On magma fragmentation by conduit shear stress: Evidence from the Kos Plateau Tuff,Aegean Volcanic Arc

Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.     

Chronology building using objective identification of annual signals in trace element profiles of stalagmites

Determination of annual lamination provides important additional constraints to radiometric dates on speleothems, both for dating the duration of specific growth intervals and optimizing growth models. In the absence of visible laminae, however, speleothem age models are reliant upon curve fitting through discretely dated points and are therefore inherently more uncertain than annual chronologies from laminae. Given that the impact of seasonality on speleothems is expected to be strong enough to generate an annual pulse in trace element chemistry regardless of whether or not visible or fluorescent growth laminae are visible, we demonstrate the potential for deriving high-resolution stalagmite chronologies from non-laminated samples using annual chemical variations in stalagmites from two Alpine caves (Obir, Austria and Ernesto, NE Italy). Trace element data were obtained by ion microprobe analyses for H, P, Mg, Na, Sr and Ba and the annual signal was sought using spectral and wavelet analysis. An automated chemical peak-counting software tool was developed in MATLAB^©. It counts significant annual peaks using criteria of minimum amplitude in relation to the local standard deviation of signal variation and minimum separation between peaks determined by the thickness of the preceding layers. Verification of the tool using visibly laminated samples suggests the software is a reliable and accurate method of chronology building, with hit ratios greater than 0.93 and less than 0.75% false alarm occurrences. Used in conjunction with other dating methods such as radiocarbon, U–Th and sulphur peak dating, the automated chemical laminae chronology-building approach provides a more meaningful alternative to simple age-depth curve fitting for non-laminated samples.     

Quantum Instability of Magnetized Stellar Objects

The equations of state for degenerate electron and neutron gases are studied in the presence of magnetic fields. After including quantum effects in the investigation of the structural properties of these systems, it is found that some hypermagnetized stars can be unstable according to the criterion of stability of pressures. Highly magnetized white dwarfs should collapse producing a supernova type Ia, while superstrong magnetized neutron stars cannot stand their own magnetic field and must implode, too. A comparison of our results with a set of the available observational data of some compact stars is also presented, and the agreement between this theory and observations is verified.     

Using geomagnetic indices to forecast the next sunspot maximum

The Babcock solar dynamo model and known interactions of the interplanetary magnetic field with the earth's magnetosphere are used to explain the relations found between geomagnetic indices at solar minimum and the sunspot number at the following solar maximum. We augment the work of Kane (1987) by updating his method of analysis, including recent smoothed aa and A_P indices. We predict a smoothed maximum sunspot number of 163±40 to peak in October 1990±9 months for solar cycle 22. This value is close to the Schatten and Sofia (1987) predicted value of 170±25, using more direct solar indicators.Now at Dept. of Astronomy, Univ. of Washington     

Gravity and seismicity analyses of the El Chichon volcano,Chiapas, Mexico

Subduction induced compressional stress, lateral displacement faults probably linked to the NW extension of the Polochic-Motagua fault system, and local magma emplacement create a complex geological setting for the El Chichon volcano.Gravity analysis reveals that the principal structures in the area correspond to synclines and anticlines. Downward continuation of the gravity field suggests the presence of magma emplacement SE of the volcano. This magmatic emplacement appears to be the principal cause of the truncation of the syncline in which the volcano lies.Analyses of earthquakes occurring after eruptions show that the vertical distribution of events is confined to a roughly cylindrical zone which correlates well with the region of magmatic emplacement inferred from the gravity analysis.Even though more than 350 km separate the volcano from the Middle American trench, the compressional stress regime reported for the area may correlate with subduction stress (N30°E). However, the strike direction for the principal faults in the zone, N60°W, permits us to postulate that the NW extension of the Polochic-Motagua fault system is implicated in the local tectonics of the El Chichon area.     

A local landscape in transition between production and consumption goals: can new management arrangements preserve the local landscape character?

Around towns in the Alentejo region, the landscape is dominated by a characteristic agricultural small-scale mosaic. These areas are central in the region landscape character – even if the large-scale latifundia landscape of the extensive silvo-pastoral systems is most commonly associated with the region. In the last two decades, these parcels became extremely attractive for new comers, who settle in the rural context as residents, week-end visitors, being often also lifestyle farmers. The paper presents a case study landscape, in Montemor-o-Novo, a small town 100 km from Lisbon, highly subject to the pressure for consumption uses, by urban users. The study shows that the new owners, even if they have settled in the area due to the tranquility and social bindings of the rural, end up doing farming, with new or reshaped production objectives, markets and models, but at the same time maintaining the traditional farm systems. Thus, the landscape character is maintained, so far. Nevertheless, the role of these neo-rurals and lifestyle farmers is still an unseen role, both by the agriculture and the planning sectors. And thus the question is, whether the combination of actors and land management drivers will continue maintaining the landscape in the future.     

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.