Assessment of the UV camera sulfur dioxide retrieval for point source plumes

Digital cameras, sensitive to specific regions of the ultra-violet (UV) spectrum, have been employed for quantifying sulfur dioxide (SO₂) emissions in recent years. The instruments make use of the selective absorption of UV light by SO₂ molecules to determine pathlength concentration. Many monitoring advantages are gained by using this technique, but the accuracy and limitations have not been thoroughly investigated. The effect of some user-controlled parameters, including image exposure duration, the diameter of the lens aperture, the frequency of calibration cell imaging, and the use of the single or paired bandpass filters, have not yet been addressed. In order to clarify methodological consequences and quantify accuracy, laboratory and field experiments were conducted. Images were collected of calibration cells under varying observational conditions, and our conclusions provide guidance for enhanced image collection. Results indicate that the calibration cell response is reliably linear below 1500 ppm m, but that the response is significantly affected by changing light conditions. Exposure durations that produced maximum image digital numbers above 32 500 counts can reduce noise in plume images. Sulfur dioxide retrieval results from a coal-fired power plant plume were compared to direct sampling measurements and the results indicate that the accuracy of the UV camera retrieval method is within the range of current spectrometric methods.     

Sea level rise and tigers: predicted impacts to Bangladesh’s Sundarbans mangroves

The Sundarbans mangrove ecosystem, shared by India and Bangladesh, is recognized as a global priority for biodiversity conservation. Sea level rise, due to climate change, threatens the long term persistence of the Sundarbans forests and its biodiversity. Among the forests’ biota is the only tiger (Panthera tigris) population in the world adapted for life in mangrove forests. Prior predictions on the impacts of sea level rise on the Sundarbans have been hampered by coarse elevation data in this low-lying region, where every centimeter counts. Using high resolution elevation data, we estimate that with a 28 cm rise above 2000 sea levels, remaining tiger habitat in Bangladesh’s Sundarbans would decline by 96% and the number of breeding individuals would be reduced to less than 20. Assuming current sea level rise predictions and local conditions do not change, a 28 cm sea level rise is likely to occur in the next 50–90 years. If actions to both limit green house gas emissions and increase resilience of the Sundarbans are not initiated soon, the tigers of the Sundarbans may join the Arctic’s polar bears (Ursus maritimus) as early victims of climate change-induced habitat loss.     

Measurements Of Thermal Updraft Intensity Over Complex Terrain Using American White Pelicans And A Simple Boundary-Layer Forecast Model

An examination of boundary-layer meteorological and avian aerodynamic theories suggests that soaring birds can be used to measure the magnitude of vertical air motions within the boundary layer. These theories are applied to obtain mixed-layer normalized thermal updraft intensity over both flat and complex terrain from the climb rates of soaring American white pelicans and from diagnostic boundary-layer model-produced estimates of the boundary-layer depth z_i and the convective velocity scale w_*. Comparison of the flatland data with the profiles of normalized updraft velocity obtained from previous studies reveals that the pelican-derived measurements of thermal updraft intensity are in close agreement with those obtained using traditional research aircraft and large eddy simulation (LES) in the height range of 0.2 to 0.8 z_i. Given the success of this method, the profiles of thermal vertical velocity over the flatland and the nearby mountains are compared. This comparison shows that these profiles are statistically indistinguishable over this height range, indicating that the profile for thermal updraft intensity varies little over this sample of complex terrain. These observations support the findings of a recent LES study that explored the turbulent structure of the boundary layer using a range of terrain specifications. For terrain similar in scale to that encountered in this study, results of the LES suggest that the terrain caused less than an 11% variation in the standard deviation of vertical velocity.     

