Estrogenic activity in sediments contaminated by nonylphenol in Tokyo Bay (Japan) evaluated by vitellogenin induction in male mummichogs (Fundulus heteroclitus)

Estrogenic activity was determined in sediments collected from Tokyo Bay. Sampling was performed at five stations including the site near the sewage treatment plant. The most estrogenic sediment collected near the sewage treatment plant was fractionated into ten fractions using normal-phase high-performance liquid chromatography. Chemical analysis was carried out for each fraction and nonylphenol (NP, 20,700 ng g⁻¹ dry wt) was detected at a higher concentration than estron (2.39 ng g⁻¹ dry wt) and 17β-estradiol (<0.7 ng g⁻¹ dry wt). Furthermore, each fraction was administered to male mummichogs (Fundulus heteroclitus), and vitellogenin (Vtg) was measured after two weeks. The induction of Vtg was observed; this estrogenic potency could be attributed to the NP content in this fraction. This is the first report to suggest that the high NP concentration in the sediments from Tokyo Bay has the potential to induce Vtg in wild fish.     

A heating process of Kuchi-erabu-jima volcano,Japan, as inferred from geomagnetic field variations and electrical structure

Since August 2000, we have recorded the total intensity of the geomagnetic field at the summit area of Kuchi-erabu-jima volcano, where phreatic eruptions have repeatedly occurred. A time series analysis has shown that the variations in the geomagnetic field since 2001 have a strong relationship to an increase in volcanic activity. These variations indicate thermal demagnetization of the subsurface around the presently active crater. The demagnetization source for the early variations, until summer 2002, was estimated at about 200 m below sea level. For the variations since 2003, the source was modeled on the basis of the expansion of a uniformly magnetized ellipsoid. The modeling result showed that the source is located at 300 m above sea level beneath the crater. We carried out an audio-frequency magnetotelluric survey with the aim of obtaining a relation between the demagnetization source and the shallow structure of the volcano. A two-dimensional inversion applied to the data detected two good conductors, a shallow thin one which is restricted to a region around the summit area, while the other extends over the edifice at depths between 200 and 800 m. These conductors are regarded as clay-rich layers with low permeability, which were assumed to be generated through hydrothermal alteration. The demagnetization source for the early variations was possibly located at the lower part of the deep conductor and the source after 2003 lies between the two conductors, where groundwater is considered to be abundant. Based on these results, as well as on seismological, geodetic, and geochemical information, we propose a heating process of the Kuchi-erabu-jima volcano. In the initial stage, high-temperature volcanic gases supplied from the deep-seated magma remained temporarily at the level around the lower part of the less permeable deep conductor since the ascent path had not yet been established. Then, when the pathway developed as a result of repeated earthquakes, it became possible for a massive flux of volcanic gases to ascend through the conductor. The high temperature gases reached the aquifer located above the conductor and the heat was efficiently transported to the surrounding rocks through the groundwater. As a consequence, an abrupt increase of the gas flux and diffusion of the heat through the aquifer occurred and the high-temperature zone expanded. Since the high-temperature zone is located beneath another conductor, which acts as caprock, we assume that the energy of the phreatic explosion is accumulated there.     

Gray box identification of flexible structures: application to robust active vibration suppression control

The paper deals with gray box identification of flexible structures and active vibration suppression from a robust control perspective. First, the linearized mathematical model of an N‐storey flexible structure is presented. Next, the generalized mathematical model is particularized for the investigated three‐storey flexible structure. The considered flexible structure is identified based on black box and gray box identification methods and the model's parametric uncertainties are deduced. Furthermore, control constraints are presented for the design problem, in case of velocity as well as acceleration feedback, from a robust control perspective. Finally, the effectiveness of the control system is tested through experiments, when the input disturbance is assumed to be a sinusoidal one as well as a historical earthquake record (1940 El Centro record). Copyright © 2001 John Wiley & Sons, Ltd.     

