Carbon sequestration and environmental effects of afforestation with Pinus radiata D. Don in the Western Cape, South Africa

A three-step methodology to assess the carbon sequestration and the environmental impact of afforestation projects in the framework of the Flexible Mechanisms of the Kyoto Protocol (Joint Implementation and Clean Development Mechanism) was developed and tested using a dataset collected from the Jonkershoek forest plantation, Western Cape, South Africa, which was established with Pinus radiata in former native fynbos vegetation and indigenous forest. The impact of a change in land use was evaluated for a multifunctional, a production and a non-conversion scenario. First, the carbon balance was modelled with GORCAM and was expressed as (1) C sequestration in tC ha⁻¹ year⁻¹ in soil, litter, and living biomass according to the rules of the first commitment period of the Kyoto Protocol, and (2) CO₂ emission reductions in tC ha⁻¹ year⁻¹, which includes carbon sequestered in the above-mentioned pools and additionally in wood products, as well as emission reductions due to fossil fuel substitution. To estimate forest growth, three data sources were used: (1) inventory data, (2) growth simulation with a process-based model, and (3) yield tables. Second, the effects of land use change were assessed for different project scenarios using a method related to Life Cycle Assessment (LCA). The method uses 17 quantitative indicators to describe the impact of project activities on water, soil, vegetation cover and biodiversity. Indicator scores were calculated by comparing indicator values with reference values, estimated for the climax vegetation. The climax vegetation is the site-specific ecosystem phase with the highest exergy content and the highest exergy flow dissipation capacity. Third, the land use impact per functional unit of 1 tC sequestered was calculated by combining the results of step 1 and step 2. The average baselines to obtain carbon additionality are 476 tC ha⁻¹ for indigenous forest and 32 tC ha⁻¹ for fynbos. Results show that the influence of the growth assessment method on the magnitude of C sequestration and hence on the environmental impact per functional unit is large. When growth rate is assessed with the mechanistic model and with the yield table, it is overestimated in the early years and underestimated in the long term. The main conclusion of the scenario analysis is that the production forest scenario causes higher impacts per functional unit than the multifunctional scenario, but with the latter being less efficient in avoiding CO₂ emissions. The proposed method to assess impacts on diverse components of the ecosystem is able to estimate the general tendency of the adverse and positive effects of each scenario. However, some indicators, more specifically about biodiversity and water balance, could be improved or reinterpreted in light of specific local data about threat to biodiversity and water status.     

Maximising Multi-Stakeholder Participation in Government and Community Volcanic Hazard Management Programs; A Case Study from Savo, Solomon Islands

Participatory rural appraisal (PRA) methods and philosophies were trialed in a volcanic risk management planning and awareness activity for Savo Island, a historically highly destructive volcano in the Solomon Islands. Through a combination of methods we tried to combine the roles of facilitators and educators, and to involve the input of all stakeholders (from community to national government) in the process of volcanic risk management. The PRA approach was an ideal way to address the fundamental differences in outlook, education, needs, and roles of individuals and groups involved or affected. It was also an important catalyst to Savo island- or community-based planning initiatives, which are arguably the most important step toward the preparedness of the 2500 inhabitants of the island for any future destructive volcanic activity. We adapted almost every tenet of the PRA philosophy through inexperience, self-perceived importance and desire to combine both scientific and traditional views for Savo volcanic risk management planning. Nevertheless, what emerged from our experiences was an idea of how fundamentally well suited many PRA approaches are to initiating dialogue within diverse stakeholder groups, and deriving combined scientific/geologic and local/community risk assessments and mitigation action plans. The main challenge remaining includes increasing the involvement or voice of less powerful community members (women, youth, non-landowners) in risk management decision-making in such male-dominated hierarchical societies.     

Chronology of Pliocene and Quaternary bioevents and climatic events from fission-track ages on tephra beds, Wairarapa, New Zealand

High-resolution Pliocene and Pleistocene sequences exposed on land in New Zealand are some of the few detailed records of widepread marine bioevents and paleoclimatic changes in the Southern Hemisphere. Marine biostratigraphy calibrated in deep-sea cores by paleomagnetic reversals has been the primary basis for the chronology of these sequences. We have determined ages for several tephra beds which now provide an independent numerical age calibration for a well-studied marine and terrestrial section in Wairarapa. By using the isothermal plateau fission track (ITPFT) method on volcanic glass we have overcome the problems of partial track fading and detrital mineral contamination, which hindered earlier studies, to reveal a new chronology extending back to nearly 5 Ma.

Our ages for the Hikawera Tuff (4.91 ± 0.25 Ma) and Spooner Tuff (3.44 ± 0.13 Ma) are consistent with the appearance and disappearance of many early Pliocene foraminiferial species, validating their age calibration in New Zealand. However, some fossil occurrences, including coccoliths, differ temporally by as much as 0.55 Ma, perhaps due to local tectonic-induced recycling.

