A contribution to the reconstruction of Miocene seepage from authigenic carbonates of the northern Apennines (Italy)

Authigenic carbonates from outcrops of the northern Apennines consist of small and irregular lenses and exhibit numerous features indicative of cold-seep settings. Detailed petrographic, mineralogical and geochemical studies from two Miocene deposits are presented. The first carbonate outcrop, named Fosso Riconi, is located in the foredeep basin of the Apenninic chain, whereas the second deposit represents a satellite basin called Sarsetta. The stable isotope data from specific carbonate minerals show a wide range of values well known from other palaeoseeps of the Apennine Mountains. The majority of seep carbonates are formed by low-Mg calcite and ankerite. Those minerals have δ¹³C values between ?7 and ?23‰ V-PDB, suggesting variable amounts of carbonate derived from oxidized methane, seawater (dissolved inorganic carbon) and sedimentary organic matter. Dolomite samples have the lowest δ¹³C values (?30.8 to ?39.0‰ V-PDB), indicating methane as the main carbon source. The findings suggest an evolutionary formation of the seeps and development of authigenic carbonates influenced by the activity of chemosynthetic organisms, of which large lucinid clams are preserved. Bioirrigation by the clams controlled the sediment–water exchange, and is here considered as an explanation for the anomalous Mg content of the calcite. We hypothesize that the seep carbonates were formed during periods of active methane-rich seepage, whereas during periods of slow seepage carbonate formation was reduced. Despite different geological settings, the two examined deposits of Sarsetta and Fosso Riconi show similar features, suggesting that a common pattern of fluid circulation played a major role in carbonate formation at both seep sites.     

Neutron star surface emission: Beyond the dipole model

Recent Chandra and XMM-Newton observations of a number of X-ray “dim” pulsating neutron stars revealed quite unexpected features in the emission from these sources. Their soft thermal spectrum, believed to originate directly from the star surface, shows evidence for a phase-varying absorption line at some hundred eVs. The pulse modulation is relatively large (pulsed fractions in the range ～8–35% in amplitude), the pulse shape is often non-sinusoidal, and the hard X-ray color appears to be anti-correlated in phase with the total emission. Moreover, the prototype of this class, RX J0720.4-3125, has been found to undergo rather sensible changes both in its spectral and timing properties over a timescale of a few years. By modeling the light curves of two sources, RBS 1223 and RX J0720.4-3125, it has been found evidence for two hot regions located at a slightly non antipodal direction. All these new findings are difficult to reconcile with the standard picture of a cooling neutron star endowed with a purely dipolar magnetic field. Here we present more realistic models of surface emission, where the effects of different neutron star thermal and magnetic surface distributions are accounted for. We show how a star-centered field made of a dipolar and a quadrupolar component can influence the properties of the observed light curves and we present results that account self-consistently for toroidal and poloidal crustal field configurations.     

New estimations of precipitation and surface sublimation in East Antarctica from snow accumulation measurements

Surface mass balance (SMB) distribution and its temporal and spatial variability is an essential input parameter in mass balance studies. Different methods were used, compared and integrated (stake farms, ice cores, snow radar, surface morphology, remote sensing) at eight sites along a transect from Terra Nova Bay (TNB) to Dome C (DC) (East Antarctica), to provide detailed information on the SMB. Spatial variability measurements show that the measured maximum snow accumulation (SA) in a 15 km area is well correlated to firn temperature. Wind-driven sublimation processes, controlled by the surface slope in the wind direction, have a huge impact (up to 85% of snow precipitation) on SMB and are significant in terms of past, present and future SMB evaluations. The snow redistribution process is local and has a strong impact on the annual variability of accumulation. The spatial variability of SMB at the kilometre scale is one order of magnitude higher than its temporal variability (20–30%) at the centennial time scale. This high spatial variability is due to wind-driven sublimation. Compared with our SMB calculations, previous compilations generally over-estimate SMB, up to 65% in some areas.     

Development of agroclimatic zoning model to delimit the potential growing areas for macaw palm (Acrocomia aculeata)

Theoretical and Applied Climatology - The growing biodiesel production requires the use of new technologies and alternative feedstocks to maintain the growing demand of this biofuel. The macaw...     

Age and geotectonic setting of Late Neoproterozoic juvenile mafic gneisses and associated paragneisses from the Ribeira belt (SE Brazil) based on geochemistry and Sm–Nd data — Implications on Gondwana assembly

