Satellite-based analysis of the spatial patterns of fire- and storm-related forest disturbances in the Ural region,Russia

Natural Hazards - Large-scale wildfires and windstorms are the most important disturbance agents for the Russian boreal forests. The paper presents an assessment of fire-related and wind-induced...     

Wind-driven diversion of summer river runoff preconditions the Laptev Sea coastal polynya hydrography: Evidence from summer-to-winter hydrographic records of 2007–2009

This paper examines the role of atmospheric forcing in modifying the pathways of riverine water on the Laptev Sea shelf, using summer-to-winter hydrographic surveys from 2007 to 2009. Over the two consecutive winter seasons of 2007–2008 and 2008–2009 in the area of the winter coastal polynya, our data clearly link winter surface salinity fields to the previous summer conditions, with substantially different winter salinity patterns preconditioned by summer atmospheric forcing. In the summer of 2007, dominant along-shore westerly winds in the cyclonic regime force the Lena River runoff to flow eastward. In contrast, in the summer of 2008, dominant along-shore easterly winds over the East Siberian Sea and on-shore northerly winds over the Laptev Sea in the anticyclonic regime lock the riverine water in the vicinity of the Lena Delta. Over the coastal polynya area in the southeastern Laptev Sea these patterns precondition a surface salinity difference of 8–16 psu between the winters of 2008 and 2009. Overall, this indicates a residence time of at least half a year for riverine water on the Laptev Sea shelf. Future climate change associated with an enhanced summer cyclonicity over the eastern Arctic may turn more riverine water eastward along the eastern Siberian coast, resulting in weaker vertical density stratification over the Laptev Sea shelf, with possible impact on the efficiency of vertical mixing and polynya dense water production.     

Batisite,Na2BaTi2(Si4O12)O2, from Inagli massif,Aldan, Russia: crystal-structure refinement and high-temperature X-ray diffraction study

Mineralogy and Petrology - The crystal structure of batisite, Na2BaTi2 (Si4O12)O2, from the Inagli massif (Aldan, Yakutia, Russia) was refined to R 1 = 0.032 for 1449 unique...     

FESOM under coordinated ocean-ice reference experiment forcing

Characteristics of the ocean state simulated with the Finite-Element Sea-Ice Ocean Model (FESOM) under the normalized year forcing of Coordinated Ocean-ice Reference Experiments (COREs; Griffies et al., Ocean Model 26:1–46, 2009) are compared with those of other models participating in COREs. In contrast to these models, FESOM is run on an unstructured mesh (with resolution varying between 20 and 150 km). It is shown that the ocean state simulated by FESOM is in most cases within the spread of other models, demonstrating that the unstructured mesh technology has reached the stage when it becomes a reliable tool for studying the large-scale ocean general circulation.     

The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds

The crystal structure of ilinskite, NaCu₅O₂(SeO₃)₂Cl₃, a rare copper selenite chloride from volcanic fumaroles of the Great fissure Tolbachik eruption (Kamchatka peninsula, Russia), has been solved by direct methods and refined to R ₁?=?0.044 on the basis of 2720 unique observed reflections. The mineral is orthorhombic, Pnma, a?=?17.769(7), b?=?6.448(3), c?=?10.522(4) Å, V?=?1205.6(8) ų, Z?=?4. The The CuO_mCl_n coordination polyhedra share edges to form tetramers that have 'additional' O1 and O2 atoms as centers. The O1Cu₄ and O2Cu₄ tetrahedra share common Cu atoms to form [O₂Cu₅]⁶⁺ sheets. The SeO₃ groups and Cl atoms are adjacent to the [O₂Cu₅]⁶⁺ sheets to form complex layers parallel to (100). The Na⁺ cations are located in between the layers. A review of mixed-ligand CuO_mCl_n coordination polyhedra in minerals and inorganic compounds is given. There are in total 26 stereochemically different mixed-ligand Cu-O-Cl coordinations.     

