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961.
Bernard Charlier Øyvind Skår Are Korneliussen Jean-Clair Duchesne Jacqueline Vander Auwera 《Contributions to Mineralogy and Petrology》2007,154(2):119-134
Major and trace element XRF and in situ LA-ICP-MS analyses of ilmenite in the Tellnes ilmenite deposit, Rogaland Anorthosite
Province, SW Norway, constrains a two stage fractional crystallization model of a ferrodioritic Fe-Ti-P rich melt. Stage 1
is characterized by ilmenite-plagioclase cumulates, partly stored in the lower part of the ore body (Lower Central Zone, LCZ),
and stage 2 by ilmenite-plagioclase-orthopyroxene-olivine cumulates (Upper Central Zone, UCZ). The concentration of V and
Cr in ilmenite, corrected for the trapped liquid effect, (1) defines the cotectic proportion of ilmenite to be 17.5 wt% during
stage 1, and (2) implies an increase of D
VIlm during stage 2, most likely related to a shift in fO2. The proportion of 17.5 wt% is lower than the modal proportion of ilmenite (ca. 50 wt%) in the ore body, implying accumulation
of ilmenite and flotation of plagioclase. The fraction of residual liquid left after crystallization of Tellnes cumulates
is estimated at 0.6 and the flotation of plagioclase at 26 wt% of the initial melt mass. The increasing content of intercumulus
magnetite with stratigraphic height, from 0 to ca. 3 wt%, results from differentiation of the trapped liquid towards magnetite
saturation. The MgO content of ilmenite (1.4–4.4 wt%) is much lower than the expected cumulus composition. It shows extensive
postcumulus re-equilibration with trapped liquid and ferromagnesian silicates, correlated with distance to the host anorthosite.
The Zr content of ilmenite, provided by in situ analyses, is low (<114 ppm) and uncorrelated with stratigraphy or Cr content.
The data demonstrate that zircon coronas observed around ilmenite formed by subsolidus exsolution of ZrO2 from ilmenite. The U-Pb zircon age of 920 ± 3 Ma probably records this exsolution process.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
962.
Vertical migration of municipal wastewater in deep injection well systems,South Florida,USA 总被引:1,自引:2,他引:1
Deep well injection is widely used in South Florida, USA for wastewater disposal largely because of the presence of an injection zone (“boulder zone” of Floridan Aquifer System) that is capable of accepting very large quantities of fluids, in some wells over 75,000 m3/day. The greatest potential risk to public health associated with deep injection wells in South Florida is vertical migration of wastewater, containing pathogenic microorganisms and pollutants, into brackish-water aquifer zones that are being used for alternative water-supply projects such as aquifer storage and recovery. Upwards migration of municipal wastewater has occurred in a minority of South Florida injection systems. The results of solute-transport modeling using the SEAWAT program indicate that the measured vertical hydraulic conductivities of the rock matrix would allow for only minimal vertical migration. Fracturing at some sites increased the equivalent average vertical hydraulic conductivity of confining zone strata by approximately four orders of magnitude and allowed for vertical migration rates of up 80 m/year. Even where vertical migration was rapid, the documented transit times are likely long enough for the inactivation of pathogenic microorganisms. 相似文献
963.
André Strasser 《Swiss Journal of Geoscience》2007,100(3):407-429
Detailed investigation of facies and sedimentary structures reveals that, during the Middle Oxfordian to Late Kimmeridgian,
the shallow carbonate platform of the Swiss and French Jura Mountains recorded high-frequency sea-level fluctuations quite
faithfully. The cyclostratigraphic analysis within the established biostratigraphic and sequence-chronostratigraphic framework
implies that the resulting hierarchically stacked depositional sequences formed in tune with the orbital cycles of precession
(20 kyr) and eccentricity (100 and 400 kyr). The astronomical time scale presented here is based on the correlation of 19
platform sections and 4 hemipelagic sections from south-eastern France where good biostratigraphic control is available. The
cyclostratigraphic interpretation suggests that the interval between sequence boundaries Ox4 and Kim1 (early Middle Oxfordian
to earliest Kimmeridgian) lasted 3.2 myr and that the Kimmeridgian sensu gallico has a duration of 3.2 to 3.3 myr. The astronomical time scale proposed here is compared to time scales established by other
authors in other regions and the discrepancies are discussed. Despite these discrepancies, there is a potential to estimate
the durations of ammonite zones and depositional sequences more precisely and to better evaluate the rates of sedimentary,
ecological and diagenetic processes.
Editorial handling: Hanspeter Funk, Helmut Weissert, Stefan Bucher 相似文献
964.
