Transport and exchange of U-series nuclides between suspended material,dissolved load and colloids in rivers draining basaltic terrains

This study presents uranium and thorium concentrations and activity ratios for all riverine phases (bedload, suspended load, dissolved load and colloids) from basaltic terrains in Iceland and the Azores. Small basaltic islands, such as these, are thought to account for ~ 25% of CO₂ consumed by global silicate weathering, and for ~ 45% of the flux of suspended material to the oceans. These data indicate that [U] and [Th] in the dissolved and colloidal fractions are strongly controlled by pH, and to a much lesser extent by levels of dissolved organic carbon (which are low in these environments). At high pH, basalt glass dissolution is enhanced, and secondary mineral formation (e.g. Fe-oxyhydroxides and allophane) is suppressed, resulting in high dissolved [U], and low colloidal [U] and [Th], indicating a direct chemical weathering control on elemental abundances. When the dissolved (²³⁴U/²³⁸U) activity ratio is >~1.3 (i.e. when physical weathering, groundwater contribution or soil formation are high), there is little isotope exchange between dissolved and colloidal fractions. At lower activity ratios, the dissolved load and colloids have indistinguishable activity ratios, suggesting that when chemical weathering rates are high, secondary clay formation is also high, and colloids rapidly adsorb dissolved U. Many of the suspended sediment samples have (²³⁴U/²³⁸U) activity ratios of > 1, which suggests that uptake of U onto the suspended load is important. Identical (²³⁰Th/²³²Th) in suspended, dissolved and colloidal samples suggests that Th, like U, is exchanged or sorbed rapidly between all riverine phases. This particle-reactivity, combined with poorly constrained contributions from groundwater and hydrothermal water, and short-term variations in input to soils (volcanic and glacial), suggests that U-series nuclides in riverine material from such basaltic terrains are unlikely to reflect steady state erosion processes.     

Sinking ships: conservation options for endemic taxa threatened by sea level rise

Low-elevation islands face threats from sea level rise (SLR) and increased storm intensity. Evidence of endangered species?? population declines and shifts in vegetation communities are already underway in the Florida Keys. SLR predictions indicate large areas of these habitats may be eliminated in the next century. Using the Florida Keys as a model system, we present a process for evaluating conservation options for rare and endemic taxa. Considering species characteristics and habitat, we assess central issues that influence conservation options. We contrast traditional and controversial options for two animal and two plant species giving special emphasis to perceptions of ecological risk and safety from SLR and suggest courses of action. Multiple strategies will be required to spread extinction risk and will be effective for different time periods. Global climate change presents an uncertain, perhaps no-analog future that will challenge land managers and practitioners to re-evaluate equilibrium-state-conceived laws and policies not only for these taxa, but for many facing similar threats. To embrace conservation in a changing world will require a new dialogue that includes controversial ideas, a review of existing laws and policies, and preparation for the oncoming change.     

Discrimination of TiO<Subscript>2</Subscript> polymorphs in sedimentary and metamorphic rocks

Investigation by Raman spectroscopy of samples from different geological settings shows that the occurrence of TiO₂ polymorphs other than rutile can hardly be predicted, and furthermore, the occurrence of anatase is more widespread than previously thought. Metamorphic pressure and temperature, together with whole rock chemistry, control the occurrence of anatase, whereas variation of mineral assemblage characteristics and/or fluid occurrence or composition takes influence on anatase trace element characteristics and re-equilibration of relict rutiles. Evaluation of trace element contents obtained by electron microprobe in anatase, brookite, and rutile shows that these vary significantly between the three TiO₂ phases. Therefore, on the one hand, an appropriation to source rock type according to Nb and Cr contents, but as well application of thermometry on the basis of Zr contents, would lead to erroneous results if no phase specification is done beforehand. For the elements Cr, V, Fe, and Nb, variation between the polymorphs is systematic and can be used for discrimination on the basis of a linear discriminant analysis. Using phase group means and coefficients of linear discriminants obtained from a compilation of analyses from samples with well-defined phase information together with prior probabilities of groupings from a natural sample compilation, one is able to calculate phase grouping probabilities of any TiO₂ analysis containing at least the critical elements Cr, V, Fe, and Nb. An application of this calculation shows that for the appropriation to the phase rutile, a correct-classification rate of 99.5% is obtained. Hence, phase specification by trace elements proves to be a valuable tool besides Raman spectroscopy.     

