Bioavailability of different chemical forms of dissolved silica can affect marine diatom growth

In this study, we demonstrate that dissolved silica obtained from mineral (crystalline quartz), biogenic amorphous (diatomaceous earth) and artificial amorphous sources (Aerosil) influence the growth rate of two marine diatoms, Chaetoceros sp. and Skeletonema marinoi. Diatoms were reared in four different experimental conditions in artificial seawater containing either dissolved silica previously obtained through dissolution of the mineral crystalline quartz or two amorphous substrates, biogenic diatomaceous earth or artificial Aerosil silica. Sodium metasilicate was used as control. When the silica in the different media reached concentrations higher than 107 μm , particles were eliminated by filtration and the diatom cells were inoculated. Maximum cell density, growth and silica assimilation rates of both species in the presence of dissolved silica derived from crystalline quartz and metasilicate were higher than those obtained with the other silica sources. These results are discussed against the background of previous geochemical studies that have shown that silica–water interactions are strictly dependent on the silica polymorphs involved and on the ionic composition of the solution. Our results demonstrate that the soluble silicon compounds generated in seawater by crystalline sources are highly bioavailable compared with those generated by biogenic and amorphous materials. These findings are potentially of considerable ecological importance and may contribute to clarifying anomalous spatial and temporal distributions of siliceous organisms with respect to the presence of lithogenic or biogenic silica sources in marine environments.     

Sorption and desorption of mercury(II) in saline and alkaline soils of Bahía Blanca, Argentina

The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (<1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO₃ solutions. Total Hg(II) concentrations ranged from 6.2 × 10^?8 to 6.3 × 10^?3 M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10^?8 to 1.1 × 10^?4 M, and (b) 6.4 × 10^?4 to 6.3 × 10^?3 M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH)₂ was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH)₂ in the interlayer of the interstratified clay minerals can be proposed. Hg(OH)₂ was partially desorbed by repeated equilibrations in 0.1 M NaNO₃ solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10^?5 M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10^?3 M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH)₂ was retained by adsorption on clay mineral surfaces.     

How to assess landslide activity and intensity with Persistent Scatterer Interferometry (PSI): the PSI-based matrix approach

We provide a step-by-step analysis and discussion of the ‘PSI-based matrix approach’, a methodology employing ground deformation velocities derived through Persistent Scatterer Interferometry (PSI) for the assessment of the state of activity and intensity of extremely to very slow landslides. Two matrices based on PSI data are designed respectively for landslides already mapped in preexisting inventories and for newly identified phenomena. Conversely, a unique intensity scale is proposed indiscriminately for both. Major influencing factors of the approach are brought to light by the application in the 14 km² area of Verbicaro, in Northern Calabria (Italy). These include lack of PSI data within the landslide boundaries, temporal coverage of the available estimates, and need of field checks as well as the operative procedures to set the activity and intensity thresholds. For the area of Verbicaro, we exploit 1992–2011 PSI data from ERS1/2 and RADARSAT1/2 satellites, projecting them along the maximum slope directions. An activity threshold of ±5 mm/year is determined by applying the average projection factor of local slopes to the PSI data precision. The intensity threshold between extremely and very slow phenomena (16 mm/year) is reduced by ~20 % to account for temporal and spatial averages being applied to attribute representative velocities to each landslide. The methodology allows assessing the state of activity and the intensity for 13 of the 24 landslides premapped in the 2007 inventory and for two newly identified phenomena. Current limitations due to characteristics and spatial coverage of PSI data are critically tackled within the discussion, jointly with respective implications.     

Virtual tools for volcanic crisis management, and evacuation decision support: applications to El Chichón volcano (Chiapas, México)

Decision making regarding massive evacuation of a population threatened by a probable volcanic eruption is a major problem in crisis management. Such a decision is general on the number of people to be evacuated, available resources and infrastructure, quantity and quality of the escape routes and shelters, and the economic, social and political costs involved in the operation, coupled with the updated information provided by scientists about the forecast of future activity and probable eruption scenarios. Knowing time-lapse between the evacuation decision-making time and the time in which the evacuation is completed is another critical issue that must be carefully considered in densely populated areas. In such areas, it is really important to estimate in advance this time-lapse, as the forecast must be released with enough time to complete all the evacuation process before the destructive manifestations of the eruption begin. In this context, evacuation planning is a crucial component of emergency management. It is common for Emergency Plans to include pre-established strategies. However, an evacuation procedure should be flexible, depending on the above-mentioned timing, and on the decisions, evacuation schemes, environmental characteristics and other factors. In this work, several hazard models such as a lava flow model based on a Monte Carlo algorithm, a pyroclastic density current based on energy cone model, a semi-empirical inversion model to estimate the thickness of ash deposits, and all available information about the El Chión volcano have been used to obtain the area that should be evacuated in case of an eruption. Then, multiple evacuation strategies at El Chichón volcano have been designed, considering not only the characteristics of the eruption forecast, but also environmental factors (e.g., weather conditions) and social factors (e.g., tourism and farming seasons). The variable scale evacuation model has been used to estimate the evacuation time. In the paper, those virtual tools are briefly described as well as the information obtained from the drill of 2009. In addition to the optimization of evacuation under variable conditions and situations, one of the main objectives of this work is to provide a reliable estimation of the mitigation action time, for an Emergency Plan.     