Daniel Bernoulli Lukas Hottinger Silvia Spezzaferri Peter Stille 《Swiss Journal of Geoscience》2007,100(2):215-225
Shallow-water limestones of presumed Late Cretaceous and Eocene age, interbedded with basaltic lavas, were described by earlier authors from São Nicolau in the northwestern part of the Cabo Verde archipelago. If confirmed, these ages would imply late Mesozoic shallow-marine and subaerial volcanic activity in the Cabo Verde archipelago, and document a geological history very different from that known so far from other Cabo Verde Islands, from which no subaerial volcanic activity before the mid-Cenozoic is known. Our re-investigation of the foraminiferal fauna indicates a Late Miocene age for the presumed Late Cretaceous and Eocene limestones. The hypothesis of a long-lived hot spot, active by the Early Cretaceous, and of a major island-building stage in the Cabo Verde Islands during this period, is therefore not supported by the present bio- or chronostratigraphic data. 相似文献
965.
966.
There is an exceptionally rich aquatic fauna in the epikarst, the skin of karst. High species richness in the epikarst, coupled
with its special vulnerability as the first point of entry of nearly all toxic spills, makes its protection especially important.
The epikarst fauna may also be an useful tool in tracing the potential route of pollutants. Copepods in epikarst have extremely
local distributions, and their body size is such that they are largely at the mercy of directional flows. In a series of caves
in southwest Slovenia and West Virginia, a significant fraction of the copepod species occur in less than 100 m of linear
extent. This suggests a pattern of highly restricted lateral flow under normal conditions and the distribution of copepods
could potentially be used to trace water movement. Under high flow conditions as would often be the case with toxic spill,
mounding of water may increase the lateral radius of flow. Nevertheless, copepods may be useful tracers. 相似文献
967.
A. Foubert D. Van Rooij D. Blamart J.-P. Henriet 《International Journal of Earth Sciences》2007,96(1):141-158
Three provinces, characterized by the presence of carbonate mounds interpreted as cold-water coral banks have been reported
in Porcupine Seabight, SW of Ireland and were recently subjected to many detailed studies. This contribution discusses the
use of X-ray imagery and physical properties in deciphering palaeoceanographic, sedimentological and biological processes.
Physical property core logging and X-ray imagery are used to identify and describe sedimentation regimes and so their respective
palaeoceanographic and palaeoclimatological settings in two mound provinces, respectively the Belgica mound province and the
Magellan mound province. Both provinces show at present time clear differences in the hydrodynamic environment. This study
confirms that also during the past the oceanographic and sedimentological environment of both provinces differ clearly. Impacts
of glacial–interglacial variations and locally derived ice rafting events (IRE), comparable with the North Atlantic Heinrich
events (HE) have been recognized in both provinces. Moreover, the combination of X-ray imagery, magnetic susceptibility, gamma
density and P-wave velocity makes it possible to estimate the coral content and coral distribution in unopened cores localized
on top of carbonate mounds. A comparison between on-mound and off-mound cores in both provinces allowed revealing some mechanisms
of mound evolution and coral growth versus time. 相似文献
968.
A model for estimating the value of sampling programs and the optimal number of samples for contaminated soil 总被引:1,自引:0,他引:1
Pär-Erik Back 《Environmental Geology》2007,52(3):573-585
A model is presented for estimating the value of information of sampling programs for contaminated soil. The purpose is to calculate the optimal number of samples when the objective is to estimate the mean concentration. A Bayesian risk–cost–benefit decision analysis framework is applied and the approach is design-based. The model explicitly includes sample uncertainty at a complexity level that can be applied to practical contaminated land problems with limited amount of data. Prior information about the contamination level is modelled by probability density functions. The value of information is expressed in monetary terms. The most cost-effective sampling program is the one with the highest expected net value. The model was applied to a contaminated scrap yard in Göteborg, Sweden, contaminated by metals. The optimal number of samples was determined to be in the range of 16–18 for a remediation unit of 100 m2. Sensitivity analysis indicates that the perspective of the decision-maker is important, and that the cost of failure and the future land use are the most important factors to consider. The model can also be applied for other sampling problems, for example, sampling and testing of wastes to meet landfill waste acceptance procedures. 相似文献
969.
Hugues Raimbourg Bruno Goffé Laurent Jolivet 《Contributions to Mineralogy and Petrology》2007,153(1):1-28
Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe2+Mg−1 exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a
H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe2+ and Mg. While these kinetic factors confine garnet reequilibration to Fe2+Mg−1 exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates. 相似文献
970.