The evolution of the Porcupine and Rockall basins,offshore Ireland: the geological template for carbonate mound development

The margins of the deep-water sedimentary basins west of Ireland contain a number of large clusters (provinces) of spectacular carbonate mounds and build-ups. These basins have a complex development history involving the interplay of rift tectonics, thermal subsidence, igneous activity and oceanographic variations. The Porcupine and Rockall basins both rest upon thin continental crust, the consequence of major rift episodes in Permo-Triassic, Late Jurassic and Early Cretaceous times. Phases of volcanism occurred in the Early Cretaceous and especially in the Early Cenozoic. Fluid flow within the basins is likely to have been controlled by the overall basin geometry and by the distribution and linkage of permeable strata with fault systems, stratal surfaces and unconformities. A number of regional unconformities, controlled by both basin tectonic and regional oceanographic effects, can be mapped and correlated throughout the Porcupine and Rockall basins. The youngest of these unconformities (C10: Early Pliocene) can be traced throughout much of the NW European Atlantic margin. It forms the horizon on which virtually all the carbonate mounds in the basins develop, suggesting a geologically instantaneous mound nucleation and growth event. Although the control on their development is uncertain, the mound clusters show a spatial association with lithified strata, buried contourite and deltaic deposits, slope failure features and with the basin margins. Analysis of these relationships points to a combination of geological and oceanographic processes controlling mound initiation and growth.     

Cenozoic alongslope processes and sedimentation on the NW European Atlantic margin

Based on studies of sediment accumulations deposited from-and erode by-alongslope flowing ocean currents on the European continental margin from Porcupine (Ireland) to Lofoten (Norway), the evolution of the Cenozoic paleocirculation was reconstructed as part of the STRATAGEM project. There is evidence of ocean current-controlled erosion and deposition in the Rockall Trough, in the Faeroe-Shetland Channel and on the Vøring Plateau since the late Eocene, although the circulation pattern remains ambiguous. The late Palaeogene flow in the Rockall Trough was almost probably driven by southerly-derived Tethyan Outflow Water. The extent and strength of any northerly-derived flow is uncertain. From the early Neogene (early-mid-Miocene), there was a massive regional expansion of contourite drift development both in the North Atlantic and in the Norwegian-Greenland Sea. This was most probably related to the development of the Faroe Conduit, the opening of the Fram Strait and the general subsidence of the Greenland-Scotland Ridge. These may have combined to cause a considerable acceleration in the exchange and overflow of deep waters between the Arctic and Atlantic Oceans. An early late Neogene (late early Pliocene) regional erosional event has been ascribed to a vigorous pulse of bottom-current activity, most probably the result of a global reorganisation of ocean currents associated with the closure of the Central American Seaway. During the late Neogene, contourites and sediment drifts developed in deep-water basins, between units of glacigenic sediments as well as infill of several paleo-slide scars. These sediments were derived from areas of bottom-current erosion as well as from the development of Plio-Pleistocene prograding sediment wedges, incorporating the extensive sediment supply derived from shelf-wide ice sheets. Presently a profound winnowing prevails along the shelf and upper slope due to the inflowing currents of Atlantic water. Depocentres of sediments derived from the winnowing are located (locally) in lower slope embayments and in slide scars.     

Dielectric constants of crystalline and amorphous spodumene,anorthite and diopside and the oxide additivity rule