The interplanetary magnetic field environment at Mercury's orbit

Mercury is exposed to the most dynamic heliospheric space environment of any planet in the solar system. The magnetosphere is particularly sensitive to variations in the interplanetary magnetic field (IMF), which control the intensity and geometry of the magnetospheric current systems that are the dominant source of uncertainty in determinations of the internal planetary magnetic field structure. The Magnetometer on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has made extensive magnetic field observations in the inner heliosphere over the heliocentric distances of Mercury's orbit, between 0.31 and 0.47 AU. In this paper, Magnetometer data from MESSENGER, obtained at rates of 2 and 20 vector samples per second, are used together with previous observations in the inner heliosphere by Helios and at Earth by the Advanced Composition Explorer, to study the characteristics of IMF variability at Mercury's orbit. Although the average IMF geometry and magnitude depend on heliocentric distance as predicted by Parker, the variability is large, comparable to the total field magnitude. Using models for the external current systems we evaluate the impact of the variability on the field near the planet and find that the large IMF fluctuations should produce variations of the magnetospheric field of up to 30% of the dipole field at 200 km altitude, corresponding to the planned periapsis of MESSENGER's orbit at Mercury. The IMF fluctuations in the frequency range are consistent with turbulence, whereas evidence for dissipation was observed for . The transition between the turbulent and dissipative regimes is indicated by a break in the power spectrum, and the frequency of this break point is proportional to the IMF magnitude.     

Ad hoc shared‐ride trip planning by mobile geosensor networks

Recent developments in miniaturization of computing devices, in location‐sensing technology and in ubiquitous short‐range wireless networks enable new types of social behaviour. This paper investigates one novel application of these technologies, ad hoc inner‐urban shared‐ride trip planning: Transportation clients such as pedestrians are seeking ad hoc shared rides from transportation hosts such as private automobiles, buses, taxi cabs or trains. While centralized trip planners are challenged by assigning clients and hosts in an ad hoc manner, in particular for non‐scheduled hosts, we consider the transportation network as a mobile geosensor network of agents that interact locally by short‐range communication and heuristic wayfinding strategies. This approach is not only fully scalable; we can also demonstrate that with short‐range communication, and hence, incomplete transportation network knowledge a system still can deliver near‐to‐optimal trips.     

Real-time flood forecasting by relating local stage and remote discharge

Abstract

The rating curve model (RCM) proposed by Moramarco and co-authors is modified here for flood forecasting purposes without using rainfall information. The RCM is a simple approach for discharge assessment at a river site of interest based on relating the local recorded stage and the remote discharge monitored at an upstream gauged river site located some distance away. The proposed RCM for real-time application (RCM-RT), involves only two parameters and can be used for river reaches where significant lateral flows occur. The forecast lead time depends on the mean wave travel time of the reach. The model is found to be accurate for a long reach of the Po River (northern Italy) and for two branches of the Tiber River (central Italy) characterized by different intermediate drainage areas and wave travel times. Moreover, the assessment of the forecast uncertainty coming from the model parameters is investigated by performing a Monte Carlo simulation. Finally, the model capability to accurately forecast the exceedence of fixed hydrometric thresholds is analysed.

Editor D. Koutsoyiannis; Associate editor C. Perrin     

Physically-based prediction of the maximum corner displacement magnification of one-storey eccentric systems

This paper gives a new insight into the linear dynamic behavior of one-storey eccentric systems, with particular attention devoted to provide a comprehensive physically-based formulation of the maximum corner displacement magnification, which involves three contributions (translational response, torsional response and their combination). It is shown that the largest magnifications, which mainly occur for the class of torsionally-flexible systems, are due to the translational contribution which is caused by the shift of the fundamental period of the eccentric system with respect to that of the equivalent not-eccentric system. A simplified method for the estimation of the maximum corner displacement under seismic excitation, based on the physical properties of the eccentric system, is finally proposed.     

A first estimation of tsunami hazard of the Pacific coast of Costa Rica from local and distant seismogenic sources

Ocean Dynamics - Costa Rica has been affected by several local and distant tsunamis in the past, but the historical information is scarce and incomplete. Its Pacific coast stretches for over a...     

B,V, and DDO photometric observations of red variable stars

Light curves of the red variables L₂ Puppis, R Carinae, and S Carinae in the region of the spectrum covered by theB, V, and DDO photometry are presented. The behavior of the DDO color indices and their meaning for this type of star are discussed. S Carinae shows a different behavior from the other two stars that seems to be due to a population effect.