Sorption and desorption of mercury(II) in saline and alkaline soils of Bahía Blanca, Argentina

The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (<1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO₃ solutions. Total Hg(II) concentrations ranged from 6.2 × 10^?8 to 6.3 × 10^?3 M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10^?8 to 1.1 × 10^?4 M, and (b) 6.4 × 10^?4 to 6.3 × 10^?3 M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH)₂ was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH)₂ in the interlayer of the interstratified clay minerals can be proposed. Hg(OH)₂ was partially desorbed by repeated equilibrations in 0.1 M NaNO₃ solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10^?5 M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10^?3 M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH)₂ was retained by adsorption on clay mineral surfaces.     

Virtual tools for volcanic crisis management, and evacuation decision support: applications to El Chichón volcano (Chiapas, México)

Decision making regarding massive evacuation of a population threatened by a probable volcanic eruption is a major problem in crisis management. Such a decision is general on the number of people to be evacuated, available resources and infrastructure, quantity and quality of the escape routes and shelters, and the economic, social and political costs involved in the operation, coupled with the updated information provided by scientists about the forecast of future activity and probable eruption scenarios. Knowing time-lapse between the evacuation decision-making time and the time in which the evacuation is completed is another critical issue that must be carefully considered in densely populated areas. In such areas, it is really important to estimate in advance this time-lapse, as the forecast must be released with enough time to complete all the evacuation process before the destructive manifestations of the eruption begin. In this context, evacuation planning is a crucial component of emergency management. It is common for Emergency Plans to include pre-established strategies. However, an evacuation procedure should be flexible, depending on the above-mentioned timing, and on the decisions, evacuation schemes, environmental characteristics and other factors. In this work, several hazard models such as a lava flow model based on a Monte Carlo algorithm, a pyroclastic density current based on energy cone model, a semi-empirical inversion model to estimate the thickness of ash deposits, and all available information about the El Chión volcano have been used to obtain the area that should be evacuated in case of an eruption. Then, multiple evacuation strategies at El Chichón volcano have been designed, considering not only the characteristics of the eruption forecast, but also environmental factors (e.g., weather conditions) and social factors (e.g., tourism and farming seasons). The variable scale evacuation model has been used to estimate the evacuation time. In the paper, those virtual tools are briefly described as well as the information obtained from the drill of 2009. In addition to the optimization of evacuation under variable conditions and situations, one of the main objectives of this work is to provide a reliable estimation of the mitigation action time, for an Emergency Plan.     

Bioavailability of different chemical forms of dissolved silica can affect marine diatom growth

In this study, we demonstrate that dissolved silica obtained from mineral (crystalline quartz), biogenic amorphous (diatomaceous earth) and artificial amorphous sources (Aerosil) influence the growth rate of two marine diatoms, Chaetoceros sp. and Skeletonema marinoi. Diatoms were reared in four different experimental conditions in artificial seawater containing either dissolved silica previously obtained through dissolution of the mineral crystalline quartz or two amorphous substrates, biogenic diatomaceous earth or artificial Aerosil silica. Sodium metasilicate was used as control. When the silica in the different media reached concentrations higher than 107 μm , particles were eliminated by filtration and the diatom cells were inoculated. Maximum cell density, growth and silica assimilation rates of both species in the presence of dissolved silica derived from crystalline quartz and metasilicate were higher than those obtained with the other silica sources. These results are discussed against the background of previous geochemical studies that have shown that silica–water interactions are strictly dependent on the silica polymorphs involved and on the ionic composition of the solution. Our results demonstrate that the soluble silicon compounds generated in seawater by crystalline sources are highly bioavailable compared with those generated by biogenic and amorphous materials. These findings are potentially of considerable ecological importance and may contribute to clarifying anomalous spatial and temporal distributions of siliceous organisms with respect to the presence of lithogenic or biogenic silica sources in marine environments.     

Simplified seismic fragility analysis of structures with two types of friction devices

This paper presents a method and results of seismic fragility estimation of frame structures with friction devices and with friction devices and restrictors. The seismic intensity parameter, defined as the mean value of the pseudovelocity spectrum in a specified periods band, is proved to allow the use of linear regression analysis of the response parameters of the considered non‐linear structures on seismic intensity. A simplified method of fragility estimation is proposed, based on the concept of ‘mean seismic excitation’ and linear regression of the seismic response parameters on seismic intensity parameter. The key risk contributors for the system with friction devices and for the system with friction devices and restrictors are identified on the basis of the fragility analysis, and recommendations for improvement of the seismic response of the respective systems are derived. The results of the fragility study show that when the initial ‘bare’ frame is retrofitted by rigidly connected bracings the effect is much lower than in the case of connecting the bracings by friction devices and especially by friction devices and restrictors. Copyright © 2000 John Wiley & Sons, Ltd.     

