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41.
Duong Du Bui Akira Kawamura Thanh Ngoc Tong Hideo Amaguchi Naoko Nakagawa 《Hydrogeology Journal》2012,20(8):1635-1650
A groundwater-monitoring network has been in operation in the Red River Delta, Vietnam, since 1995. Trends in groundwater level (1995?C2009) in 57 wells in the Holocene unconfined aquifer and 63 wells in the Pleistocene confined aquifer were determined by applying the non-parametric Mann-Kendall trend test and Sen??s slope estimator. At each well, 17 time series (e.g. annual, seasonal, monthly), computed from the original data, were analyzed. Analysis of the annual groundwater-level means revealed that 35?% of the wells in the unconfined aquifer showed downward trends, while about 21?% showed upward trends. On the other hand, confined-aquifer groundwater levels experienced downward trends in almost all locations. Spatial distributions of trends indicated that the strongly declining trends (>0.3?m/year) were mainly found in urban areas around Hanoi where there is intensive abstraction of groundwater. Although the trend results for most of the 17 time series at a given well were quite similar, different trend patterns were detected in several. The findings reflect unsustainable groundwater development and the importance of maintaining groundwater monitoring and a database in the Delta, particularly in urban areas. 相似文献
42.
Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting 总被引:2,自引:0,他引:2
Shoji Arai Hidenobu Okamura Kazuyuki Kadoshima Chima Tanaka Kenji Suzuki Satoko Ishimaru 《Island Arc》2011,20(1):125-137
We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall. 相似文献
43.
Eko Siswanto Junwu Tang Hisashi Yamaguchi Yu-Hwan Ahn Joji Ishizaka Sinjae Yoo Sang-Woo Kim Yoko Kiyomoto Keiko Yamada Connie Chiang Hiroshi Kawamura 《Journal of Oceanography》2011,67(5):627-650
A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag440). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for TChl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (TChl2i in case-2 waters), TTSM (regionally tuned Tassan??s TSM algorithm), and Tag440 or Cag440 (regionally tuned Tassan??s or Carder??s ag440 algorithm) were able to retrieve Chl-a, TSM, and ag440 with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, TChl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. TChl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified TChl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw555) > 2 mW cm?2 ??m?1 sr?1 (TChl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from TChl2s (for case-2 waters) to MOCChl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag440 using SeaWiFS Rrs, we recommend empirical algorithms for TTSM (pre-SeaWiFS-modified form) and MTag440 or MCag440 (SeaWiFS Rrs-modified forms of Tag440 or Cag440). These could retrieve with uncertainties as high as 82 and 52%, respectively. 相似文献
44.
Shoji Arai Akihiro Tamura Satoko Ishimaru Kazuyuki Kadoshima Yong‐Il Lee Ken‐ichiro Hisada 《Island Arc》2008,17(4):485-501
Peridotites exposed in the Yugu area in the Gyeonggi Massif, South Korea, near the boundary with the Okcheon Belt, exhibit mylonitic to strongly porphyroclastic textures, and are mostly spinel lherzolites. Subordinate dunites, harzburgites, and websterites are associated with the lherzolites. Amphiboles, often zoned from hornblende in the core to tremolite in the rim, are found only as neoblasts. Porphyroclasts have recorded equilibrium temperatures of about 1000°C, whereas neoblasts denote lower temperatures, about 800°C. Olivines are Fo90–91 in lherzolites and Fo91 in a dunite and a harzburgite. The Cr# (= Cr/(Cr + Al) atomic ratio) of spinels varies together with the Fo of olivines, being from 0.1 to 0.3 in lherzolites and around 0.5 in the dunite and harzburgite. The Na2O content of clinopyroxene porphyroclasts is relatively low, around 0.3 to 0.5 wt% in the most fertile lherzolite. The Yugu peridotites are similar in porphyroclast mineral chemistry not to continental spinel peridotites but to sub‐arc or abyssal peridotites. Textural and mineralogical characteristics indicate the successive cooling with hydration from the upper mantle to crustal conditions for the Yugu peridotites. Almost all clinopyroxenes and amphiboles show the same U‐shaped rare earth element (REE) patterns although the level is up to ten times higher for the latter. The hydration was associated with enrichment in light REE, resulting from either a slab‐derived fluid or a fluid circulating in the crust. The mantle‐wedge or abyssal peridotites were emplaced into the continental crust as the Yugu peridotite body during collision of continents to form a high‐pressure metamorphic belt in the Gyeonggi Massif. The peridotites from the Gyeonggi Massif exhibit lower‐pressure equilibration than peridotites, with or without garnets, from the Dabie–Sulu Collision Belt, China, which is possibly a westward extension of the Gyeonggi Massif. 相似文献
45.