The improvement of greenhouse gas inventory as a tool for reduction emission uncertainties for operations with oil in the Russian Federation

The high quality inventory is an important step to greenhouse gas emission mitigation. The inventory quality is estimated by means of the uncertainty analysis. The level of uncertainty depends upon the reliability of activity data and the parameters used. An attempt has been made to improve the accuracy of the estimates through a shift from production-based method (IPCC Tier 1) (IPCC 2000) to enhanced combination of production-based and mass balance methods (IPCC Tier 2) (IPCC 2006) in the estimation of emissions from operations with oil that are key in the national greenhouse gas inventory of the Russian Federation. The IPCC Tier 2 (IPCC 2006) was adapted for the national conditions. The greenhouse gas emissions were calculated for 1990 to 2009 with the use of both methods. The quantitative uncertainty assessment of the calculations was performed, and the outcomes were compared. The comparison showed that the estimates made with the use of higher tier method resulted in higher accuracy and lower uncertainties (26 % respectively compared to previously derived 54 %).     

Open and coastal seas interactions south of Japan represented by an ensemble Kalman filter

We investigated the feasibility of the ensemble Kalman filter (EnKF) to reproduce oceanic conditions south of Japan. We have adopted the local ensemble transformation Kalman filter algorithm based on 20 members’ ensemble simulations of the parallelized Princeton Ocean Model (the Stony Brook Parallel Ocean Model) with horizontal resolution of 1/36°. By assimilating satellite sea surface height anomaly, satellite sea surface temperature, and in situ temperature and salinity profiles, we reproduced the Kuroshio variation south of Japan for the period from 8 to 28 February 2010. EnKF successfully reproduced the Kuroshio path positions and the water mass property of the Kuroshio waters as observed. It also detected the variation of the steep thermohaline front in the Kii Channel due to the intrusion of the Kuroshio water based on the observation, suggesting efficiency of EnKF for detection of open and coastal seas interactions with highly complicated spatiotemporal variability.     

A 35 kyr record of organic matter composition and δ13C of n-alkanes in bog sediments close to Lake Baikal: Implications for paleoenvironmental studies

We characterized the compositions of organic compounds in a Cheremushka bog sediment core (deposited over the last 35 kyr), located at the eastern coast of Lake Baikal, to obtain basic information about the terrestrial organic matter (OM) which contributed to Lake Baikal sediments. The bog sediment was analyzed for the molecular composition of n-alkanes, lignin phenols and n-C₂₄ to C₃₀ alkanoic acids, as well as the carbon isotopic composition of plant wax derived n-C₂₇ to C₃₃ alkanes.Concentrations of lignin phenols [vanillyl (V) plus syringyl (S) phenols] normalized to total organic carbon (TOC) in the Holocene are twice those for the last glacial maximum (LGM), while concentrations of TOC-normalized n-C₂₄ to C₃₀ alkanoic acids do not change markedly in this period. Thus, the ratio of lignin phenols to n-C₂₄ to C₃₀ alkanoic acids increases from the LGM to the Holocene. This result is essentially consistent with pollen analysis indicating an expansion of woody plants in the Holocene and a prevailing herb-abundant environment for the LGM. The δ¹³C values of n-C₂₇ to C₃₃ alkanes (e.g. ?29‰ to ?33‰ for C₃₁) indicate the presence of C₃-dominant plants throughout the core.The contribution of terrestrial OM to Lake Baikal sediments was estimated using the biomarkers, on the assumption that the OM in the bog sediments is a representative of the terrestrial OM around the lake. Hence, the estimation using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters indicates that 11–24% of the TOC in the Academician Ridge sediments is land-derived for both the Holocene and the LGM, which is similar to the estimates from C/N values of bulk OM. However, the estimates for terrestrial OM using the n-C₂₇ to C₃₃ alkane parameter are generally higher than those using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters. The difference is thought to be associated with the difference in source and behavior of these biomarkers.