Le domaine Tariquide (arc de Gibraltar,Espagne et Maroc) : succession et hiatus de la sédimentation du Jurassique supérieur au Paléocène

The originality of the Malm–Cretaceous series of the Tariquides (Gibraltar arc), as compared to those of the Rifian–Betic ‘Dorsale’ (Alboran domain), and especially with the Penibetic (Iberia) domain, is emphasized. In the Los Pastores Group, near Algeciras, Upper Tithonian nodular limestones directly lie on the Dogger and are followed by Aptychus-bearing limestones (Late Berriasian to Barremian). In the Musa Group, Rif, radiolarites are followed by siliceous limestones (Kimmeridgian–Tithonian), then by karst and massflow breccias connected to a Berriasian tectonics, by Aptychus-bearing marly limestones, then by karst filled by Turonian limestones, and finally by Maastrichtian–Palaeocene polychrome pelites, whose micropalaeontological and mineral compositions (clay minerals, FeMn nodules) refer to a deep-sea, probably infra-CCD, sedimentation. To cite this article: M. Durand-Delga et al., C. R. Geoscience 337 (2005).     

Relationships of Agricultural Land Use to an Expanded Road Network within Tropical Forest Landscapes of Cameroon and Republic of the Congo

Road building in Congo Basin forests has increased due to expansion of commercial logging, with potential to expose intact forests to greater establishment of agriculture. We developed new knowledge of agriculture clearing sizes, spatial patterns, and relationships with roads in seven case study sites comprising 7,529 km². Using very high spatial resolution satellite imagery, we mapped roads and rivers, plus clearings for agriculture, settlements, and logging. Mapped clearings (N = 1,781) ranged in size from 0.008 ha to more than 300 ha; most were smallholder agriculture, with 64 percent ≤ 1 ha. Statistical tests of spatial pattern confirmed that agriculture occurred in an inhomogeneous-aggregated pattern, suggesting interactions with other landscape elements. Proximity analyses showed that 76 percent of clearings were within 1 km of a road or river. Thirty-five percent of agriculture clearings were within 1 km of main public roads built before 1990, compared to 17 percent for logging roads built after 2000. Less than 6 percent of agriculture clearings were within 1 km of logging roads with overgrown canopies, suggesting transient relationships. Results based on fine-scale data provide new empirical support for understanding the interactions between agriculture and roads in one of the remaining relatively intact forest areas of the Congo Basin.     

Detecting filaments in the ultra-high energy cosmic ray distribution

We propose and test new statistical tools to study the distribution of cosmic rays based on the use of the minimal spanning tree. The method described is particularly sensitive to filamentary structures, as those expected to arise from strong sources of charged cosmic rays which get deflected by intervening magnetic fields. We also test the method with data available from the AGASA and SUGAR surface detector arrays.     

Physically-based prediction of the maximum corner displacement magnification of one-storey eccentric systems

This paper gives a new insight into the linear dynamic behavior of one-storey eccentric systems, with particular attention devoted to provide a comprehensive physically-based formulation of the maximum corner displacement magnification, which involves three contributions (translational response, torsional response and their combination). It is shown that the largest magnifications, which mainly occur for the class of torsionally-flexible systems, are due to the translational contribution which is caused by the shift of the fundamental period of the eccentric system with respect to that of the equivalent not-eccentric system. A simplified method for the estimation of the maximum corner displacement under seismic excitation, based on the physical properties of the eccentric system, is finally proposed.     

Bronze Age paleohydrography of the southern Venetian Plain

The Bronze Age paleohydrography of the distal Adige and Po alluvial plain (northeastern Italy) is notable for its relations with protohistoric human activities in this area. This paper regards the stratigraphy and petrography of the Saline–Cona alluvial ridge, upon which the Saline, Sarzano, and Cantarana Bronze Age sites lie, and the petrography of Fratta alluvial ridge, upon which the Frattesina complex (Bronze–Iron Age) lies. Sand analyses indicate the Po River as the source for sediments underlying the alluvial ridge that runs through Fratta Polesine, Rovigo, Sarzano, and Cona. Radiometric ages indicate that the branch of the Saline–Cona ridge was formed by the Po River between the second half of the 3rd millennium B.C. and the end of 2nd millennium B.C. This ridge represents the maximum northward expansion of the Po alluvial system, through the same area of coastal plain crossed by the Adige and Brenta paleochannels. This paleohydrographic setting implies that fluvial connections between the Central Po Plain settlements, the Venetian Plain and Alps were relatively less complex in the Early and Middle Bronze Age than in the Late Bronze Age, when the terminal reach of the Po River was separated by the Adige River by hundreds of km² of swampy terrain. © 2009 Wiley Periodicals, Inc.