Preconditioning effects of intermittent stream flow on leaf litter decomposition

Autumnal input of leaf litter is a pivotal energy source in most headwater streams. In temporary streams, however, water stress may lead to a seasonal shift in leaf abscission. Leaves accumulate at the surface of the dry streambed or in residual pools and are subject to physicochemical preconditioning before decomposition starts after flow recovery. In this study, we experimentally tested the effect of photodegradation on sunlit streambeds and anaerobic fermentation in anoxic pools on leaf decomposition during the subsequent flowing phase. To mimic field preconditioning, we exposed Populus tremula leaves to UV–VIS irradiation and wet-anoxic conditions in the laboratory. Subsequently, we quantified leaf mass loss of preconditioned leaves and the associated decomposer community in five low-order temporary streams using coarse and fine mesh litter bags. On average, mass loss after approximately 45 days was 4 and 7% lower when leaves were preconditioned by irradiation and anoxic conditions, respectively. We found a lower chemical quality and lower ergosterol content (a proxy for living fungal biomass) in leaves from the anoxic preconditioning, but no effects on macroinvertebrate assemblages were detected for any preconditioning treatment. Overall, results from this study suggest a reduced processing efficiency of organic matter in temporary streams due to preconditioning during intermittence of flow leading to reduced substrate quality and repressed decomposer activity. These preconditioning effects may become more relevant in the future given the expected worldwide increase in the geographical extent of intermittent flow as a consequence of global change.     

Dynamics of arsenic adsorption in the targeted arsenic-safe aquifers in Matlab, south-eastern Bangladesh: Insight from experimental studies

Targeting shallow low-As aquifers based on sediment colour may be a viable solution for supplying As-safe drinking water to rural communities in some regions of Bangladesh and West Bengal in India. The sustainability of this solution with regard to the long-term risk of As-safe oxidized aquifers becoming enriched with As needs to be assessed. This study focuses on the adsorption behaviour of shallow oxidized sediments from Matlab Region, Bangladesh, and their capacity to attenuate As if cross-contamination of the oxidized aquifers occurs. Water quality analyses of samples collected from 20 tube-wells in the region indicate that while there may be some seasonal variability, the groundwater chemistry in the reduced and oxidized aquifers was relatively stable from 2004 to 2009. Although sediment extractions indicate a relatively low amount of As in the oxidized sediments, below 2.5 mg kg⁻¹, batch isotherm experiments show that the sediments have a high capacity to adsorb As. Simulations using a surface complexation model that considers adsorption to amorphous Fe(III) oxide minerals only, under-predict the experimental isotherms. This suggests that a large proportion of the adsorption sites in the oxidized sediments may be associated with crystalline Fe(III) oxides, Mn(IV) and Al(III) oxides, and clay minerals. Replicate breakthrough column experiments conducted with lactose added to the influent solution demonstrate that the high adsorption capacity of the oxidized sediments may be reduced if water drawn down into the oxidized aquifers contains high levels of electron donors such as reactive dissolved organic C.     

Cosmogenic <Superscript>10</Superscript>Be-derived denudation rates of the Eastern and Southern European Alps

Denudation rates from cosmogenic ¹⁰Be measured in quartz from recent river sediment have previously been used in the Central Alps to argue that rock uplift occurs through isostatic response to erosion in the absence of ongoing convergence. We present new basin-averaged denudation rates from large rivers in the Eastern and Southern European Alps together with a detailed topographic analysis in order to infer the forces driving erosion. Denudation rates in the Eastern and Southern Alps of 170–1,400 mm ky⁻¹ are within a similar range to those in the Central Alps for similar lithologies. However, these denudation rates vary considerably with lithology, and their variability generally increases with steeper landscapes, where correlations with topographic metrics also become poorer. Tertiary igneous rocks are associated with steep hillslopes and channels and low denudation rates, whereas pre-Alpine gneisses usually exhibit steep hillslopes and higher denudation rates. Molasse, flysch, and schists display lower mean basin slopes and channel gradients, and, despite their high erodibility, low erosion rates. Exceptionally low denudation rates are also measured in Permian rhyolite, which has high mean basin slopes. We invoke geomorphic inheritance as a major factor controlling erosion, such that large erosive glaciers in the late Quaternary cold periods were more effective in priming landscapes in the Central Alps for erosion than in the interior Eastern Alps. However, the difference in tectonic evolution of the Eastern and Central Alps potentially adds to differences in their geomorphic response; their deep structures differ significantly and, unlike the Central Alps, the Eastern Alps are affected by ongoing tectonic influx due to the slow motion and rotation of Adria. The result is a complex pattern of high mountain erosion in the Eastern Alps, which has evolved from one confined to the narrow belt of the Tauern Window in late Tertiary time to one affecting the entire underthrust basement, orogenic lid, and parts of the Southern Alps today.     