Four Pleistocene tephra beds (Potaka tephra (1.00 ± 0.03 Ma), Kaukatea tephra (0.87 ± 0.05 Ma), Rangitawa tephra (ca. 0.35 Ma) and Kawakawa tephra (ca. 0.22 Ma)) are now recognised in the Wairarapa sequence via stratigraphic and new geochemical and age data. These beds allow direct correlation to other marine and terrestrial basins, as well as volcanic regions in New Zealand, and will ultimately aid in a regional paleoenvironmental reconstruction where bioevents are absent. The tephra ages indicate that the marine sediment accumulation rates varied from 90 to 250 m/Ma between different sections of the Pliocene and reached ca. 350 m/Ma in the last 2.4 Ma, when the sequence displays pronounced glacioeustatic cyclic deposition. In the terrestrial realm, the oldest loess in New Zealand is now constrained to between 1.00 and 0.87 Ma.     

Geomorphological characteristics of slope failures in northeast Viti Levu island,Fiji, triggered by Tropical Cyclone Winston in February 2016

The highways circumnavigating Viti Levu play a pivotal role in Fiji's socioeconomic development, and are a crucial link to transport aid during disasters. Slope failures triggered by heavy rainfall and tropical cyclones have led to considerable damage and fatalities along Viti Levu's main roads in the past. Knowledge of slope instability mechanisms is key for the successful identification and management of slope failure hazards, however, there is a paucity of such information for Fiji's main roads. Severe Tropical Cyclone (STC) Winston was the strongest cyclone on record to make landfall in Fiji and affected the Fiji Islands from the early hours of 20 February until 3 am, 21 February, 2016. We present a field reconnaissance examining the characteristics and mechanisms of slope failures induced by STC Winston along a 35 km stretch of the northern part of the Viti Levu's ring road, “Kings Road”. Approximately 61 distinct shallow, small‐scale slope failures were identified most of which were of a complex type and included earth and debris slides (planar and rotational) with a minor flow component. The trigger for the slope failures was the ~258 mm of rainfall in 24 hours after 30‐days of antecedent rainfall totalling 482 mm. This caused rapid increases in porewater pressures, especially at the contact of residual soils and the underlying weathered basement rock. Evidence of recurring slips along Kings Road indicates that contemporary slope instability is likely caused by elevated porewater pressure during high intensity rainfall events in clay‐dominated soils.     

Influence of Hydrological Regime in Determining the Response of Macroalgal Blooms to Nutrient Loading in Two Irish Estuaries

Eutrophication and the development of persistent opportunistic macroalgal blooms are recognised as one of the main detrimental effects of increased anthropogenic pressures on estuarine and coastal systems. This study aimed to highlight the interplay between pressures and controlling physical factors on ecosystem functioning. The hypothesis that hydrological regime can control the growth of opportunistic macroalgae was tested with the study of two Irish estuaries, the Argideen and the Blackwater, with similar nutrient loading sources but divergent hydrological regimes. Seasonal monitoring data was initially examination, while the application of a pre-existing box model allowed a further analysis of the influence of residence time and nutrient load modifications on macroalgal growth. Seasonal oscillations in monitored river flow rates altered nutrient transfer from the catchments to the estuaries in both cases, as is shown through differences between winter and summer nutrient concentrations. In the Argideen, however, the relative contribution of phosphorus (P) from adjacent marine waters was high due to the shorter residence times and greater influx of marine water into the estuary. Modelling studies showed that in the Argideen Estuary, P load reduction would have potentially minimal impact on macroalgal growth due to the shorter residence time which increased the influx of P from marine sources. Nitrogen (N) load reduction of 60 % had a significant, albeit limited, impact on macroalgae and was insufficient in achieving the environmental objectives for this waterbody. For the more river-dominated Blackwater Estuary, modelled reductions in P resulted in a considerable decrease in biomass. Any further P decreases would accentuate the existing disparity in estuarine N:P ratios with possible repercussions for N transport to the coastal system. Hence, the hydrological complexity of estuarine systems demonstrated dictates that a portfolio of separate, but complimentary, management approaches may be required to address eutrophication in these estuaries.     

Initial exploration results of the Collins epithermal Au-base metal prospect,Aceh, Indonesia