峨眉山地区大气漂尘化学组成研究

为了揭示峨眉山大气漂尘的化学特征，研究小组分别在1998，1999，2000年使用小型大气采样器进行采样，并测得样品中含有水溶性化学成分（Na^ ,K^ ,Mg^2 ,Ca^2 ,SO4^2-,NO3^-,NH4^ 和Cl^-)和酸溶性化学成分（Pb和Zn)。这一地区三年的大气成分与1990年的相似，而且峨眉山的Na^ ,Cl^-,SO4^2-,NO3^-,Ca^2 ,NH4^ ，Pb和Zn浓度分别比日本山形县鹤岗的要高出4－15，3－19，3－5，3－6，13－23，4－7，11－28和10－23倍之多。     

Electrokinetic phenomena associated with a water injection experiment at the Nojima fault on Awaji Island, Japan

Abstract Self-potential variations were measured to estimate the magnitude of electrokinetic and hydrological parameters (zeta potential and permeability) of the Nojima Fault zone in Awaji, Japan. The study observed self-potential variations that seemed to be associated with water flow from the injection well to the fracture zone, which were induced by turning the injection on and off. Amplitudes of the variations were a few to 0.03 V across 320–450 m dipoles. These variations can be explained well with an electrokinetic model. The quantity k/ζ (permeability/zeta potential) is in the range 1.6 × 10⁻¹³− 5.4 × 10⁻¹³ m²/V. Permeability of the Nojima fault zone can be estimated as approximately 10⁻¹⁶–10⁻¹⁵ m² on the assumption that the zeta potential is in the range –0.01 to –0.001 V.     

Detection of crustal inhomogeneity in the Nojima Fault zone using earth current noise

Abstract A resistivity survey method using artificial telluric noise was examined and applied to a field of a fault zone. The electric earth current was measured at 50 sites in the Nojima Fault zone, which is in the northwestern part of Awaji Island, southwestern Japan. The dominant component of the observed electric field is supposed to be leakage currents from DC electric railways running outside the island. Amplitude and polarization of the stray current were systematically investigated and were revealed to represent the subsurface electrical structure of the study area. Some features on the fault zone's electrical structure have been pointed out, including: (i) an electrical boundary that corresponds to a geological one between granite (resistive) and sediments (conductive); and (ii) a low resistivity spot on the surface rupture of the earthquake fault. The structure estimated in the present study is both qualitatively and quantitatively consistent with previous resistivity surveys done using other methods pursued in the same area. It shows the validity of the 'stray current method' as one that is easy and uses low-cost resistivity exploration tools in a region where the effect of artificial noise caused mainly by leakage currents from electrical railways cannot be ignored.     

Geochemistry of apatites in the granitic rocks of the Molybdenum, Tungsten, and Barren provinces of Southwest Japan

Recognition of the importance of chlorine complexing in enhancing the solubility of metal sulfides in aqueous solutions has led to the view that the chlorine content of intrusive rock could govern the ability of a magma to separate a metal-rich hydrothermal phase. This article presents the chlorine and fluorine contents of apatites in the granitic rocks of the Barren, Tungsten, and Molybdenum provinces of Southwest Japan.The abundance of Cl in apatites correlates negatively with rock D.I. (differentiation indices), and the abundance of F in apatites correlates positively with rock D.I. The abundance of Cl in apatites of the Molybdenum province is generally higher than that of the Tungsten and Barren provinces, and the abundance of F in apatites in the Molybdenum province is generally lower than that of F in apatites of the Tungsten and Barren provinces.Apatites in the granitic rocks associated with tungsten and fluorite mineralization and granite pegmatite formation, and from the Barren province are mostly F-OH apatites     

Numerical modelling of the three-dimensional stress field in southwestern Japan

It has been inferred from the focal mechanism of earthquakes and their hypocenter distribution (Shiono, 1977) that the stress field in southwestern Japan indicates complicated features; a NW-SE compression at shallow depths along the Nankai trough, an E-W or ESE-WNW compression in the inland crust, an extension parallel to the leading edge of the Philippine Sea plate at subcrustal depths in the region from the southern Chubu to northwestern Shikoku, and a down-dip tension beneath the Kyushu island.In order to investigate possible sources of these complex features of the stress state, a three-dimensional finite element method is employed to model the configuration of the subducting Philippine Sea plate, taking into consideration the following three possible types of forces:

1. (1) A negative buoyancy due to the density contrast between the subducting plate and the surrounding mantle.

