鄂尔多斯盆地南部延长组富铀凝灰岩地球化学特征及形成机制

本文系统地研究了鄂尔多斯盆地南部延长组凝灰岩元素和同位素地球化学特征。结果表明：凝灰岩主量元素具有高K、高Al、Si中等至高、低Na的特征; REE总体特征为轻稀土富集、重稀土亏损,∑REE在4857～40212 μg/g 之间变化,Eu呈现出负异常,在034～082内变化,δCe范围在080～208之间; 微量元素中U含量在312～144 μg/g 之间,Ba、U、Th、Hf和Ce呈明显正异常,Nb、P、Ti和Rb呈现负异常。详细的分析表明：U的富集和一些微量元素如Ta、Dy、Lu等相关,Th与∑REE存在明显的正相关性,这些变化可能和盆地中铀矿的富集有关; 凝灰岩的硫同位素总体呈现深源特征。根据以上的研究对凝灰岩的形成原因及形成环境进行了探讨。鄂尔多斯盆地南部延长组凝灰岩来源于秦岭造山带火山作用,其中的铀元素富集是由于砂岩型铀矿中铀向凝灰岩迁移而被还原所致。本研究对盆地砂岩型铀矿的铀运移和富集机理认识具有一定指导意义。     

宁夏河东沙地不同坡度柠条锦鸡儿(Caragana korshinskii)水分利用策略差异

为探讨全球气候变化背景下多元线性混合模型（IsoSource）和贝叶斯混合模型（MixSIAR）解析宁夏河东沙地柠条锦鸡儿（Caragana korshinskii）水分利用策略差异及适用性,利用氢氧稳定同位素技术,结合直接对比法、IsoSource模型和MixSIAR模型对比分析不同坡度（6°、10°、16°和24°）样地柠条锦鸡儿在生长季不同时期对各潜在水源的利用率,并评估两种模型的植物水分溯源效果。结果表明：柠条锦鸡儿对不同土层深度土壤水的利用存在明显的季节性差异,生长季初期,随着坡度的增大,柠条锦鸡儿对中层土壤水的利用率呈现出先增大后减小的趋势;生长季中期,随坡度增大,柠条锦鸡儿主要水分来源由深层土壤转移至浅层土壤;生长季后期,柠条锦鸡儿主要水分来源随着坡度的增大由浅层土壤转移至深层土壤。基于直接对比法的定性判断结果,IsoSource模型和MixSIAR模型计算坡度6°、10°和16°样地柠条锦鸡儿主要水分来源利用率的适用性均较高;而Mix-SIAR模型计算坡度24°样地柠条锦鸡儿主要的水分来源以及其贡献率具有更高的可靠性。Iso-Source模型更适合解析较小坡度（6°和1...     

浅谈灰土挤密桩与DDC桩在工程实践中应用与发展

DDC桩是挤密桩的一种新型桩。根据宝鸡某大型电厂中DDC桩与灰土挤密桩地基处理工程实例,从挤密机理、挤密效果、复合地基承载力与抗变形性状及复合地基浸水稳定性等诸方面进行了系统地分析对比,进而探讨挤密桩地基的应用与发展。     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

石笋记录的西南地区MIS4阶段夏季风的演化

基于重庆市丰都县羊子洞石笋Y-02的12个²³⁰Th年龄和503个氧同位素数据重建了中国西南地区60~73ka B.P.时段夏季风的演化历史。Y-02的δ¹⁸O记录显示中国季风区D/O18、D/O19a和D/O19共3个千年尺度夏季风增强事件与格陵兰间冰阶（GIS）18~19相对应。此外,Y-02记录显示：紧接着D/O18事件以后,夏季风强度突然减弱,而此时北半球高纬度地区正经历着明显的降温过程。Y-02记录捕捉到的这次东亚夏季风突然且短暂的一次减弱过程,可能是H6事件或者是H6事件季风最弱的时段。Y-02的δ¹⁸O记录显示,D/O18事件是一次较强烈的千年尺度季风增强事件,持续时间近千年,而D/O19事件在持续时间和强度上不如D/O18事件,这不同于格陵兰冰芯记录。中国季风区气候变化与格陵兰地区存在着如此紧密的联系进一步支持：东亚夏季风演化受到北半球高纬度地区气候变化的影响,但是对具体的气候事件响应可能存在不同的模式。

     

关联演化视角下地理学区域韧性分析的新思考

区域韧性是一个区域应对发展进程中短期冲击与长期变化、积极进行自我调适与转型的能力,表征了区域的适应性、创新性与可持续性,作为新兴理念反映了地理学可持续发展与区域研究的新需求。本研究综述了区域韧性研究进展,基于关联演化视角,探索构建区域韧性认知框架,将情境分析与过程分析并重,思考并总结区域韧性分析的方法论,尝试建立区域韧性评估方程,从经济、社会、环境及制度四个维度进行区域韧性评估,将区域韧性应用于中国地理学研究,分析中国区域韧性研究的一般性与特殊性,将区域韧性研究对接中国实际问题,以期对区域韧性研究做出理论贡献,助推地理学区域发展研究及相关认知领域的跨学科讨论、知识集成与学术交流,为国家制定相关区域政策提供参考,并为国家及区域可持续发展提供科学指引。     

