Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.     

Origin of layering in cumulate gabbros in the Oman ophiolite: Insights from magnetic susceptibility measurements in the Wadi Sadm area

Abstract   Magnetic susceptibility and the anisotropy of magnetic susceptibility were measured on an 800-cm-thick succession of cumulate gabbro in the Sadm area of the Oman ophiolite. The section contained three distinct cumulate units. The susceptibility tends to decrease upward in each from a melanocratic layer (several tens of centimeters thick) to a leucocratic layer (a few meters thick). The susceptibility decreases in accordance with the decreasing number of magnetite grains, which are the alteration product mainly of olivine minerals. This suggests the cyclic downward accumulation of olivine in the cumulate gabbro. The apparent strain deduced from the patterns of magnetic and grain fabrics was the result mostly of simple shear, so that the layering of gabbro is understood to be formed primarily by a crystal cumulus process followed by simple shear deformation.     

Dike intrusion associated with the 2000 eruption of Miyakejima Volcano, Japan

The model for the 2000 dike intrusion event between Kozushima and Miyakejima volcano, Japan, was reinvestigated. After the sudden earthquake swarm in Miyakejima volcano, a dike intrusion of large volume was detected by the nationwide GPS network (Geonet). The displacements detected with GPS stations over an area with a radius of about 200 km shows a distribution that is consistent with the dike source being located near Miyakejima volcano.The dike was intruded northwestwards between Miyakejima and the neighboring Kozushima volcano. We searched for the parameters in the models that reproduce the regional displacements due to dike intrusion between Miyakejima and Kozushiima islands. We tested three models, (1) the model with a single dike, (2) the model with a dike and a point dislocation source which represents a creep dislocation source and (3) the model with a dike and a deflation source which represents a magma reservoir. Though all three models can match the horizontal displacements near the source area, model 1 fails to reproduce the regional displacements in the central part of Japan. Both models 2 and 3 can reproduce the regional displacement for horizontal components. Model 3 produces slightly better results than model 2 for vertical components. The balance in the volume budget for models 2 and 3 is also consistent with the observations. These results show that we cannot distinguish between the two models using only GPS observation. As there is no direct evidence for such a large creep or ductile source (corresponds to M7 or more) as proposed in model 2 and the active seismic region migrated back and forth within the linear swarm region, the model with a dike and a deep magma source is preferable. For the deflation point source, we obtained a deflation volume of 1.5 km³ at the depth of 20 km below the dike. An additional ~0.95 km³ of volume loss through caldera collapse and edifice deflation took place at Miyakejima. We conclude that the magma that intruded the dike came in part from below Miyakejima and in part from below the sea floor between Miyakejima and Kozushima, perhaps from reservoirs at the Moho.Editorial responsibility: S Nakada, T Druitt     

Distribution and expression of gas seeps in a gas hydrate province of the northeastern Sakhalin continental slope, Sea of Okhotsk

Multidisciplinary surveys were conducted to investigate gas seepage and gas hydrate accumulation on the northeastern Sakhalin continental slope (NESS), Sea of Okhotsk, during joint Korean–Russian–Japanese expeditions conducted from 2003 to 2007 (CHAOS and SSGH projects). One hundred sixty-one gas seeps were detected in a 2000 km² area of the NESS (between 53°45′N and 54°45′N). Active gas seeps in a gas hydrate province on the NESS were evident from features in the water column, on the seafloor, and in the subsurface: well-defined hydroacoustic anomalies (gas flares), side-scan sonar structures with high backscatter intensity (seepage structures), bathymetric structures (pockmarks and mounds), gas- and gas-hydrate-related seismic features (bottom-simulating reflectors, gas chimneys, high-amplitude reflectors, and acoustic blanking), high methane concentrations in seawater, and gas hydrates in sediment near the seafloor. These expressions were generally spatially related; a gas flare would be associated with a seepage structure (mound), below which a gas chimney was present. The spatial distribution of gas seeps on the NESS is controlled by four types of geological structures: faults, the shelf break, seafloor canyons, and submarine slides. Gas chimneys that produced enhanced reflection on high-resolution seismic profiles are interpreted as active pathways for upward gas migration to the seafloor. The chimneys and gas flares are good indicators of active seepage.     

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.     

SAR-imaged spiral eddies in Mutsu Bay and their dynamic and kinematic models

A pattern of slick streaks winding into a spiral, known as a spiral eddy, was identified in 5 images taken by the ERS-1/2 synthetic aperture radar (SAR) in Mutsu Bay (Japan); dynamic and kinematic models of these spiral eddies have been proposed. Common characteristics of the five spiral eddies are: 1) an eddy diameter of about 15 km; 2) their location in the western part of the bay; and 3) their cyclonic direction of rotation. Moreover, the wind conditions over the bay were common: prior to acquiring the images, a strong easterly wind continued blowing for more than one day. The wind field on the bay is known to be orographically steered and has strong windstress vorticity, which generates cyclonic circulation. The diameter and location of the circulation simulated with a numerical ocean model corresponded well to those of the identified spiral eddies. Based on these facts, we propose a dynamic model for the movement of a slick streak, and a kinematic model for the formation of a spiral eddy. We have assumed calm air, a microlayer and seawater with a cyclonic circulation in the dynamic model. The balance of forces is established in the microlayer among the frictional force from the seawater, the frictional force from the calm air, the gravitational force, and the Coriolis force. As a result, the velocity vector of the microlayer deflects slightly towards the center of the cyclonic circulation. We have assumed a point source of the microlayer in the kinematic model. The shapes of a slick streak simulated with the models agree well with the identified patterns in the SAR images.     

Detecting red tides in the eastern Seto inland sea with satellite ocean color imagery

A multi-spectral classification scheme is proposed to identify water with red tide(s) using satellite ocean color imagery obtained by the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). The study area was the eastern Seto Inland Sea in Japan, where serious red tides frequently occur. “Background Ocean Colors” (BOCs hereafter), or colors of water around a red tide or those of the water before/after a red tide, are calculated as the monthly climatological average of normalized water-leaving radiances (nLw) with 0.01 degree spatial resolution with SeaWiFS imagery. Criteria for detecting red-tide pixels are established from analyses of characteristics of the nLws (in the 443, 490, 510, and 555 nm bands) anomalies from BOCs and the nLw spectra together with the red-tide records in Osaka Bay. The proposed scheme can efficiently indicate the presence or absence of red tides for independent match-ups with 83% accuracy. Additional validations of specific events indicate that the algorithm performed well in the study area. These results suggest that the scheme is appropriate to detect red tides in the optically complex coastal water of the eastern Seto Inland Sea.