Polyphase structural evolution of the southwestern Argentine Precordillera

The western and southwestern parts of the Argentine Precordillera display complex geometries which are not consistent with those of a typical high-level fold-and-thrust belt. They are the result of a polyphase structural evolution which spans the Early Paleozoic to Late Tertiary period. After an Early Paleozoic folding and shearing event under a greenschist facies metamorphism, uplift, erosion, and deposition of Late Carboniferous to Early Permian clastics were accompanied by extensional faulting. This was followed by a Permian folding and faulting event which led to a partial inversion of the Late Carboniferous-Early Permian graben fill. Permian to Triassic crustal extension was combined with block faulting and the deposition of a thick volcanic sequence. The subsequent Late Tertiary crustal shortening partly reactivated older fault lines. Excluding folds, a few thrusts, and reverse faults, the crustal shortening within the older blocks was accommodated by a dominant sinistral strike-slip faulting under a W-E compressive regime. Above a major décollement, the entire sequence of faulted and folded blocks was carried from west to east towards its present position. The regional situation indicates that this southern part of the orogen was transferred further to the east with respect to the central thin-skinned parts. The movements are interpreted to be related to an important thrust fault which obliquely cuts through the fold-and-thrust belt.     

Late Proterozoic Patsy Springs Canyon,Adelaide Geosyncline: submarine or subaerial origin?

A significant aspect of Late Proterozoic sedimentation in the Adelaide Geosyncline, South Australia, is the presence of kilometre-deep erosional incisions which have been termed canyons. These structures were formerly described to be of submarine origin, cut and filled in an inferred basin-slope setting by subaqueous processes. Subsequent detailed research, particularly on a specific incision known as Patsy Springs Canyon, indicates that sedimentary structures within some of the canyon-filling sediments are indicative of deposition above fair weather wave base. In addition, an unusual carbonate unit, which is observed to veneer upper portions of canyon shoulders and to contribute to carbonate breccias interbedded with canyon-fill, has a stable isotope signature which may imply a non-marine origin. The presence of the carbonate veneer, where it is in situ, suggests that at least upper portions of the canyons could have been emergent during the canyon-filling phase. Considering these observations, and combining them with regional stratigraphical relationships, an alternative model for canyon genesis is proposed involving subaerial erosion and subsequent filling by coastal onlap. Such a model requires base-level changes of the order of 1 km, in order to account for observed canyon cutting and filling. Vertical movements associated with halokinesis, or thermally-induced uplift of the order of 1 km, could have resulted in the observed erosional events. Alternatively, a Messinian-style evaporitic lowering of base-level is currently receiving serious attention. With present knowledge this mechanism most satisfactorily explains all observations.     

Human impact on the forests of Bermuda: the decline of endemic cedar and palmetto since 1609, recorded in the Holocene pollen record of Devonshire Marsh

The wreck of the Sea Venture on Bermuda reefs in 1609 initiated continuous habitation by humans on these islands. Colonization brought significant changes to the native and endemic flora of Bermuda. Original floral diversity was low, due to the effects of isolation and lack of previous anthropogenic influences. Two dominant endemic components of the flora, Bermuda cedar (Juniperus bermudiana) and Bermuda palmetto (Sabal bermudana), were extensively utilized by the colonists. Cedar was used for housing, furniture, shipbuilding and export, while the palmetto was used for roof thatch, basketry, food and drink. Exploitation of these species occurred to such extent that the General Laws of Bermuda included resolutions protecting them as early as 1622. Later, in the period between 1946 and 1951, two accidentally introduced scale insects eliminated 95% of the existing cedar population.While the flora and geography of upland habitats on Bermuda have been drastically modified by humans, the peat marsh basins have remained relatively unaffected. From the peats of one of these, Devonshire Marsh, a 9-m core was extracted for pollen analysis and to evaluate the potential for further study. The pollen record below 1.6 m indicated very little change in the native and endemic flora of Bermuda, but above that depth statistically significant changes in the relative abundances of pollen of Bermuda cedar and Bermuda palmetto are noted. Relative abundances of both species decreases significantly above this depth. This decrease is interpreted to represent the arrival of colonists and their impact on the cedar and palmetto populations. A second decrease in relative abundance of Bermuda cedar is recorded above 0.7 m. This reflects the scale infestation and decimation of the remaining cedar population. Coincident with decreases in cedar and palmetto are increases in relative abundance of Poaceae and Asteraceae, indicative of cleared land and the spread of weedy taxa. A radiocarbon date of 520±70 yr BP at a depth of 1.7 m and major changes in relative abundance of palynomorphs in proximity to the marsh surface allows their interpretation as a record of human impact on the endemic flora of Bermuda.This is the 19th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.