不同带宽的防风固沙林流场结构及防风效能风洞实验

林带宽度是防风固沙林建植时要考虑的基本参数,研究不同带宽林带的防护效果对防风固沙林配置及构建具有重要的指导意义。通过风洞模拟实验,在7、10、15 m·s^-1风速条件下,对单行一带（Ⅰ型）、三行一带（Ⅱ型）、六行一带（Ⅲ型）和九行一带（Ⅳ型）共4种带宽的林带的迎风面、带中和背风面的风速进行了测定,分析了4种林带的风速流场、风速加速率和防风效果。结果表明：（1）4种林带流场结构和垂直风速变化规律相似,沿来风向均形成了林带上方和迎风面林缘附近的小范围高风速区及其后的风影区相互组合的流场结构;依据风速垂直变化规律划分为上部变化层（高度30~60 cm,受林带的影响最小）、中间变化层（高度5~20 cm,风速受林冠遮蔽作用,影响最大,且为风影区形成层）和近床面变化层（高度1~3 cm）。（2）4种林带在垂直纵剖面上的平均风速加速率随林带宽度的增大而减小,即Ⅰ型（0.90） > Ⅱ型（0.87） > Ⅲ型（0.79） > Ⅳ型（0.78）。（3）4种林带的防风效果为Ⅰ型和Ⅱ型林带相同,Ⅲ型和Ⅳ型林带相同,后2种林带的防风效果优于前2种林带,且4种林带的防风效能均随着风速的增大而减小。     

273.15 到 308.15 K下二元体系（LiCl-H2O 和 MgCl2-H2O）和三元体系（LiCl-MgCl2-H2O）的体积性质研究

用高精度振动管在 273.15 至 308.15 K 的温度范围内以 5 K 的间隔对两个二元系统（LiCl-H2O 和 MgCl2-H2O）和三元系统（LiCl-MgCl2-H2O）的密度进行了实验测定密度计。基于 Vogel-Fulcher-Tamman (VFT) 方程,对 LiCl(aq) 和 MgCl2(aq) 密度与温度和摩尔浓度的相关方程的系数进行了参数化。 Young的理想混合规则被成功地应用于基于相关的二元解性质关联三元系统的密度。根据二元和三元体系的体积特性数据,根据 Pitzer 离子相互作用理论,得到 Pitzer 单盐参数和混合离子相互作用参数。在本工作中确定了三元体系在恒定离子强度下的混合体积 (ΔVm)。     

The trade network of the Belt and Road Initiative and its topological relationship to the global trade network

Unimpeded trade is one of the cooperation priorities in the Belt and Road Initiative proposed by China. On 15 May 2017, the Joint Communique of the Leaders Roundtable of the Belt and Road Forum for International Cooperation reaffirmed the participants’ shared commitment to build an open economy and ensure free and inclusive trade. The Belt and Road Initiative (BRI) is not only China's new action to drive its open and global development, but also a platform for an increasing number of countries to explore free and inclusive trade and promote a universal, rule-based, open, non-discriminatory, and equitable multilateral trade system. It is therefore important to examine the topological relationship between the BRI and global trade networks. More specifically, this article first analyzes the community structure of trade networks using a community detection algorithm, and then estimates the topological relationship between different trade communities. The findings of this article are as follows. First, this research identified three trade communities and two sub-communities in the BRI trade network, in which China is the core, Russia is the sub-core of the biggest trade community, and India, United Arab Emirates, and Saudi Arabia are cores of the second trade community (South Asia-West Asia). Second, it identified five trade communities in the global trade network, centred on China, USA, Russia, India-United Arab Emirates, and Germany- Netherlands-France-Britain and other European developed countries. Third, the topological analysis indicated that in the global trade network, most BRI countries are attracted by the core nodes of the BRI regions, such as the China, Russia and India-United Arab Emirates core nodes, and have strong trade contacts with BRI countries. Most Central-East European countries are mainly attracted by Germany-Netherlands-France-Britain and other developed European countries with a low penetration of BRI trade. Although some Southeast Asian countries are incorporated into the Asia-Australia-South Africa community with China as the core, they still need to strengthen trade linkages with BRI countries.     

On Evaluating Characteristics of the Solute Transport in the Arid Vadose Zone

The transport of bromide (Br) under matric heads of 0, ?2, ?5, and ?10 cm using undisturbed soil columns was investigated for understanding the solute transport in arid soils. Undisturbed soil cores were collected at ground surface, directly below where tension infiltrometer measurements were made in the Amargosa Desert, Nevada, United States. Laboratory experiments were conducted by introducing water containing Br tracer into a soil column maintained at steady‐state conditions. The observed data of breakthrough curves (BTC) were well fitted to an one‐region model, except for the cores at saturation, and a core at the matric head of ?5 cm, from which the observed data were better fitted to a two‐region model. Fitted pore water velocities with the one‐region model ranged from 1.2 to 56.6 cm/h, and fitted dispersion coefficients (D) ranged from 2.2 to 100 cm²/h. Results for the core analyzed with the two‐region model indicated that D ranged from 27.6 to 70.9 cm²/h at saturation, and 25.7 cm²/h at the matric head of ?5 cm; fraction of mobile water (β) ranged from 0.18 to 0.65, and mass transfer coefficient (ω) ranged from 0.006 to 0.03. In summary, the water fluxes and Br dispersion coefficients at investigated matric heads were very high due to the coarseness of the soils and possibly due to preferential flow pathways. These high water fluxes and Br dispersion coefficients would lead to a higher risk of deeper leaching accumulating nitrate nitrogen to the groundwater, and have significant effects on the desert ecosystem.