pH influence on sorption characteristics of heavy metal in the vadose zone

Sorption is an important process in the modelling and prediction of the movement of heavy metals in unsaturated clay barriers. This experimental study investigates the effect of pH changes in the acidic range on the sorption characteristics of heavy metals such as: lead, copper and zinc in an unsaturated soil. A series of one-dimensional coupled solute and moisture leaching column tests, using different heavy metal solutions, were conducted on an unsaturated illitic soil at varying pH values. Variations of volumetric water content (VWC) with distance were measured for different time durations, and concentrations of heavy metals in the liquid and solid phases were analysed. Partitioning coefficient profiles of contaminants along the soil column were determined for each individual layer in the soil.

Results from column leaching tests showed that the sorption characteristics of heavy metals are controlled by many factors which should be taken into consideration, i.e. the VWC, time of wetting, soil pH, and the influent heavy metal concentrations. Simplification of K_d as a constant and of the VWC as a linear function cannot be considered a good assumption and may lead to an improper evaluation of the sorption phenomena and also to serious errors in predicting contaminant transport through unsaturated soils.     

Use of Geomorphological Information in Indirect Landslide Susceptibility Assessment

The objective of this paper is to evaluate the importance of geomorphological expert knowledge in the generation of landslide susceptibility maps, using GIS supported indirect bivariate statistical analysis. For a test area in the Alpago region in Italy a dataset was generated at scale 1:5,000. Detailed geomorphological maps were generated, with legends at different levels of complexity. Other factor maps, that were considered relevant for the assessment of landslide susceptibility, were also collected, such as lithology, structural geology, surficial materials, slope classes, land use, distance from streams, roads and houses. The weights of evidence method was used to generate statistically derived weights for all classes of the factor maps. On the basis of these weights, the most relevant maps were selected for the combination into landslide susceptibility maps. Six different combinations of factor maps were evaluated, with varying geomorphological input. Success rates were used to classify the weight maps into three qualitative landslide susceptibility classes. The resulting six maps were compared with a direct susceptibility map, which was made by direct assignment of susceptibility classes in the field. The analysis indicated that the use of detailed geomorphological information in the bivariate statistical analysis raised the overall accuracy of the final susceptibility map considerably. However, even with the use of a detailed geomorphological factor map, the difference with the separately prepared direct susceptibility map is still significant, due to the generalisations that are inherent to the bivariate statistical analysis technique.     

Water pollution in gold mining industry: a case study in Roşia Montană district, Romania

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.     

One-atmosphere melting behaviour and nomenclature of terrestrial lavas

On a plot of MgO against one-atmosphere liquidus almost all published data for lavas delineate a single trend, which is fairly well-defined above 1160° C. Segments of this trend form a convenient set of major classificatory subdivisions of lavas. It appears to be hard to justify the use of the term basalt for lavas with less than 6 percent MgO. Even with this restriction, basaltic aphanites occupy a substantial thermal (1150 to 1250° C one-atmosphere liquidi) and chemical (e.g. 6 to 11 percent MgO) range, which might profitably be subdivided. Finally, it is shown that the one-atmosphere liquidus thermal range occupied by the strongly alkalic sodic and potassic lavas is as wide as that covered by the entire set of basaltic volcanic suites from picrites and ankaramites to rhyolites, trachytes and phonolites.Presented at the symposium Recent Advances in the Studies of Rocks and Minerals at High Pressures and Temperatures held in Montreal, 1972. Jointly sponsored by the International Mineralogical Association and the Commission on Experimental Petrology.     

Trophic modeling of the Northern Humboldt Current Ecosystem, Part II: Elucidating ecosystem dynamics from 1995 to 2004 with a focus on the impact of ENSO

The Northern Humboldt Current Ecosystem is one of the most productive in the world in terms of fish production. Its location near to the equator permits strong upwelling under relatively low winds, thus creating optimal conditions for the development of plankton communities. These communities ultimately support abundant populations of grazing fish such as the Peruvian anchoveta, Engraulis ringens. The ecosystem is also subject to strong inter-annual environmental variability associated with the El Niño Southern Oscillation (ENSO), which has major effects on nutrient structure, primary production, and higher trophic levels. Here our objective is to model the contributions of several external drivers (i.e. reconstructed phytoplankton changes, fish immigration, and fishing rate) and internal control mechanisms (i.e. predator-prey) to ecosystem dynamics over an ENSO cycle. Steady-state models and time-series data from the Instituto del Mar del Perú (IMARPE) from 1995 to 2004 provide the base data for simulations conducted with the program Ecopath with Ecosim. In simulations all three external drivers contribute to ecosystem dynamics. Changes in phytoplankton quantity and composition (i.e. contribution of diatoms and dino- and silicoflagellates), as affected by upwelling intensity, were important in dynamics of the El Niño of 1997–98 and the subsequent 3 years. The expansion and immigration of mesopelagic fish populations during El Niño was important for dynamics in following years. Fishing rate changes were the most important of the three external drivers tested, helping to explain observed dynamics throughout the modeled period, and particularly during the post-El Niño period. Internal control settings show a mix of predator–prey control settings; however a “wasp-waist” control of the ecosystem by small pelagic fish is not supported.     