The Sindong Group was deposited in the north–south trending half‐graben Nakdong Trough, southern Korean peninsula. The occurrence of detrital chromian spinels from the Jinju Formation of the Sindong Group in the Gyeongsang Basin means that the mafic to ultramafic rocks were exposed in its provenance. The chromian spinels from the Jinju Formation are characterized by extremely low TiO2 and Fe3+. Moreover, their range of Cr# is from 0.45 to 0.80 and makes a single trend with Mg#. The chemistry of chromian spinels implies that the source rocks for chromian spinels were peridotites or serpentinites, which originated in the mantle wedge. To more narrowly constrain their source rocks, the Ulsan and Andong serpentinites exposed in the Gyeongsang Basin were examined petrographically. Chromian spinels in the Andong serpentinite differ from those of the Jinju Formation and those in the Ulsan serpentinite partly resemble them. Furthermore, the Jinju chromian spinel suite is similar to the detrital chromian spinels from the Mesozoic sediments in the Circum‐Hida Tectonic zone, which includes the Nagato Tectonic zone in Southwest Japan and the Joetsu Belt in Northeast Japan. This suggests that the basement rocks, which were located along the main fault bounding the eastern edge of the Nakdong Trough, had exposures of peridotite or serpentinite. It is possible that the Nakdong Trough was directly adjacent to the Circum‐Hida Tectonic zone before the opening of the Sea of Japan (East Sea). 相似文献
46.
Shuichi Tanahashi Hiroshi Kawamura Toshihiko Matsuura Tomoyuki Takahashi Hiroyuki Yusa 《Journal of Oceanography》2000,56(3):345-358
We have developed an algorithm to estimate the wide-ranging Sea Surface Temperature (SST) data from the GMS-5 (Geostationary Meteorological Satellite) S-VISSR (Stretched-Visible Infrared Spin Scan Radiometer). Better SST estimates are realized by averaging the temporal variation of the VISSR calibration table and decreasing noise of the split-window terms using a spatial filter. The effects of the satellite zenith angle were examined in detail for better estimates, and VISSR-derived SSTs with root-mean-square (rms) error of 0.8 K were achieved using a new algorithm. The accuracy of SST estimates has been improved by using the temporal-spatial average of the split-window terms. Using the new techniques, we demonstrate that the hourly wide-ranging SST image data can be used to study the daily variations of SSTs in the Northern and Southern Pacific Oceans. 相似文献
47.
Shoji Arai 《Contributions to Mineralogy and Petrology》1984,87(3):260-264
Compositional variation of phlogopitic micas in upper mantle peridotites is reviewed. Phlogopitic micas in garnet peridotites are systematically lower in Al (or eastonite component) than those in spinel peridotites. The core of phlogopite megacryst and phenocryst of kimberlite is always lower in Al than the rim. It is apparent that Al/(Al + Si) ratio or eastonite component in phlogopitic micas in ultramafic rocks is controlled by the equilibrium pressure and temperature. In the upper mantle peridotites containing garnet or spinel, the Al/(Al + Si) ratio of phlogopitic mica decreases with increasing pressure at constant temperature. Phlogopitic mica is a potential thermo-barometer in both garnet- and spinel-peridotite facies. 相似文献
48.
Shin-Ichi Machida Hisako Hirai Taro Kawamura Yoshitaka Yamamoto Takehiko Yagi 《Physics and Chemistry of Minerals》2007,34(1):31-35
High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa
at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν
1 appeared at 17 GPa and that the splitting of vibration mode of ν
3 occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between
the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might
result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up
to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman
shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into
another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition
of the structure. 相似文献
49.
