Mass-dependent fractionation of quadruple stable sulfur isotope system as a new tracer of sulfur biogeochemical cycles

Sulfur isotope studies of post-Archean terrestrial materials have focused on the ratio ³⁴S/³²S because additional isotopes, ³³S and ³⁶S, were thought to carry little information beyond the well-known mass-dependent relationship among multiple-isotope ratios. We report high-precision analyses of Δ³³S and Δ³⁶S values, defined as deviations of ³³S and ³⁶S from ideal mass-dependent relationships, for international reference materials and sedimentary sulfides of Phanerozoic age by using a fluorination technique with a dual-inlet isotope ratio mass spectrometer. Measured variations in Δ³³S and Δ³⁶S are explained as resulting from processes involve branching reactions (two or more reservoirs formed) or mixing. Irreversible processes in closed systems (Rayleigh distillation) amplify the isotope effect. We outline how this new isotope proxy can be used to gain new insights into fundamental aspects of the sulfur biogeochemical cycle, including additional constraints on seawater sulfate budget and processes in sedimentary sulfide formation. The isotope systematics discussed here cannot explain the much larger variation of Δ³³S and Δ³⁶S observed in Archean rock records. Furthermore, Phanerozoic samples we have studied show a characteristic Δ³³S and Δ³⁶S relationship that differs from those measured in Archean rocks and laboratory photolysis experiments. Thus, high precision analysis of Δ³³S and Δ³⁶S can be used to distinguish small non-zero Δ³³S and Δ³⁶S produced by mass-dependent processes from those produced by mass-independent processes in Archean rocks and extraterrestrial materials.     

Triaxial stress state deep in orogenic belts: an example from Turkey

A rare metachert pebble containing amphibole grains with microboudin structures in a wide range of orientations provides an opportunity to perform stress analysis in two orthogonal orientations on the foliation surface. The sample was analysed by the microboudin method to infer the triaxial stress state during microboudinage. Stress parameters proportional to the far-field differential stress were determined for sodic amphibole grains in the two orientations. The ratio of the stresses in the two orthogonal orientations (σ₁−σ₂)/(σ₁−σ₃) was calculated to be 0.64, indicating that σ₂ lies closer to the midpoint between σ₁ and σ₃ than to σ₃.     

中国东部新生代玄武岩的地球化学（Ⅱ）Sr、Nd、Ce同位素组成

对有代表性的中国东部新生代玄武岩的Ｓｒ、Ｎｄ和Ｃｅ同位素组成进行了系统的研究，结合系统的微量元素研究结果，进一步阐明其地幔源区同位素组成的不均一性；利用Ｃｅ、Ｎｄ同位素地球化学给出的信息，探讨富集Ⅰ型（ＥＭⅠ）地幔端元的成因。     

Magnitude of σ1, σ2, and σ3 at mid-crustal levels in an orogenic belt: Microboudin method applied to an impure metachert from Turkey

We revised an equation for estimating palaeostress magnitude using the microboudin technique by incorporating the influence of time on the fracture strength of minerals. The equation was used to estimate triaxial palaeostresses from a rare sample of metachert from Turkey that contains microboudinaged, columnar tourmaline grains in a wide range of orientations within the foliation plane. The estimated principal palaeostresses are σ₁ = 605 MPa, σ₂ = 598 MPa, and σ₃ = 597 MPa. As the microboudinage is considered to have occurred immediately before the rock encountered the brittle-plastic transition during exhumation, these stress values correspond to conditions at approximately 18 km depth and 300 °C within a Cretaceous orogenic belt.     

State Estimation of the North Pacific Ocean by a Four-Dimensional Variational Data Assimilation Experiment

A four-dimensional variational data assimilation system has been applied to an experiment to describe the dynamic state of the North Pacific Ocean. A synthesis of available observational records and a sophisticated ocean general circulation model produces a dynamically consistent dataset, which, in contrast to the nudging approach, provides realistic features of the seasonally-varying ocean circulation with no artificial sources/sinks for temperature and salinity fields. This new dataset enables us to estimate heat and water mass transports in addition to the qualification of water mass formation and movement processes. A sensitivity experiment on our assimilation system reveals that the origin of the North Pacific Intermediate Water can be traced back to the Sea of Okhotsk and the Bering Sea in the subarctic region and to the subtropical Kuroshio region further south. These results demonstrate that our data assimilation system is a very powerful tool for the identification and characterization of ocean variabilities and for our understanding of the dynamic state of ocean circulation. This revised version was published online in July 2006 with corrections to the Cover Date.     

