PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.     

Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.     

2060 Chiron back to a minimum of brightness

The results of photometric observations of comet/asteroid 2060 Chiron at the Observatório do Pico dos Dias (Brazil-OPD) and the Observatoire de Haute-Provence (France-OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060 Chiron brightness from its peak values of 1988–1991. The absolute magnitude, H_v, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983–1985. The slope parameter G is found to be G = 0.71 ± 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object.     

Sediment Organic Carbon in Todos Santos Bay, Baja California, Mexico

Sediment grain size and organic carbon (OC) data collected over the past 50 years, together with δ¹³C values of OC in recently collected samples, were analyzed to improve understanding of sediment OC distribution and abundance in Todos Santos Bay. Sediments in the submarine canyon at the mouth of the bay and in quiet-water locations along the shore are fine grained, high in OC, and have generally low δ¹³C values; sediments in high-energy environments are low in OC and have high δ¹³C values. A bivariate isotopic mixing model indicates that none of the sediments contain >50% terrigenous OC (average ~30%), and that the terrigenous OC content of the sediments is a small proportion of the OC content of local soils. Sediment OC composition is apparently controlled by energy-related sorting and deposition, oxidation of much of the original terrigenous OC, and replacement of some terrigenous OC by marine OC.     

Seismic driven probabilistic classification of reservoir facies for static reservoir modelling: a case history in the Barents Sea

In this paper we present a case history of seismic reservoir characterization where we estimate the probability of facies from seismic data and simulate a set of reservoir models honouring seismically‐derived probabilistic information. In appraisal and development phases, seismic data have a key role in reservoir characterization and static reservoir modelling, as in most of the cases seismic data are the only information available far away from the wells. However seismic data do not provide any direct measurements of reservoir properties, which have then to be estimated as a solution of a joint inverse problem. For this reason, we show the application of a complete workflow for static reservoir modelling where seismic data are integrated to derive probability volumes of facies and reservoir properties to condition reservoir geostatistical simulations. The studied case is a clastic reservoir in the Barents Sea, where a complete data set of well logs from five wells and a set of partial‐stacked seismic data are available. The multi‐property workflow is based on seismic inversion, petrophysics and rock physics modelling. In particular, log‐facies are defined on the basis of sedimentological information, petrophysical properties and also their elastic response. The link between petrophysical and elastic attributes is preserved by introducing a rock‐physics model in the inversion methodology. Finally, the uncertainty in the reservoir model is represented by multiple geostatistical realizations. The main result of this workflow is a set of facies realizations and associated rock properties that honour, within a fixed tolerance, seismic and well log data and assess the uncertainty associated with reservoir modelling.     

Analytical study of the energy rate balance equation for the magnetospheric storm-ring current

We present some results of the analytical integration of the energy rate balance equation, assuming that the input energy rate is proportional to the azimuthal interplanetary electric field, E_y, and can be described by simple rectangular or triangular functions, as approximations to the frequently observed shapes of E_y, especially during the passage of magnetic clouds. The input function is also parametrized by a reconnection-transfer efficiency factor (which is assumed to vary between 0.1 and 1). Our aim is to solve the balance equation and derive values for the decay parameter compatible with the observed Dst peak values. To facilitate the analytical integration we assume a constant value for through the main phase of the storm. The model is tested for two isolated and well-monitored intense storms. For these storms the analytical results are compared to those obtained by the numerical integration of the balance equation, based on the interplanetary data collected by the ISEE-3 satellite, with the values parametrized close to those obtained by the analytical study. From the best fit between this numerical integration and the observed Dst the most appropriate values of are then determined. Although we specifically focus on the main phase of the storms, this numerical integration has been also extended to the recovery phase by an independent adjust. The results of the best fit for the recovery phase show that the values of may differ drastically from those corresponding to the main phase. The values of the decay parameter for the main phase of each event, _m, are found to be very sensitive to the adopted efficiency factor, , decreasing as this factor increases. For the recovery phase, which is characterized by very low values of the power input, the response function becomes almost independent of the value of and the resulting values for the decay time parameter, _r, do not vary greatly as varies. As a consequence, the relative values of between the main and the recovery phase, _m/_r, can be greater or smaller than one as varies from 0.1 to 1.     

Dust-induced chemical differentiation in dense regions

Dust grains respond to the physical and chemical conditions of the interstellar region in which they are embedded. The interaction produces an extinction curve which depends on the local environment and on the past history of the dust grains. In this work we present a theoretical study of the effects of radial variations of dust extinction properties on gas-phase chemistry in spherical core–halo clouds. We use observational constraints on the variation range of the extinction curve, and we analyse if the degree of dust environmental processing could be reflected by chemical signatures in the gas-phase molecular concentrations. The results of this work show that significant variations in the photodestruction rates and in the thermal profile of the cloud might induce chemical patterns otherwise excluded in the standard dense-cloud chemistry. Some discrepancies between observations and theoretical provisions are discussed in the light of the present results.     

On magma fragmentation by conduit shear stress: Evidence from the Kos Plateau Tuff,Aegean Volcanic Arc

Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.     

用于中阿合作的卫星激光测距(SLR)系统的现状和未来

简要介绍了用于中国科学院国家天文台与阿根廷San Juan大学合作观测与研究的一个高精度卫星激光测距(SLR)系统.该望远镜口径为60cm的SLR系统由中国研制,于2005年秋被运往阿根廷,安装在阿根廷国立San Juan大学天文台,San Juan大学建立了观测室.准备了工作条件.该系统于2006年2月底完成调试并开始运行.在过去的两年阃,该系统保持了良好的工作状态,由于San Juan具有良好的天气条件,该系统取得了丰富的高精度观测资料.国际激光测距服务认为该仪器的工作对国际激光测距系统是重要的,希望对其增加白天测距的功能.文章也简单介绍了该SLR站未来升级改造和发展的计划.