The Eocene dyke swarm with east-west general trend intrudes the Cretaceous sedimentary rocks in ~25 km north of the Khur city (Central Iran). Some of the studied dykes can be followed for over 7 km, but the majority of exposures in the area are less than 5 km long. The dykes commonly exhibit a chilled contact with the wall rocks. These dykes are trachybasalt and basalt in composition. The trachybasalt dykes are much more abundant. The basaltic dykes cross cut the trachybasalt dykes in some locations, indicating that trachybasalt dykes are older than the basaltic ones. Primary igneous minerals of the basaltic dykes are olivine (chrysolite), clinopyroxene (diopside, augite), plagioclase (labradorite), sanidine, magnetite, orthopyroxene (enstatite), spinel and phlogopite, and secondary minerals are zeolite (natrolite and mesolite), chlorite (diabantite), calcite and serpentine. The trachybasalt dykes are composed of clinopyroxene (diopside), plagioclase (labradorite), sanidine, mica (biotite and phlogopite), amphibole (magnesio-hastingsite) and magnetite as primary minerals, and chlorite and calcite as secondary ones. Whole rocks geochemical data of the studied dykes indicate their basic and calc-alkaline nature and suggest that these two set of dykes were derived from the same parental magma. The chondrite-normalized REE patterns and the primitive mantle-normalized multi-elemental diagram of the Khur dykes show enrichment of light rare earth elements (LREE) relative to heavy rare earth elements (HREE), and negative anomalies of high field strength elements (HFSE) (e.g. Ti, Nb and Ta). These rocks show enrichment of the large ion lithophile elements (LILE) (e.g. Cs, Ba, Th and U) and depletion of the HREE and Y relative to MREE, Zr and Hf. In the chondrite-normalized REE diagram, the basalts show elevated REE abundances relative to the trachybasalt samples. Geochemical analyses of the studied samples suggest a spinel lherzolite from the mantle as the source rock and confirm the role of subduction in their generation. The chemical characteristics of the Khur dykes resemble those of continental arc rocks, and they were possibly formed by subduction of the Central-East Iranian microcontinent (CEIM) confining oceanic crust and decompression melting of a lithospheric subcontinental mantle spinel lherzolite enriched by subduction. 相似文献
50.
The prograde deserpentinized peridotites from the talc zone in the Happo-O’ne complex, central Japan, show differences in their field relation and mineral assemblage with the high-P retrograde peridotites of the other part of the complex. They show a mineral assemblage, olivine + talc + antigorite ± prograde tremolite ± chlorite, formed by thermal metamorphism around the granitic intrusion at T, 500-650 °C and P < 7 kbar. The olivine has numerous opaque inclusions and high Fo (91.5-96.5) relative to the retrograde olivine, reflecting its formation by deserpentinization. The prograde tremolite, which is low in Al2O3 (<1.0 wt.%), Cr2O3 (<0.35 wt.%), and Na2O (<0.6 wt.%) but high in Mg# (up to 0.98) and SiO2 (up to 59.9 wt.%), is different in size, shape and chemistry from the retrograde tremolite. The prograde peridotites display a U-shaped REE pattern (0.02-0.5 times PM), similar to diopside-zone retrograde metaperidotites, possible protoliths. They are enriched in LILE (e.g., Cs, Pb, Sr, Rb) relative to HFSE (e.g., Ta, Hf, Zr, Nb), like their protoliths, because of their local re-equilibration with the fluid released during dehydration of the protoliths. They have high contents of REE and some trace elements (e.g., Cs, Th, U, Ta) relative to their protoliths because of an external-element addition from the granitic magma. In-situ analyses of peridotitic silicates confirmed that the prograde tremolite and talc display a spoon-shaped primitive mantle (PM)-normalized REE pattern (0.1-3 times PM) in which LREE are higher than HREE contents. The prograde tremolite is depleted in Al, Na, Cr, Sc, V, Ti, B, HREE and Li, but is enriched in Si, Cs, U, Th, HFSE (Hf, Zr, Nb, Ta), Rb and Ba relative to the retrograde tremolite; the immobile-element depletion in this tremolite is inherited from its source (antigorite + secondary diopside), whereas the depletion of mobile elements (e.g., Li, B, Na, Al) is ascribed to their mobility during the deserpentinization and/or the depleted character of the source of tremolite. The enrichment of HFSE and LILE in the prograde tremolite is related to an external addition of these elements from fluid/melt of the surrounding granitic magma and/or in situ equilibrium with LILE-bearing fluid released during dehydration of serpentinized retrograde metaperidotites and olivine-bearing serpentinites (protoliths). The prograde olivine is higher in REE and most trace-element contents than the retrograde one due to the external addition of these elements; it is enriched in B, Co and Ni, but depleted in Li that was liberated during deserpentinization by prograde metamorphism. 相似文献