Rare-earths in Icelandic neovolcanic rocks

Seven volcanic rocks from neovolcanic zone of Iceland were analysed for rare-earths (RE). The bulk partition coefficients are estimated from combination of the studied samples. In contrast with the mid-ocean ridge basalts which show the solid-type RE patterns, four of five arbitrarily chosen Icelandic basalts appear to have liquid-type RE patterns. The occurrence of relatively pristine lava with relative unfractionated RE abundances to chondrite is also considered to be associated with the peculiar tectonics of Iceland.     

Velocity Measurements and Crack Density Determination During Wet Triaxial Experiments on Oshima and Toki Granites

— A set of experiments on four samples of Oshima Granite at 15, 40 and 60 MPa confining pressure have been performed in order to investigate the damage behavior of granite submitted to deviatoric stress. In addition an experiment on one sample of Toki Granite at 40 MPa confining pressure was performed, in order to compare and elucidate the structural effects. Using acoustic emission data, strain measurements and elastic wave velocities allow to define consistently a damage domain in the stress space. In this domain, microcracking develops. The microcracking process is, in a first stage, homogeneous and, close to failure, localized. Elastic wave velocities decrease in the damage domain and elastic anisotropy develops. Using Kachanov's model (1993), elastic wave velocities have been inverted to derive the full second-order crack density tensor and characterize the fluid saturation state from the fourth-order crack density tensor. Crack density is strongly anisotropic and the total crack density close to failure slightly above one. The results indicate that the rock is saturated in agreement with the experimental conditions. The model is thus shown to be very appropriate to infer from elastic wave velocities a complete quantitative characterization of the damaged rock.     

Notes on Extended-Range Atmospheric Prediction in the Northern Hemisphere Winter

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Characterization of serpentinization in olivine-orthopyroxene-H2O system revealed by thermogravimetric and multivariate statistical analyses

Thermogravimetric (TG) analyses were used to characterize the products and quantify the extent of serpentinization as a stepwise weight loss during heating (TG loss) or its derivative (DTG). Multivariate analyses are powerful tools for extracting information from complicated spectrum data; however, no studies have applied them to characterize serpentinites. In this study, hydrothermal experiments of olivine-H₂O, olivine–orthopyroxene-H₂O and orthopyroxene-H₂O were conducted at 250–400°C and under vapor-saturated pressure. The product minerals observed were serpentine+brucite+magnetite in the olivine-H₂O experiments and serpentine±talc in the orthoyroxene-H₂O and olivine-orthopyroxene-H₂O experiments. These results are consistent with those of previous studies; however, the positions and width of DTG peaks for individual minerals were varied depending on the experimental conditions. To extract systematics from the TG spectra, non-negative matrix factorization (NMF), an unsupervised machine learning technique, was applied to the DTG spectra of the experimental products. NMF revealed that the DTG profiles were explained by a linear combination of six basis spectra, which corresponded to the characteristic products, including three types of serpentine minerals (low-, medium-, and high-T), two types of brucite (low-and high-T), two type of talc (talc+serpentine mixture, well-crystallized talc) with different crystallinity, and noise during the TG measurement. Systematic changes in the factor loading revealed that, in the olivine-H₂O systems, the products changed from medium-T serpentine+low-T brucite to high-T serpentine+high-T brucite as serpentinization progressed. In the olivine-orthopyroxene system, low-T serpentine or poorly crystallized talc+serpentine mixture was initially formed, followed by the formation of well-crystallized talc, resulting in dehydration. Applying NMF to DTG showed the mineralogical differences between olivine and orthopyroxene systems and increases of the crystallinity during the progress of serpentinization, suggesting its potential for characterizing various serpentinites within oceanic lithospheres that suffer from several stages of alteration and weathering at different temperatures.     

A laboratory study of directional spectra with maximum likelihood method─I Developing wind wave

INTRODUCTIONDirectionalspectraofwind-generatedwavesareveryimportanttotheresearchrelatedto1.InstituteofPhysicalOceanography,OceanUniversityofQingdao,Qingdao266003,China2.ResearchinstituteforAppliedMechanics,KyUshuUniversity,Kasuga816,Japanwindwaves.Theyfindapplicationinfieldsasdiverseasbasicair-seainteraction,practicalwaveforecasting,satellitesurveillanceandengineeringdesignofmarinestructuresandvehicles.Sincethepioneeringworkofthestereowaveobservationproject(Coteetal.11960),alotofeff…     

Bathymetric influences of the Emperor Seamounts upon the subarctic gyre of the North Pacific: Examining boundary current dynamics along the eastern side of the mountain ridge with an idealized numerical model

The possible influences of the Emperor Seamounts (ESs) upon the subarctic gyre of the North Pacific (NPSAG) were investigated by a series of numerical experiments. In the experiments, a two-layer ocean with a meridional mountain ridge was forced by seasonally varying wind stress. We focused on how the return ratio, the ratio of the boundary transport along the eastern side of the ridge to the interior Sverdrup transport, changes with ridge height, width and density stratification. It was found that the return ratio can be large if the ridge width is greater than the width of the viscous boundary layer. In this case, the bottom pressure torque determines the return ratio; the return ratio is almost proportional to the ridge height when the ridge height is small and some contours of planetary potential vorticity pass over the ridge. However, the return ratio is independent of the ridge height and decreases with the stratification when the ridge height is large and all the contours of planetary potential vorticity are closed. These dependences of the return ratio were understood in terms of barotropic and baroclinic components of the bottom pressure torque. Implications for the bathymetric influences of ESs on the actual NPSAG are also discussed.     

Interannual variability of North Pacific eastern subtropical mode water formation in the 1990s derived from a 4-dimensional variational ocean data assimilation experiment

The interannual variability of eastern subtropical mode water (ESTMW) formation in the North Pacific is examined using a new ocean dataset constructed by a 4-dimensional variational data assimilation experiment covering the decade of the 1990s. The volume of newly formed ESTMW varies due to interannual variability in the following three physical processes taking place in the surface layer: (1) convergence in the transport of surface saline water induced by Ekman flow in the vicinity of the formation region, (2) thermal stratification in the preconditioning phase in association with the insolation anomaly induced largely by low-level cloud coverage, and (3) wintertime surface cooling in the eastern subtropics. We find that, in addition to the surface forcing, the properties of both the ESTMW and the upper mixed-layer water are broadly controlled by the volume of the new ESTMW component, and that the variations in the upper mixed-layer water affect the properties of ESTMW formed in the following winter. Due to the combined effect of these processes, the ESTMW subducts down to subsurface layers with a wide range of σ_θ values lying between 24.8 and 25.4 and with significant interannual variation in water mass formation.     

Provenance diversification within an arc‐trench system induced by batholith development: the Cretaceous Japan case

By comparing detrital zircon U–Pb age spectra of coeval fore‐arc and back‐/intra‐arc basin sandstones, we identified the overall distributary pattern of terrigenous clastic material within the Cretaceous arc system of SW Japan. Abundant Proterozoic (c. 1500–2500 Ma) detrital grains from the interior of East Asia are present in the Cretaceous intra‐arc basin. However, after a barrier mountain range formed during batholith emplacement, Proterozoic clastics were rarely transported into the fore‐arc domain. Episodic batholith formation in Pacific‐type orogens likely played a major role in controlling terrigenous supply routes between coeval back‐arc and fore‐arc domains. The Cretaceous orogen in Japan thus provides a good template for analysing the tectono‐sedimentary development of other arc‐related basins.