The dielectric constants and dissipation factors of LiAlSi₂O₆, CaAl₂Si₂O₈ and CaMgSi₂O₆ in both the crystalline (α-spodumene, anorthite, and diopside) and amorphous forms were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: spodumene κ′ ₁₁=7.30 tan δ= 0.0007 κ′₂₂=8.463 tan δ= 0.0002 κ′₃₃ =11.12 tan δ= 0.0007 anorthite κ′ _a ^*=5.47 tan δ= 0.0009 κ′_b ^*=8.76 tan δ= 0.0010 κ′_c ^*=7.19 tan δ= 0.0013 diopside κ′₁₁=9.69 tan δ= 0.0016 κ′₂₂ = 7.31 tan δ= 0.0007 κ′₃₃=7.29 tan δ= 0.00019 LiAlSi₂O₆ κ′=8.07 tan δ= 0.047 amorphous CaAl₂Si₂O₈ κ′=7.50 tan δ= 0.0024 amorphous CaMgSi₂O₆ κ′=8.89 tan δ= 0.0021 amorphous The dielectric properties of a spodumene glass, progressively crystallized at different conditions, were also determined. As the crystallization temperature was increased from 720 to 920° C, κ′ increased from 6.22 to 6.44. The dissipation factor, tan δ, remained constant at 0.020. Similarly, as the crystallization time at 750° C increased from 0.5 hr to 6.0 hr, κ′ increased from 6.28 to 6.35. The deviations of the measured dielectric polarizabilities as determined from the Clausius-Mosotti equation from those calculated from the sum of oxide polarizabilities according to α _D(mineral, glass) = σ α _D(oxides) are +7.4% for α-spodumene, +1.2% for diopside, and +28.0, +19.6 and +15.9% for amorphous spodumene, anorthitie and diopside compositions, respectively. Positive deviations in α-spodumene and anorthite are consistent with lower than normal apparent cation bond valence sums and are believed to be evidence for loosely bonded “rattling” Li and Ca ions. Diopside, with Ca and Mg ions having normal bond valence sums, exhibits no abnormal deviation from additivity. Larger positive deviations in amorphous SiO₂, LiAlSi₂O₆, CaAl₂Si₂O₈ and CaMgSi₂O₆ are postulated to arise from a combination of loosely bonded cations and disordered O⁼ ions where the oxygen dielectric polarizability increased from its normal value of 2.0 ų in well-behaved oxides to 2.2–3.0 Å₃ in the amorphous phases.     

A wide-angle seismic traverse through the Variscan of southwest Ireland

A wide-angle seismic profile across the western peninsulas of SW Ireland was performed. This region corresponds to the northernmost Variscan thrust and fold deformation. The dense set of 13 shots and 109 stations along the 120  km long profile provides a detailed velocity model of the crust.
  The seismic velocity model, obtained by forward and inverse modelling, defines a five-layer crust. A sedimentary layer, 5–8  km thick, is underlain by an upper-crustal layer of variable thickness, with a base generally at a depth of 10–12  km. Two mid-crustal layers are defined, and a lower-crustal layer below 22  km. The Moho lies at a depth of 30–32  km. A low-velocity zone, which coincides with a well-defined gravity low, is observed in the central part of the region and is modelled as a Caledonian granite which intruded upper-crustal basement. The granite may have acted as a buffer to northward-directed Variscan thrusting. The Dingle–Dungarvan Line (DDL) marks a major change in sedimentary and crustal velocity and structure. It lies immediately to the north of the velocity and gravity low, and shows thickness and velocity differences in many of the underlying crustal layers and even in the Moho. This suggests a deep, pre-Variscan control of the structural development of this area. The model is compatible with thin-skinned tectonics, which terminated at the DDL and which incorporated thrusts involving the sedimentary and upper-crustal layers.     

The remarkable occurrence of large rainfall-induced debris flows at two different locations on July 12, 2008, Southern Sierra Nevada, CA, USA

On July 12, 2008, two convective cells about 155 km apart produced a brief period of intense rainfall triggering large debris flows in the southern Sierra Nevada. The northernmost cell was centered over Oak Creek Canyon, an east-flowing drainage, and its tributaries near Independence, CA, USA. About 5:00 p.m., debris flows passed down the South Fork and North Fork of Oak Creek to merge into a large single feature whose passage affected the historic Mt. Whitney Fish hatchery and blocked California State Highway 395. At about the same time, the southernmost cell was largely centered over Erskine Creek, a main tributary of the west-flowing Kern River. Debris flows issued from several branches to coalesce into a large debris flow that passed along Erskine Creek, through the town of Lake Isabella, CA, USA and into the Kern River. It was observed reaching Lake Isabella about 6:30 p.m. Both debris flows caused significant disruption and damage to local communities.