Real-time difference imaging analysis of MOA Galactic bulge observations during 2000

We describe observations carried out by the MOA group of the Galactic bulge during 2000 that were designed to detect efficiently gravitational microlensing of faint stars in which the magnification is high and/or of short duration. These events are particularly useful for studies of extrasolar planets and faint stars. Approximately 17 deg² were monitored at a sampling rate of up to six times per night. The images were analysed in real time using a difference imaging technique. 20 microlensing candidates were detected, of which eight were alerted to the microlensing community whilst in progress. Approximately half of the candidates had high magnifications (≳10), at least one had very high magnification (≳50), and one exhibited a clear parallax effect. The details of these events are reported here, together with details of the on-line difference imaging technique. Some nova-like events were also observed and these are described, together with one asteroid.     

Water wedge advancing along the interface between two homogeneous layers

The behavior of the water wedge advancing along the interface between two homogeneous layers is investigated experimentally. The horizontally intruding wedge is strongly influenced by the detailed structure of the interface, even when the interface is sharp enough for its position to be visually determined. Within our experimental range, the intrusion velocity is very slow and depends on the thickness of the interface along which the water wedge intrudes. The wedge length is well described by the relation which is derived using an analogy to the linearly stratified case. The results could be useful for understanding the generation mechanism of the oceanic microstructure.     

A skewed eddy of Batchelor-modon type

A Batchelor-modon eddy is a highly specialized nonlinear vortex pair, whose potential vorticity depends linearly on the stream function viewed from the coordinates moving with the translation velocity of the eddy. To generalize it, a skewed model is developed by introducing a cubic nonlinearity in addition to the linear term. A perturbation analysis shows that the eddy region is no longer a circle but is elongated longitudinally or transversely according as the sign of the cubic term. Moreover, the eddy is slightly flattened or steepened. The cubic term increases or decreases the translation velocity, if the average radius and the amplitude are fixed. A numerical experiment on anf-plane is carried out to show that these skewed eddies retain their initial forms even after they turn a corner of the basin; they are as stable as (first-mode) standard Batchelor-modon eddies. The present skewed model gives a reasonable qualitative interpretation of deformed eddies which result from merging of two eddies or from initially Gaussian eddies near the boundary.     

http://dx.doi.org/10.1016/j.gsf.2016.06.013

The Archean continental crusts account for ca.20% of the present volume,but the thermal history of the Earths' mantle suggests much more continental crusts were formed in the early Archean.Because the Archean continental crust underwent severe metamorphism,it is important to avoid influence by the later thermal events.We carried out a comprehensive geochronological work of Cathodoluminescence(CL) observation and U-Pb dating of zircons from orthogneisses and supracrustal rocks over the Saglek Block to obtain their protolith ages.The zircons were classified into three domains of core,mantle and rims,and the cores were further classified into three groups of inherited,altered and zoned cores based on the zonation on the CL images.We estimated the protolith ages from Pb-Pb ages of the zoned-cores of zircons with low U contents.We made a detailed sketch of a small outcrop in St.John's Harbour South(SJHS) area,and classified the orthogneisses and mafic enclaves into seven generations based on the geologic occurrence.The first and second generations comprise mafic rocks and lack magmatic zircons.We conducted CL imaging and U-Pb dating of zircons from the third,sixth and seventh generation of the orthogneisses to estimate the protolith ages at 3902 L 25,3892 ± 33 and 3897 ± 33 Ma for each,supporting the presence of the over 3.9 Ca Iqaluk Gneiss.The geological occurrence that the mafic rocks occur as enclaves within the 3.9 Ga Iqaluk Gneiss indicates that they are the oldest supracrustal rocks in the world.Our geochronological and geological studies show the Uivak Gneiss is quite varied in lithology and age from 3.6 to 3.9 Ga,and tentatively classified into six groups based on their ages.The oldest Uivak Gneiss components including the Iqaluk Gneiss are present around the SJHS area,and the orthogneisses become young as it is away.The lines of evidence of overprinting of younger granitoid on older granitoid in small outcrops and geological-map scale as well as presence of inherited zircons even in the oldest suite suggests that crustal reworking played an important role on erasing the ancient crusts.