loffredo D. Pellicciotta V. Carassiti F. Evangelisti K. Andersen P. Courtois L. Amati E. Caroli T. Franceschini G. Landini S. Silvestri J. Stephen 《Experimental Astronomy》2005,20(1-3):241-251
A review of the HAXTEL project devoted to the development of a Laue lens telescope for hard X-/gamma-ray observation of the continuum spectra of celestial sources is presented. Main design properties, open issues, the status of the project and an example of multi-lens configuration with sensitivity expectations are discussed. 相似文献
37.
The aim of this paper is to investigate different aspects of the seasonal-to-interannual temperature variability in Eastern Patagonia, the southernmost area of South America, east of the Andes Cordillera. Homogenous regions of seasonal variability and the atmospheric circulation patterns associated with warm and cold conditions in each of them are described in this study. Relationships between temperature in Eastern Patagonia and that registered in other areas of southern South America are also addressed. Results show that the northern and southern areas of Eastern Patagonia have different temperature variability in summer and autumn whereas the temperature variability tends to be more homogeneous within the region during winter and spring. Warm (cold) conditions in the northern areas are associated with reinforced (weakened) westerlies in summer, winter and spring whereas northerly (southerly) advections of warm (cold) air toward the region produce such conditions in autumn. Temperature in the southern portion of Eastern Patagonia is affected by anticyclonic (cyclonic) anomalies that enhance (reduce) the incoming solar radiation and induce reinforced (weakened) westerlies promoting warm (cold) conditions in the region. Furthermore, cyclonic (anticyclonic) anomalies at subpolar latitudes hinder (favor) outbreaks of cold air increasing (decreasing) the temperature over areas of Eastern Patagonia. The circulation anomalies associated with warm (cold) conditions in Eastern Patagonia also promote cold (warm) conditions over areas of northern Argentina, Paraguay and southern Brazil. Consequently, a dipole of temperature is detected in southern South America with centers of opposite sign over these regions. 相似文献
38.
Elizabeth Bryan Claudia Ringler Barrack Okoba Jawoo Koo Mario Herrero Silvia Silvestri 《Climatic change》2013,118(2):151-165
Changes in the agriculture sector are essential to mitigate and adapt to climate change, meet growing food demands, and improve the livelihoods of poor smallholder producers. What agricultural strategies are needed to meet these challenges? To what extent are there synergies among these strategies? This paper examines these issues for smallholder producers in Kenya across several agroecological zones. Several practices emerge as triple wins, supporting climate adaptation, greenhouse gas mitigation, and profitability goals. In particular, integrated soil fertility management and improved livestock feeding are shown to provide multiple benefits across all agroecological zones examined. Triple wins of other agricultural practices are limited to specific agroecological zones. Irrigation and soil and water conservation, for example, are essential for adaptation, mitigation, and profitability in arid areas. The results suggest that agricultural investments targeted toward these triple-win strategies will have the greatest payoff in terms of increased resilience of farm and pastoralist households and global climate change mitigation. To reap the benefits of triple-win strategies will require that policymakers, researchers, and practitioners move away from isolated approaches focused on either adaptation or mitigation or rural income generation toward a more holistic assessment of joint strategies as well as their tradeoffs and synergies. 相似文献
39.
D. W.Kurtz S. D.Kawaler R. L.Riddle M. D.Reed † M. S.Cunha M.Wood N.Silvestri T. K.Watson N.Dolez P.Moskalik S.Zola E.Pallier J. A.Guzik T. S.Metcalfe A. S.Mukadam R. E.Nather D. E.Winget D. J.Sullivan T.Sullivan K.Sekiguchi X.Jiang R.Shobbrook B. N.Ashoka S.Seetha S.Joshi D.O'Donoghue G.Handler M.Mueller J. M.Gonzalez Perez J.-E.Solheim F.Johannessen A.Ulla S. O.Kepler A.Kanaan A.da Costa L.Fraga O.Giovannini J. M.Matthews 《Monthly notices of the Royal Astronomical Society》2002,330(3):57-61
HR 1217 is a prototypical rapidly oscillating Ap star that has presented a test to the theory of non-radial stellar pulsation. Prior observations showed a clear pattern of five modes with alternating frequency spacings of 33.3 and 34.6 μHz, with a sixth mode at a problematic spacing of 50.0 μHz (which equals 1.5×33.3 μHz) to the high-frequency side. Asymptotic pulsation theory allowed for a frequency spacing of 34 μHz, but Hipparcos observations rule out such a spacing. Theoretical calculations of magnetoacoustic modes in Ap stars by Cunha predicted that there should be a previously undetected mode 34 μHz higher than the main group, with a smaller spacing between it and the highest one. In this Letter, we present preliminary results from a multisite photometric campaign on the rapidly oscillating Ap star HR 1217 using the 'Whole Earth Telescope'. While a complete analysis of the data will appear in a later paper, one outstanding result from this run is the discovery of a newly detected frequency in the pulsation spectrum of this star, at the frequency predicted by Cunha. 相似文献
40.
Silvia Casu Cesare Cecchi-Pestellini Santi Aiello 《Monthly notices of the Royal Astronomical Society》2001,325(2):826-834
Dust grains respond to the physical and chemical conditions of the interstellar region in which they are embedded. The interaction produces an extinction curve which depends on the local environment and on the past history of the dust grains. In this work we present a theoretical study of the effects of radial variations of dust extinction properties on gas-phase chemistry in spherical core–halo clouds. We use observational constraints on the variation range of the extinction curve, and we analyse if the degree of dust environmental processing could be reflected by chemical signatures in the gas-phase molecular concentrations. The results of this work show that significant variations in the photodestruction rates and in the thermal profile of the cloud might induce chemical patterns otherwise excluded in the standard dense-cloud chemistry. Some discrepancies between observations and theoretical provisions are discussed in the light of the present results. 相似文献