The buckling of plastic oblate hemi-ellipsoidal dome shells under external hydrostatic pressure

The paper presents a theoretical and an experimental investigation into the buckling of seven oblate hemi-ellipsoidal dome shells under external hydrostatic pressure. Four of the shells were made in glass reinforced plastic and three were made from a thermosetting plastic called solid urethane plastic. All the vessels were tested to destruction. The theoretical study was made with the aid of a non-linear finite element solution, where both geometrical and material non-linearity were allowed for. Good agreement was found between experiment and theory for all the vessels. The very oblate domes failed axisymmetrically. Theoretical convergence was good for the more oblate domes but it was not as good as for the less oblate domes. This may have been because the less oblate domes did not fail in a classical axisymmetric manner as was expected. This work is of much importance in ocean engineering.     

Geophysical and geochemical observations on actively seeping hydrocarbon gases on the south-eastern Yellow Sea continental shelf

In the southeastern Yellow Sea, active seepage of hydrocarbon gases has been observed by high-resolution (3.5 kHz) seismic profiling both in 1987 and 2001, occurring through a large number of plumes from the topmost pre-Holocene sedimentary layer. It is strong enough to compensate for current speed, extending vertically up to the sea surface. The gas seepage often appears to be explosive to form craters and diapirs, although pockmarks are rare due to the redistribution of mobile palimpsest sands. In core-top seawater and sediments, the gases are characterized by high amounts of C₂, homogenous ¹³C₁ values and a large difference (19.7 on average) between ¹³C₁ (–55.2 to –53.6 PDB) and ¹³C₂ (–36.8 to –32.5 PDB) values. The gases are considered to be generated with a smaller amount of C₁ at the early thermal cracking stage of labile source materials, after which the C₂ gas is enriched in ¹³C by diffusion or biological alternation at the generation or accumulation site. The homogenous ¹³C₁ values may be one of the geochemical characteristics of gases acquired at depth which are less altered in the case of rapid diffusive gas migration to the seafloor.     

Crustal complexity in the Lachlan Orogen revealed from teleseismic receiver functions

There is an ongoing debate about the tectonic evolution of southeast Australia, particularly about the causes and nature of its accretion to a much older Precambrian core to the west. Seismic imaging of the crust can provide useful clues to address this issue. Seismic tomography imaging is a powerful tool often employed to map elastic properties of the Earth's lithosphere, but in most cases does not constrain well the depth of discontinuities such as the Mohorovi?i? (Moho). In this study, an alternative imaging technique known as receiver function (RF) has been employed for seismic stations near Canberra in the Lachlan Orogen to investigate: (i) the shear-wave-velocity profile in the crust and uppermost mantle, (ii) variations in the Moho depth beneath the Lachlan Orogen, and (iii) the nature of the transition between the crust and mantle. A number of styles of RF analyses were conducted: H-K stacking to obtain the best compressional–shear velocity (V _P /V _S) ratio and crustal thickness; nonlinear inversion for the shear-wave-velocity structure and inversion of the observed variations in RFs with back-azimuth to investigate potential dipping of the crustal layers and anisotropy. The thick crust (up to 48 km) and the mostly intermediate nature of the crust?mantle transition in the Lachlan Orogen could be due to the presence of underplating at the base of the crust, and possibly to the existing thick piles of Ordovician mafic rocks present in the mid and lower crust. Results from numerical modelling of RFs at three seismic stations (CAN, CNB and YNG) suggest that the observed variations with back-azimuth could be related to a complex structure beneath these stations with the likelihood of both a dipping Moho and crustal anisotropy. Our analysis reveals crustal thickening to the west beneath CAN station which could be due to slab convergence. The crustal thickening may also be related to the broad Macquarie volcanic arc, which is rooted to the Moho. The crustal anisotropy may arise from a strong N–S structural trend in the eastern Lachlan Orogen and to the preferred crystallographic orientation of seismically anisotropic minerals in the lower and middle crust related to the paleo-Pacific plate convergence.