Mafic gneisses and associated paragneisses from the Cabo Frio Tectonic Domain in the southeastern part of the Ribeira Belt, along the coast of Rio de Janeiro State in southeast Brazil, were subjected to a geochemical and Sm–Nd isotope study. Four lithotypes are distinguished: aluminous paragneisses (mainly sillimanite–kyanite–garnet–biotite gneiss), calcsilicate lenses, quartzo–feldspathic metasedimentary gneisses and mafic–ultramafic lenses. The whole-rock major and trace, including rare earth element distributions in the mafic–ultramafic intercalations indicate that derivation from subalkaline basalt/gabbro of tholeiitic affinity with E-MORB signature from a non-subduction environment. These mafic rocks have positive ε_Nd(t) and T_DM of 1.1 Ga. The metasedimentary rocks have negative ε_Nd(t) and T_DM of 1.7 Ga. A Sm–Nd whole rock isochron of mafic rocks yielded an age of 604 ± 38 Ma for the crystallization. This matches with the age of some detrital zircon grains from the paragneisses. The depositional basin, named Buzios–Palmital, was active at least until 620 Ma (age of the youngest detrital zircon) and was subsequently deformed and metamorphosed at ca. 525 Ma (age of metamorphic zircons) during the Buzios Orogeny. It is interpreted as a back arc basin with relation to the 630 Ma magmatic arc of the Oriental Terrane in the Ribeira Belt to the NW. However, after 600 Ma, the Buzios–Palmital basin changed to an active margin setting because the arc collided with the continental margin and the subduction shifted to the back arc environment. By 610 Ma, most of the Brasiliano belts registered collisional events related to multiple convergent blocks. The stress fields and paleocontinent shapes would have allowed the occurrence of extensional areas with not only sedimentary deposition but also ocean floor spreading. Its remnants are preserved in this Brazilian coastal region as an ancient suture, reworked intensively during the Mesozoic rifting events. The reconnaissance of Late Neoproterozoic basins in the Brasiliano–Pan-African belts is of major importance to partially unravel the final amalgamation events of SW Gondwana. Considering that the Buzios–Palmital basin rock units are mostly covered by the marginal Atlantic basins, it is possible that other evidence could be preserved in the coastal regions of SW-Africa and SE-South America.     

Rainfall thresholds for the possible landslide occurrence in Sicily (Southern Italy) based on the automatic reconstruction of rainfall events

Review of the literature on the reconstruction of the rainfall responsible for slope failures reveals that criteria for the identification of rainfall events are lacking or somewhat subjective. To overcome this problem, we developed an algorithm for the objective and reproducible reconstruction of rainfall events and of rainfall conditions responsible for landslides. The algorithm consists of three distinct modules for (i) the reconstruction of distinct rainfall events, in terms of duration (D, in h) and cumulated event rainfall (E, in mm), (ii) the identification of multiple ED rainfall conditions responsible for the documented landslides, and (iii) the definition of critical rainfall thresholds for possible landslide occurrences. The algorithm uses pre-defined parameters to account for different seasonal and climatic settings. We applied the algorithm in Sicily, southern Italy, using rainfall measurements obtained from a network of 169 rain gauges, and information on 229 rainfall-induced landslides occurred between July 2002 and December 2012. The algorithm identified 29,270 rainfall events and reconstructed 472 ED rainfall conditions as possible triggers of the observed landslides. The algorithm exploited the multiple rainfall conditions to define objective and reproducible empirical rainfall thresholds for the possible initiation of landslide in Sicily. The calculated thresholds may be implemented in an operational early warning system for shallow landslide forecasting.     

Identifying landslide preconditions in Swedish quick clays—insights from integration of surface geophysical,core sample- and downhole property measurements

Quick-clay landslides are a serious geohazard in Canada, Norway and Sweden. Identification and mapping of quick clays are essential endeavours because the damage caused by an individual landslide can be large and costly, with potentially fatal consequences. We collected geophysical borehole and soil core data from an area prone to quick-clay landslides in southwestern Sweden. Methodologies included in situ and laboratory measurements, providing information about natural gamma radiation, sonic velocities, electrical conductivity, pH, physical grain size, elemental and mineral composition, magnetic properties, cation exchange capacity and fossil content. A stratigraphic thickness of almost 60 m enables us to study quick clays and their host environment in Sweden at unusually high resolution. Results identify the origin and location of reflections in nearby seismic lines and assign physico-chemical properties to the geological units present in the area. We show that coarse-grained layers are sandwiched between marine clays (some of which are quick clays). These layers function as a conduit for relatively fresh water that infiltrates the marine clays and chemically destabilizes them by leaching out their salts. The salinity distribution in the boreholes indicate that the groundwater movement is downwards, through the coarse-grained layer and towards the Göta river. The presence of these materials is important for the development of quick clays, although not a prerequisite. With the help of surface geophysical methods, the location of the coarse-grained layers can be known faster and more economically, which could be relevant for studying the potential for quick-clay landslide occurrence over large areas.     

Measurements and modelling of the advection of suspended sediment in the swash zone by solitary waves

Novel laboratory experiments and numerical modelling have been performed to study the advection scales of suspended sediment in the swash zone. An experiment was designed specifically to measure only the sediment picked up seaward of the swash zone and during bore collapse. The advection scales and settling of this sediment were measured during the uprush along a rigid sediment-free beach face by a sediment trap located at varying cross-shore positions. Measurements were made using a number of repeated solitary broken waves or bores. Approximately 25% of the pre-suspended sediment picked up by the bores reaches the mid-swash zone (50% of the horizontal run-up distance), indicating the importance of the sediment advection in the lower swash zone. The pre-suspended sediment is sourced from a region seaward of the shoreline (still water line) which has a width of about 20% of the run-up distance. An Eulerian–Lagrangian numerical model is used to model the advection scales of the suspended sediment. The model resolves the hydrodynamics by solving the non-linear shallow water equations in an Eulerian framework and then solves the advection–diffusion equation for turbulence and suspended sediment in a Lagrangian framework. The model provides good estimates of the measured mass and distribution of sediment advected up the beach face. The results suggest that the correct modelling of turbulence generation prior to and during bore collapse and the advection of the turbulent kinetic energy into the lower swash is important in resolving the contribution of pre-suspended sediment to the net sediment transport in the swash zone.