Interpretation of various exploration data, in particular geochemical prospecting, offers a powerful and rapid assessment of grass-root projects in a green-field terrain. Here, we present an example of the Collins epithermal prospect in Aceh Province, Indonesia. In this area, the Au+ base-metal-bearing sheeted quartz veins (individually mostly 2–4 cm wide), which are controlled by a 250 m wide by 800 m long NNE-trending structural corridor within Paleogene sandstone and volcanic rocks, are the product of two main stages of deposition. Stage I formed veins with a sliver of cryptocrystalline quartz wall zone followed by an inner zone of comb quartz with interstitial rhombic adularia that terminates in open space. Stage I or main-stage sulfide mineralization consisting of early galena + sphalerite and later chalcopyrite occurs with the quartz + adularia. Small amounts of galena also occur in the wall zone. Stage II mineralization brecciated Stage I veins and overprinted them with silicification characterized by vuggy texture. Mineralization associated with this episode consists of earlier chalcopyrite + sphalerite + tennantite–tetrahedrite and later, vug-filling Au–Ag alloy (Ag_0.37–0.41Au_0.62–0.59). The above mineralized veins are successively flanked by silicic selvages, an illite + chlorite + pyrite ± kaolinite zone and a chlorite + epidote + carbonate + pyrite zone. Local supergene alteration induced replacement of galena by plumbogummite and anglesite and chalcopyrite by covellite. Data from fluid inclusion microthermometry in quartz indicated that the inner zone of Stage I veins formed from fluids with a 2.3 wt% salinity (0.5–3.3 wt% NaCl equivalent), at 174°C (155–211°C). Combining these physico-chemical parameters with the mineral assemblage, the mineralization occurred under a reduced environment. Rock and soil assays indicate that elevated Au concentrations (up to 16.5 ppm over 1 m) occur along northeast-trending zones and show a strong correlation with Pb, while Cu (up to 2.58% over 1 m), Zn, As, Sb, and Mo anomalies lie mostly at the periphery. The high-grade mineralized veins correlate with moderate to high resistivity and chargeability zones, and the pseudosections of such geophysical signals are interpreted as reflecting coalesced or enlarged veins at depth, or inclined veins in other localities. The intermediate sulfidation affinity for Collins points to potential mineralization at depth as well as preservation of Au-rich and sulfide-poor zones in the less eroded areas.     

The oxidation state of nanophase Fe particles in lunar soil: Implications for space weathering

We report measurements of the oxidation state of Fe nanoparticles within lunar soils that experienced varied degrees of space weathering. We measured >100 particles from immature, submature, and mature lunar samples using electron energy‐loss spectroscopy (EELS) coupled to an aberration‐corrected transmission electron microscope. The EELS measurements show that the nanoparticles are composed of a mixture of Fe⁰, Fe²⁺, and Fe³⁺ oxidation states, and exhibit a trend of increasing oxidation state with higher maturity. We hypothesize that the oxidation is driven by the diffusion of O atoms to the surface of the Fe nanoparticles from the oxygen‐rich matrix that surrounds them. The oxidation state of Fe in the nanoparticles has an effect on modeled reflectance properties of lunar soil. These results are relevant to remote sensing data for the Moon and to the remote determination of relative soil maturities for various regions of the lunar surface.     

Amplified hazard of small-volume monogenetic eruptions due to environmental controls, Orakei Basin, Auckland Volcanic Field, New Zealand

Orakei maar and tuff ring in the Auckland Volcanic Field is an example of a basaltic volcano in which the style and impacts of the eruption of a small volume of magma were modulated by a fine balance between magma flux and groundwater availability. These conditions were optimised by the pre-85?ka eruption being hosted in a zone of fractured and variably permeable Plio-Pleistocene mudstones and sandstones. Orakei maar represents an end-member in the spectrum of short-lived basaltic volcanoes, where substrate conditions rather than the magmatic volatile content was the dominant factor controlling explosivity and eruption styles. The eruption excavated a crater ?80?m deep that was subsequently filled by slumped crater wall material, followed by lacustrine and marine sediments. The explosion crater may have been less than 800?m in diameter, but wall collapse and wave erosion has left a 1,000-m-diameter roughly circular basin. A tuff ring around part of the maar comprises dominantly base surge deposits, along with subordinate fall units. Grain size, texture and shape characteristics indicate a strong influence of magma–water and magma–mud interactions that controlled explosivity throughout the eruption, but also an ongoing secondary role of magmatic gas-driven expansion and fragmentation. The tuff contains >70?% of material recycled from the underlying Plio-Pliestocene sediments, which is strongly predominant in the >2 ? fraction. The magmatic clasts are evolved alkali basalt, consistent with the eruption of a very small batch of magma. The environmental impact of this eruption was disproportionally large, when considering the low volume of magma involved (DRE?<?0.003?km³). Hence, this eruption exemplifies one of the worst-case scenarios for an eruption within the densely populated Auckland City, destroying an area of ~3?km² by crater formation and base surge impact. An equivalent scenario for the same magma conditions without groundwater interaction would yield a scoria/spatter cone with a diameter of 400–550?m, destroying less than a tenth of the area affected by the Orakei event.     

Dissolved oxygen levels in estuarine and coastal waters around Ireland

This paper presents the status of summer oxygen conditions in estuarine and coastal waters around Ireland between 2003 and 2007. Of the 95 water bodies surveyed, 85 had oxygen levels sufficient to support aquatic life. This corresponds to a surface area of 3125 km² or 99.4% of the total area assessed. Ten water bodies, representing a surface area of 20.2 km², were deficient in oxygen but still capable of supporting most aquatic life. No evidence of hypoxia (<2.0 mg/l O₂) or anoxia (<0.2 mg/l O₂) was found. Dissolved oxygen conditions in a number of estuaries continue to improve, probably due to improved municipal waste water treatment. The implementation of measures contained in both the Nitrates and Urban Waste Water Treatment Directives, together with those of the Water Framework Directive, should ensure areas of oxygen deficiency are eliminated from Irish waters.