2. (2) A northwestward compressive force generated by the movement of the Philippine Sea plate.

3. (3) A westward compressive force due to the movement of the Pacific plate.

For various combinations of different magnitudes of these forces, and of different elastic moduli, the stresses at a number of selected sites are calculated, and their directions are compared with those inferred from the focal mechanism and other geophysical information.It is found that the observed extensional stresses parallel to the leading edge of the subducting Philippine Sea plate may be caused mainly by the negative buoyancy. The northwestward compressive force may not play an important role in generating the complex stress field in southwestern Japan. The observed E-W compressional stress field prevailing in the inland region appears to result mainly from the westward-moving Pacific plate. The present results suggest that if a thin low-velocity transitional layer exists just above the subducting Philippine Sea plate, it could give appreciable effects on the mechanism of low-angled thrust faulting off the Kii peninsula and the Shikoku island.The magnitude of the shear stress in the continental crust and in the subducting plate is estimated to be of the order of several hundred bars, although the calculated shear stresses are considerably affected by the configuration of the subducting plate and also by the applied forces.It is interesting that the stress distribution appears to have some relations to seismicity of subcrustal earthquakes, and to the rupture process of large thrust earthquakes along the plate boundary.     

Surface microtopography of metamorphic white micas

Gold decoration and platinum-carbon-shadowing techniques of electron microscopy have been applied to study the surface microtopographs of noncleavage (001) faces of porphyroblastic white micas and sericite crystals collected from the chlorite, biotite, and garnet zones in the Shiragayama area in the Sanbagawa metamorphic terrain, Shikoku, Japan. Two different types of surface microtopograph have been observed; parallel step system and saw-tooth step system. The former is interpreted as representing the surface microtopographs formed either by growth or under near equilibrium conditions, the latter either by dissolution or under rigorous kinetic conditions. The former has been observed on porphyroblastic white micas occurring in the middle portion of each metamorphic zone and on all sericite crystals, the latter on most sericites and on porphyroblastic white micas occurring along the boundaries of the neighboring metamorphic zones. It is suggested that the observed variations in the surface microtopographic characteristics are due to Ostwald ripening during a kind of sintering process in which interstitial water plays an essential role, and that the drastic changes along the metamorphic zone boundaries are due to dehydration reactions. Retrogressive metamorphism is considered to have an almost negligible effect, if any, upon the surface microtopographs.     

3-D Simulation of Tectonic Loading at Convergent Plate Boundary Zones: Internal Stress Fields in Northeast Japan

The evidence of east-west compression in northeast Japan has been reported by many investigators on the basis of geodetic, geologic and geomorphic data, but its origin still remains far from understood. In the present study we have proposed a mechanical model of tectonic loading at convergent plate boundary zones, and demonstrated its validity through the numerical simulation of internal stress fields in northeast Japan with realistic 3-D geometry of plate interfaces. At convergent plate boundary zones, in general, a part of plate convergence is consumed by steady slip along plate interfaces, and the remaining part by inelastic deformation (seismic faulting, aseismic faulting, and active folding) of overriding plates. Such a plate boundary process to be called ``partial collision' can be quantitatively described by introducing a collision rate defined as c = 1 − steady slip rate at plate interfaces/plate convergence rate. By this definition, we can simply represent the mechanical process of partial collision, which includes total subduction (c = 0) and total collision (c = 1) as two extreme cases, in terms of steady slip rates at plate interfaces. On the basis of elastic dislocation theory, first, we numerically computed the internal stress fields in northeast Japan produced by the total subduction of the Pacific plate beneath the North American plate, however the computed stress pattern was opposite in sense to observations. Then, we computed the internal stress fields by taking c = 0.1 on average, and succeeded in reproducing the observed east-west compression in northeast Japan. This indicates that the concept of partial collision is essential to understand the mechanism of intraplate tectonic loading.